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Volume 30 Issue 10
Oct.  2023
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文章导航 >  矿物冶金与材料学报（英文）  > 2023  >  30(10): 1897-1905
Tao Wei, Qi Zhang, Sijia Wang, Mengting Wang, Ye Liu, Cheng Sun, Yanyan Zhou, Qing Huang, Xiangyun Qiu,  and Fang Tian, A gel polymer electrolyte with IL@UiO-66-NH2 as fillers for high-performance all-solid-state lithium metal batteries, Int. J. Miner. Metall. Mater., 30(2023), No. 10, pp. 1897-1905. https://doi.org/10.1007/s12613-023-2639-0
Cite this article as:
Tao Wei, Qi Zhang, Sijia Wang, Mengting Wang, Ye Liu, Cheng Sun, Yanyan Zhou, Qing Huang, Xiangyun Qiu,  and Fang Tian, A gel polymer electrolyte with IL@UiO-66-NH2 as fillers for high-performance all-solid-state lithium metal batteries, Int. J. Miner. Metall. Mater., 30(2023), No. 10, pp. 1897-1905. https://doi.org/10.1007/s12613-023-2639-0
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研究论文

IL@UiO-66-NH2作为凝胶聚合物电解质的有效填料及其在高性能全固态锂金属电池中的应用

  • 1)

    江苏科技大学能源与动力学院, 镇江 212003, 中国

  • 2)

    南京林业大学材料科学与工程学院, 南京 210037，中国

  • 3)

    青岛大学动力集成及储能系统工程技术中心, 青岛 266071, 中国

  • 4)

    邯郸学院化学化工与材料学院, 邯郸 056005, 中国



  • 通讯作者:

    魏涛    E-mail: wt863@just.edu.cn

文章亮点

  • (1) 系统地研究了离子液体含量对纳米级别的UiO-66-NH2的改性作用。
  • (2) 提出并验证了适量地添加离子液体可在充放电循环中发生氧化分解，从而促进稳定的SEI生成的机理。
  • (3) 总结了离子液体的适量添加可以使聚合物基全固态电解质表现出更为优异的电化学性能的影响规律。
  • 随着电动汽车领域和各种储能系统的飞速发展，既具有高能量密度又具备高安全性的新型全固态锂离子电池映入了研究人员的眼帘。然而，固体电极与固态电解质之间的固-固接触可能会导致较大的界面电阻。近年来，离子液体由于具有较宽的电化学窗口（~6 V）和较高的离子电导率，也常常被用来作为固态电解质膜中的添加剂或溶剂以进一步制备凝胶聚合物电解质。本文旨在开发一种以适量离子液体加入MOFs孔内作为有效填料的凝胶聚合物电解质。本文制备了不同离子液体含量的MOFs纳米颗粒，并采用简单的流延法制备了新型凝胶聚合物电解质。同时对其进行了电化学测试，最后还将其与商业正极组装成全固态电池以进行恒电流充放电试验。研究了不同离子液体含量的MOFs纳米颗粒对固态电池电化学性能的影响。研究结果表明， 适量添加离子液体可以有效地提升凝胶聚合物电解质的电化学性能（离子电导率、锂离子迁移数、电化学窗口等），UPP-5在60°C下的离子电导率为4.842 × 10−4 S·cm−1，离子迁移数为0.52，电化学窗口可高达5.5 V。此外，Li/UPP-5/LiFePO4的全固态电池在0.2C的倍率下可稳定循环超过100个周期，且几乎没有任何容量衰减。这项研究可以为未来开发新一代全固态锂离子电池（ASSLB）创造更为有效的Li+ 导电网络提供新的见解。
    • Research Article

    A gel polymer electrolyte with IL@UiO-66-NH2 as fillers for high-performance all-solid-state lithium metal batteries

    + Author Affiliations
      Abstract
    • All solid-state electrolytes have the advantages of good mechanical and thermal properties for safer energy storage, but their energy density has been limited by low ionic conductivity and large interfacial resistance caused by the poor Li+ transport kinetics due to the solid–solid contacts between the electrodes and the solid-state electrolytes. Herein, a novel gel polymer electrolyte (UPP-5) composed of ionic liquid incorporated metal-organic frameworks nanoparticles (IL@MOFs) is designed, it exhibits satisfying electrochemical performances, consisting of an excellent electrochemical stability window (5.5 V) and an improved Li+ transference number of 0.52. Moreover, the Li/UPP-5/LiFePO4 full cells present an ultra-stable cycling performance at 0.2C for over 100 cycles almost without any decay in capacities. This study might provide new insight to create an effective Li+ conductive network for the development of all-solid-state lithium-ion batteries.
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