航空铝合金高耐蚀耐磨化学镀Ni–P梯度镀层

王波; 李佳蔚; 谢治辉; 王更杰; 余刚

doi:10.1007/s12613-023-2689-3

Volume 31 Issue 1

Jan. 2024

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文章导航 > 矿物冶金与材料学报（英文） > 2024 > 31(1): 155-164

Bo Wang, Jiawei Li, Zhihui Xie, Gengjie Wang, and Gang Yu, High corrosion and wear resistant electroless Ni–P gradient coatings on aviation aluminum alloy parts, Int. J. Miner. Metall. Mater., 31(2024), No. 1, pp. 155-164. https://doi.org/10.1007/s12613-023-2689-3

Cite this article as:

Bo Wang, Jiawei Li, Zhihui Xie, Gengjie Wang, and Gang Yu, High corrosion and wear resistant electroless Ni–P gradient coatings on aviation aluminum alloy parts, Int. J. Miner. Metall. Mater., 31(2024), No. 1, pp. 155-164. https://doi.org/10.1007/s12613-023-2689-3

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研究论文

航空铝合金高耐蚀耐磨化学镀Ni–P梯度镀层

1)
湖南大学化学与化工学院, 长沙 410012, 中国
2)
四川省化学合成与污染控制重点实验室/西华师范大学化学化工学院, 南充 637002, 中国
3)
中国航空发动机总公司中川机械有限公司, 长沙 410200, 中国

通讯作者:
谢治辉 E-mail: zhxie@cwnu.edu.cn

余刚 E-mail: yuganghnu@163.com

文章亮点

（1）系统的研究了二次浸锌的温度和时间对锌层表面形貌的影响。

（2）设计了不同含量，不同厚度的Ni–P组合梯度镀层。

（3）系统的研究了组合梯度镀层的耐磨性和耐蚀性。

中文摘要

铝合金具有极其优秀的物理性能，故而广泛应用在航空、汽车、电子等高端领域。但在严酷的航空环境中，由于铝的化学性质活泼，极其容易形成氧化膜，这层薄的氧化膜耐腐蚀性能差，同时其自身还存在硬度低和耐磨性差等缺点。为了克服铝合金性能方面的缺点，本文在航空铝合金表面制备了由不同磷含量的Ni–P化学镀层组成的Ni–P合金梯度镀层。采用多种表征和电化学方法对不同Ni–P镀层的形貌、相结构、元素组成和耐蚀性进行了表征。梯度涂层具有良好的附着力和耐腐蚀磨损性能，使铝合金能够在恶劣环境中应用。结果表明，二次浸锌对获得良好的结合力（81.2 N）至关重要。即使在弯曲试验（角度大于90°）后，最佳涂层也不会剥落和碎裂，并且在35°C下进行500 h中性盐雾试验后，目测未见腐蚀。高耐蚀性归因于三种不同镍合金层中这些微缺陷的错位和外层高P含量的非晶态结构。这些研究结果为探索满足复杂恶劣航空环境下铝合金零件高应用要求的功能梯度涂层提供了依据。

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Research Article

High corrosion and wear resistant electroless Ni–P gradient coatings on aviation aluminum alloy parts

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Abstract

Abstract

A Ni–P alloy gradient coating consisting of multiple electroless Ni–P layers with various phosphorus contents was prepared on the aviation aluminum alloy. Several characterization and electrochemical techniques were used to characterize the different Ni–P coatings’ morphologies, phase structures, elemental compositions, and corrosion protection. The gradient coating showed good adhesion and high corrosion and wear resistance, enabling the application of aluminum alloy in harsh environments. The results showed that the double zinc immersion was vital in obtaining excellent adhesion (81.2 N). The optimal coating was not peeled and shredded even after bending tests with angles higher than 90° and was not corroded visually after 500 h of neutral salt spray test at 35°C. The high corrosion resistance was attributed to the misaligning of these micro defects in the three different nickel alloy layers and the amorphous structure of the high P content in the outer layer. These findings guide the exploration of functional gradient coatings that meet the high application requirement of aluminum alloy parts in complicated and harsh aviation environments.
- aluminum alloy;
- electroless;
- nickel coating;
- corrosion;
- adhesion

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