FeCoNiCrMo高熵纳米片催化改善氢化镁的固态储氢性能

钟涛; 章浩宇; 宋梦臣; 蒋艺群; 商丹红; 吴富英; 张刘挺

doi:10.1007/s12613-023-2669-7

Volume 30 Issue 11

Nov. 2023

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文章导航 > 矿物冶金与材料学报（英文） > 2023 > 30(11): 2270-2279

Tao Zhong, Haoyu Zhang, Mengchen Song, Yiqun Jiang, Danhong Shang, Fuying Wu, and Liuting Zhang, FeCoNiCrMo high entropy alloy nanosheets catalyzed magnesium hydride for solid-state hydrogen storage, Int. J. Miner. Metall. Mater., 30(2023), No. 11, pp. 2270-2279. https://doi.org/10.1007/s12613-023-2669-7

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Tao Zhong, Haoyu Zhang, Mengchen Song, Yiqun Jiang, Danhong Shang, Fuying Wu, and Liuting Zhang, FeCoNiCrMo high entropy alloy nanosheets catalyzed magnesium hydride for solid-state hydrogen storage, Int. J. Miner. Metall. Mater., 30(2023), No. 11, pp. 2270-2279. https://doi.org/10.1007/s12613-023-2669-7

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研究论文

FeCoNiCrMo高熵纳米片催化改善氢化镁的固态储氢性能

1)
江苏科技大学能源与动力学院, 分析测试中心, 镇江 212003, 中国
2)
Max Planck Institute for Iron Research, Düsseldorf, 40237, Germany
3)
江苏科技大学环境与化学工程学院, 镇江 212003, 中国

通讯作者:
吴富英 E-mail: wufuying@just.edu.cn

张刘挺 E-mail: zhanglt89@just.edu.cn

文章亮点

(1) 通过湿化学球磨制备了FeCoNiCrMo高熵合金纳米片。

(2) 首次将高熵合金FeCoNiCrMo纳米引入到MgH₂体系中，较好的改进了其储氢性能。

(3) Fe、Co、Ni、Cr和Mo五种元素的协同催化作用，有助于MgH₂中氢的快速转移。

中文摘要

作为一种高密度（7.6wt%，110 kg·m⁻³）固态储氢材料，氢化镁（MgH₂）在氢气运输和储存方面大有可为。然而，其稳定的热力学特性和缓慢的动力学特性限制了其实际应用。在各种被采用的改性方法中，催化掺杂被证实在调整MgH₂放氢和吸氢性能方面发挥着重要作用。本文首次研究了铁钴镍铬钼高熵合金纳米片对MgH₂储氢性能的催化作用。实验结果表明，掺杂了9wt% FeCoNiCrMo的MgH₂在200°C开始脱氢，并在325°C下60分钟内释放出5.89wt%的氢。完全脱氢的复合材料可在低至100°C的温度下于50分钟内吸收3.23wt%的氢气。与MgH₂相比，复合材料的脱氢 ((84.47 ± 1.09) kJ·mol⁻¹）和加氢((33.02 ± 0.10) kJ·mol⁻¹)活化能分别比MgH₂降低了44.21%和55.22%。此外，复合材料的氢容量在20次循环后仅下降了0.28wt%，显示出良好的循环稳定性。微观结构分析证实，在循环过程中，Fe、Co、Ni、Cr和Mo五种元素以高熵合金的形式稳定存在，五种元素协同催化促进了MgH₂的脱氢/加氢反应。此外，FeCoNiCrMo和MgH₂之间的紧密接触提供了大量的异质活化位点和扩散通道，有助于MgH₂–9wt% FeCoNiCrMo复合材料中氢的快速转移。

关键词:

Research Article

FeCoNiCrMo high entropy alloy nanosheets catalyzed magnesium hydride for solid-state hydrogen storage

+ Author Affiliations

1)
School of Energy and Power, Instrumental Analysis Center, Jiangsu University of Science and Technology, Zhenjiang 212003, China
2)
Max Planck Institute for Iron Research, Düsseldorf, 40237, Germany
3)
School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China

Liuting Zhang is a youth editorial board member for this journal and was not involved in the editorial review or the decision to publish this article. The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Corresponding authors:
Fuying Wu E-mail: wufuying@just.edu.cn

Liuting Zhang E-mail: zhanglt89@just.edu.cn
Received: 25 February 2023; Revised: 13 April 2023; Accepted: 4 May 2023; Available online: 6 May 2023

Abstract

Abstract

The catalytic effect of FeCoNiCrMo high entropy alloy nanosheets on the hydrogen storage performance of magnesium hydride (MgH₂) was investigated for the first time in this paper. Experimental results demonstrated that 9wt% FeCoNiCrMo doped MgH₂ started to dehydrogenate at 200°C and discharged up to 5.89wt% hydrogen within 60 min at 325°C. The fully dehydrogenated composite could absorb 3.23wt% hydrogen in 50 min at a temperature as low as 100°C. The calculated de/hydrogenation activation energy values decreased by 44.21%/55.22% compared with MgH₂, respectively. Moreover, the composite’s hydrogen capacity dropped only 0.28wt% after 20 cycles, demonstrating remarkable cycling stability. The microstructure analysis verified that the five elements, Fe, Co, Ni, Cr, and Mo, remained stable in the form of high entropy alloy during the cycling process, and synergistically serving as a catalytic union to boost the de/hydrogenation reactions of MgH₂. Besides, the FeCoNiCrMo nanosheets had close contact with MgH₂, providing numerous non-homogeneous activation sites and diffusion channels for the rapid transfer of hydrogen, thus obtaining a superior catalytic effect.
- hydrogen storage;
- magnesium hydride;
- high entropy alloy;
- nano-sheets;
- catalysis

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