金属镁纳米薄膜电镀修饰的二氧化钛纳米管及其作为可逆钠金属负极沉积骨架研究

王锦山; 李锋; 赵思; 郑力拓; 黄艺吟; 洪振生

doi:10.1007/s12613-023-2685-7

Volume 30 Issue 10

Oct. 2023

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文章导航 > 矿物冶金与材料学报（英文） > 2023 > 30(10): 1868-1877

Jinshan Wang, Feng Li, Si Zhao, Lituo Zheng, Yiyin Huang, and Zhensheng Hong, Uniform nanoplating of metallic magnesium film on titanium dioxide nanotubes as a skeleton for reversible Na metal anode, Int. J. Miner. Metall. Mater., 30(2023), No. 10, pp. 1868-1877. https://doi.org/10.1007/s12613-023-2685-7

Cite this article as:

Jinshan Wang, Feng Li, Si Zhao, Lituo Zheng, Yiyin Huang, and Zhensheng Hong, Uniform nanoplating of metallic magnesium film on titanium dioxide nanotubes as a skeleton for reversible Na metal anode, Int. J. Miner. Metall. Mater., 30(2023), No. 10, pp. 1868-1877. https://doi.org/10.1007/s12613-023-2685-7

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研究论文

金属镁纳米薄膜电镀修饰的二氧化钛纳米管及其作为可逆钠金属负极沉积骨架研究

1)
福建省量子调控与新能源重点实验室, 福建师范大学物理与能源学院, 福州 350117, 中国
2)
福建师范大学碳中和研究院, 福州 350117, 中国

通讯作者:
郑力拓 E-mail: zhenglituo@fjnu.edu.cn

洪振生 E-mail: zshong@fjnu.edu.cn

文章亮点

(1) 采用低温熔盐电沉积法制备出镁金属纳米薄膜电镀修饰的二氧化钛纳米管阵列；

(2) 三维STNA-Mg骨架在钠金属负极沉积中具有超高的库伦效率和极小的过电势；

(3) 基于三维STNA-Mg-Na金属负极在全电池中展现出优异的循环性能。

中文摘要

为了实现低成本的钠金属负极，这篇文章报道一种利用离子液体作为电解液的脉冲电沉积技术，在间隙型二氧化钛纳米管阵列上进行均匀的约20 nm厚的纳米电镀镁金属薄膜。镁金属镀膜具有良好亲钠特性和低成本优势，可以有效地降低钠金属的成核能。在Na||Na对称电池中，三维结构的间隙二氧化钛纳米管能有效限制钠沉积与溶解过程中的体积变化，实现超稳定的金属可逆沉积/溶解和高达99.5%的库伦效率，以及仅为5 mV的电压极化。另外，对同样式样方法制得的镀铜样品进行对比研究表明，镁金属确实能够引导钠金属的均匀沉积并抑制枝晶生长。最后，将镀镁的间隙二氧化钛沉积金属钠负极后与商业的磷酸钒钠正极组装成全电池，可得到放电容量110.2 mAh⋅g⁻¹的全电池，并在1C的倍率下循环110圈后仍有95.6%的容量保持率。本研究为低成本的镁金属纳米电镀和高性能的钠金属负极开发提供了切实可行的方法和科研依据。

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Research Article

Uniform nanoplating of metallic magnesium film on titanium dioxide nanotubes as a skeleton for reversible Na metal anode

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Abstract

Abstract

To meet the low-cost concept advocated by the sodium metal anode, this paper reports the use of a pulsed electrodeposition technology with ionic liquids as electrolytes to achieve uniform nanoplating of metallic magnesium films at around 20 nm on spaced titanium dioxide (TiO₂) nanotubes (STNA-Mg). First, the sodiophilic magnesium metal coating can effectively reduce the nucleation overpotential of sodium metal. Moreover, three-dimensional STNA can limit the volume expansion during sodium metal plating and stripping to achieve the ultrastable deposition and stripping of sodium metals with a high Coulombic efficiency of up to 99.5% and a small voltage polarization of 5 mV in symmetric Na||Na batteries. In addition, the comparative study of sodium metal deposition behavior of STNA-Mg and STNA-Cu prepared by the same route further confirmed the advantage of magnesium metal to guide sodium metal growth. Finally, the prepared STNA-Mg–Na metal anode and commercial sodium vanadium phosphate cathode were assembled into a full cell, delivering a discharge capacity of 110.2 mAh·g⁻¹ with a retention rate of 95.6% after 110 cycles at 1C rate.
- sodium metal anode;
- titanium dioxide nanotubes;
- skeleton;
- electrodeposition;
- metallic magnesium coating

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