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Volume 30 Issue 9
Sep.  2023
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文章导航 >  矿物冶金与材料学报（英文）  > 2023  >  30(9): 1667-1679
Na Xiao, Xu Guan, Dong Wang, Haile Yan, Minghui Cai, Nan Jia, Yudong Zhang, Claude Esling, Xiang Zhao,  and Liang Zuo, Impact of W alloying on microstructure, mechanical property and corrosion resistance of face-centered cubic high entropy alloys: A review, Int. J. Miner. Metall. Mater., 30(2023), No. 9, pp. 1667-1679. https://doi.org/10.1007/s12613-023-2641-6
Cite this article as:
Na Xiao, Xu Guan, Dong Wang, Haile Yan, Minghui Cai, Nan Jia, Yudong Zhang, Claude Esling, Xiang Zhao,  and Liang Zuo, Impact of W alloying on microstructure, mechanical property and corrosion resistance of face-centered cubic high entropy alloys: A review, Int. J. Miner. Metall. Mater., 30(2023), No. 9, pp. 1667-1679. https://doi.org/10.1007/s12613-023-2641-6
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特约综述

W合金化对面心立方高熵合金组织、力学性能和耐蚀性的影响：综述

  • 1)

    东北大学分析测试中心，沈阳 110819，中国

  • 2)

    东北大学材料科学与工程学院，沈阳 110819，中国

  • 3)

    浙江工业大学之江学院，绍兴 312030，中国

  • 4)

    Laboratoire d'Étude des Microstructures et de Mécanique des Matériaux (LEM3), CNRS UMR 7239, Université de Lorraine, 57045 Metz, France

  • 5)

    Laboratory of Excellence on Design of Alloy Metals for low-mAss Structures (DAMAS), Université de Lorraine, 57045 Metz, France


  • 通讯作者:

    闫海乐    E-mail: yanhaile@mail.neu.edu.cn

    贾楠    E-mail: jian@mail.neu.edu.cn

文章亮点

  • (1) 从晶格畸变、第二相析出与细晶强化三个方面综述了W掺杂对面心立方高熵合金微观组织与力学性能的影响。
  • (2) 概述了W掺杂对面心立方高熵合金耐腐蚀性能的影响并探讨了其作用机制。
  • (3) 总结了高熵合金W合金化研究存在的问题并探讨了可能的解决方法。
  • 多主元高/中熵合金是由多种主要组成元素构成的固溶体合金。与传统合金相比，高熵合金因其具有高强度、高硬度、高耐磨性、高温稳定性、抗高温氧化性以及抗辐照性等优点，成为近些年来金属材料科学领域的研究热点。研究表明，W元素掺杂可激活多种强化机制，包括固溶强化、细晶强化和第二相强化（μ相、σ相和b.c.c.相），并且能够促使合金表面形成致密的WO3钝化膜进而改善其抗腐蚀性能。W元素合金化的上述作用使得其引起了高熵合金领域研究者的广泛关注。本文从组织结构、力学性能及抗腐蚀性能三个方面综述了掺杂W元素对多主元高/中熵合金的影响，并对其存在的问题及可能解决途径进行了探讨和分析。
    • Invited Review

    Impact of W alloying on microstructure, mechanical property and corrosion resistance of face-centered cubic high entropy alloys: A review

    + Author Affiliations
      Abstract
    • Face-centered cubic (f.c.c.) high entropy alloys (HEAs) are attracting more and more attention owing to their excellent strength and ductility synergy, irradiation resistance, etc. However, the yield strength of f.c.c. HEAs is generally low, significantly limiting their practical applications. Recently, the alloying of W has been evidenced to be able to remarkably improve the mechanical properties of f.c.c. HEAs and is becoming a hot topic in the community of HEAs. To date, when W is introduced, multiple strengthening mechanisms, including solid-solution strengthening, precipitation strengthening (μ phase, σ phase, and b.c.c. phase), and grain-refinement strengthening, have been discovered to be activated or enhanced. Apart from mechanical properties, the addition of W improves corrosion resistance as W helps to form a dense WO3 film on the alloy surface. Until now, despite the extensive studies in the literature, there is no available review paper focusing on the W doping of the f.c.c. HEAs. In that context, the effects of W doping on f.c.c. HEAs were reviewed in this work from three aspects, i.e., microstructure, mechanical property, and corrosion resistance. We expect this work can advance the application of the W alloying strategy in the f.c.c. HEAs.
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