TiSiN/CrV<sub><i>x</i></sub>N硬质多层膜的抗氧化机理以及摩擦学行为研究

鞠洪博; Moussa. Athmani; Jing Luan; Abbas AL-Rjoub; Albano Cavaleiro; TalhaBin Yaqub; Abdelouahad Chala; Fabio Ferreira; and Filipe Fernandes

doi:10.1007/s12613-023-2655-0

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文章导航 > 矿物冶金与材料学报（英文） > 2023 > 30(12): 2459-2468

Hongbo Ju, Moussa Athmani, Jing Luan, Abbas AL-Rjoub, Albano Cavaleiro, Talha Bin Yaqub, Abdelouahad Chala, Fabio Ferreira, and Filipe Fernandes, Insights into the oxidation resistance mechanism and tribological behaviors of multilayered TiSiN/CrV_xN hard coatings, Int. J. Miner. Metall. Mater., 30(2023), No. 12, pp. 2459-2468. https://doi.org/10.1007/s12613-023-2655-0

Cite this article as:

Hongbo Ju, Moussa Athmani, Jing Luan, Abbas AL-Rjoub, Albano Cavaleiro, Talha Bin Yaqub, Abdelouahad Chala, Fabio Ferreira, and Filipe Fernandes, Insights into the oxidation resistance mechanism and tribological behaviors of multilayered TiSiN/CrVxN hard coatings, Int. J. Miner. Metall. Mater., 30(2023), No. 12, pp. 2459-2468. https://doi.org/10.1007/s12613-023-2655-0

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研究论文Open Access

TiSiN/CrV_xN硬质多层膜的抗氧化机理以及摩擦学行为研究

1)
江苏科技大学材料科学与工程学院, 镇江 212003, 中国
2)
Laboratory of Physics of Thin Films and Applications, University of Mohamed Khider, BP 145 RP, Biskra 07000, Algeria
3)
CEMMPRE, ARISE, Department of Mechanical Engineering, University of Coimbra, Coimbra 3030-788, Portugal
4)
IPN - LED & MAT - Instituto Pedro Nunes, Laboratory of Tests, Wear and Materials, Coimbra 3030-199, Portugal
5)
ISEP, Polytechnic of Porto, Rua Dr. António Bernardino de Almeida, Porto 4249-015, Portugal

通讯作者:
鞠洪博 E-mail: hju@uc.pt

and Filipe Fernandes E-mail: fid@isep.ipp.pt

文章亮点

(1) 系统地研究了TiSiN/CrV_xN涂层的高温氧化物类型及其分布规律。

(2) 探讨了V在高温环境下的高温氧化行为。

(3) 揭示了V对TiSiN/CrV_xN涂层室温摩擦磨损性能影响机制。

中文摘要

全球因摩擦和磨损而造成的能源消耗和资源浪费日益严重，研发环境友好型固体润滑材料以解决严苛工况下减摩和耐磨问题是当今摩擦学领域的热点。含钒(V)的过渡族金属氮化物涂层材料因在高温范围内能原位生成具有层状结构的Magneli相而体现出优异的自润滑性能，得到了国内外相关领域学者的广泛关注。但其氧化机理的不明确限制了这类涂层材料性能进一步提升。本文通过利用直流磁控溅射技术制备了一系列的TiSiN/CrV_xN自润滑涂层材料，研究了V对其抗氧化和摩擦磨损性能的影响规律。结果表明，涂层在高温氧化过程中会出现明显的两层氧化层，其中顶层为疏松的Ti(V)O₂；底层为具有保护作用的氧化层，由铬的氧化物和硅的氧化物组成。V在高温环境下的迁移释放及其氧化导致涂层抗氧化能力随着V含量的升高而逐渐减弱。在室温条件下，V元素的添加能够显著的提升涂层的耐磨损性能，但是对这类涂层材料的摩擦系数的影响不大。

关键词:

Research ArticleOpen Access

Insights into the oxidation resistance mechanism and tribological behaviors of multilayered TiSiN/CrV_xN hard coatings

+ Author Affiliations

1)
School of Materials Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China
2)
Laboratory of Physics of Thin Films and Applications, University of Mohamed Khider, BP 145 RP, Biskra 07000, Algeria
3)
CEMMPRE, ARISE, Department of Mechanical Engineering, University of Coimbra, Coimbra 3030-788, Portugal
4)
IPN - LED & MAT - Instituto Pedro Nunes, Laboratory of Tests, Wear and Materials, Coimbra 3030-199, Portugal
5)
ISEP, Polytechnic of Porto, Rua Dr. António Bernardino de Almeida, Porto 4249-015, Portugal

Hongbo Ju is a youth editorial board member for this journal and was not involved in the editorial review or the decision to publish this article. The authors declare no conflict of interest.
The online version contains supplementary material available at https://doi.org/10.1007/s12613-023-2655-0.
Open access funding provided by FCT|FCCN (b-on).
Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.

Corresponding authors:
Hongbo Ju E-mail: hju@uc.pt

Filipe Fernandes E-mail: fid@isep.ipp.pt
Received: 23 February 2023; Revised: 24 March 2023; Accepted: 17 April 2023; Available online: 1 December 2023

Abstract

Abstract

In the last decades, vanadium alloyed coatings have been introduced as potential candidates for self-lubrication due to their perfect tribological properties. In this work, the influence of V incorporation on the wear performance and oxidation resistance of TiSiN/CrN film coatings deposited by direct current (DC) reactive magnetron sputtering is investigated. The results show that vanadium incorporation significantly decreases the oxidation resistance of the coatings. In general, two layers are formed during the oxidation process: i) Ti(V)O₂ on top, followed by a protective layer, which is subdivided into two layers, Cr₂O₃ and Si–O. ii) The diffusion of V controls the oxidation of V-containing coatings. The addition of vanadium improves the wear resistance of coatings, and the wear rate decreases with increasing V content in the coatings; however, the friction coefficient is independent of the chemical composition of the coatings. The wear of the V-containing coatings is driven by polishing wear.
- DC magnetron sputtering;
- TiSiN/CrV_xN multilayer coatings;
- oxidation resistance;
- tribology;
- wear rate

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References(51)

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TiSiN/CrV_xN硬质多层膜的抗氧化机理以及摩擦学行为研究

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Insights into the oxidation resistance mechanism and tribological behaviors of multilayered TiSiN/CrV_xN hard coatings

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TiSiN/CrVxN硬质多层膜的抗氧化机理以及摩擦学行为研究

文章亮点

中文摘要

Insights into the oxidation resistance mechanism and tribological behaviors of multilayered TiSiN/CrVxN hard coatings

Abstract

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TiSiN/CrV_xN硬质多层膜的抗氧化机理以及摩擦学行为研究

Insights into the oxidation resistance mechanism and tribological behaviors of multilayered TiSiN/CrV_xN hard coatings