金属–共价有机框架和共价金属–有机框架的结构综述

熊朝智; 邵振武; 洪佳男; 毕可鑫; 黄青松; 刘冲

doi:10.1007/s12613-023-2690-x

Volume 30 Issue 12

Dec. 2023

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文章导航 > 矿物冶金与材料学报（英文） > 2023 > 30(12): 2297-2309

Chaozhi Xiong, Zhenwu Shao, Jia’nan Hong, Kexin Bi, Qingsong Huang, and Chong Liu, Structural survey of metal–covalent organic frameworks and covalent metal–organic frameworks, Int. J. Miner. Metall. Mater., 30(2023), No. 12, pp. 2297-2309. https://doi.org/10.1007/s12613-023-2690-x

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Chaozhi Xiong, Zhenwu Shao, Jia’nan Hong, Kexin Bi, Qingsong Huang, and Chong Liu, Structural survey of metal–covalent organic frameworks and covalent metal–organic frameworks, Int. J. Miner. Metall. Mater., 30(2023), No. 12, pp. 2297-2309. https://doi.org/10.1007/s12613-023-2690-x

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特约综述

金属–共价有机框架和共价金属–有机框架的结构综述

1)
四川大学化学工程学院, 成都 610065, 中国
2)
北京昌平中西医结合医院, 北京 102208, 中国
3)
Department of Bioprocess Engineering, Institute of Biotechnology, Technische Universität Berlin, Berlin 10623, Germany

通讯作者:
刘冲 E-mail: liuchong@scu.edu.cn

文章亮点

(1) 系统地总结了目前已报道的MCOF和CMOF材料结构、几何拓扑以及构建单元。

(2) 从网格化学的角度对MCOF和CMOF中的分子单元和结合方式进行了综述与分析。

(3) 展望了未来MCOF和CMOF材料的结构设计方向、合成潜力以及应用前景。

中文摘要

本综述总结和归纳了金属-共价有机框架(MCOF)和共价金属-有机框架(CMOF）材料的最新进展。近年来文献中报道了多种新型MCOF和CMOF材料，它们的构建同时包含了传统金属有机框架（MOF）材料中的可逆配位键和传统共价有机框架（COF）材料中的可逆共价键。本综述首先聚焦于已报道的MCOF和CMOF材料的结构，重点介绍了它们的构建单元和单元间的连接方式（即拓扑结构）。具体而言，本综述按照MCOF和CMOF材料的构建单元维度分类（即离散构建单元和一维无限构建单元）并展开论述。对于具有离散构建单元的MCOF和CMOF材料，本文根据拓扑结构将各案例进一步划分为二维和三维网络并分别加以介绍。对于具有一维无限构建单元的材料，本文主要关注了最近出现的具有编织结构的若干种MCOF。最后，基于上述总结和分析，本文为未来MCOF和CMOF材料的设计思路、合成潜力及应用前景提出了设想。

关键词:

Invited Review

Structural survey of metal–covalent organic frameworks and covalent metal–organic frameworks

+ Author Affiliations

Abstract

Abstract

This review offers an overview of the latest developments in metal–covalent organic framework (MCOF) and covalent metal–organic framework (CMOF) materials, whose construction entails a combination of reversible coordination and covalent bonding adapted from metal–organic frameworks (MOFs) and covalent organic frameworks (COFs), respectively. With an emphasis on the MCOF and CMOF structures, this review surveys their building blocks and topologies. Specifically, the frameworks are classified based on the dimensions of their components (building blocks), namely, discrete building blocks and one-dimensional infinite building blocks. For the first category, the materials are further divided into collections of two- and three-dimensional networks based on their topologies. For the second category, the recently emerging MCOFs with woven structures are covered. Finally, the state-of-the-art in MCOF and CMOF chemistry has been laid out for promising avenues in future developments.
- metal–covalent organic frameworks;
- covalent metal–organic frameworks;
- topology;
- building block

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