低成本钠离子电池玻璃纤维隔膜的高效利用

马小航; 陈志杰; 张天文; 张雪倩; 马元; 郭雁青; 魏义永; 葛梦缘; 候之国; 訾振发

doi:10.1007/s12613-023-2691-9

Volume 30 Issue 10

Oct. 2023

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文章导航 > 矿物冶金与材料学报（英文） > 2023 > 30(10): 1878-1886

Xiaohang Ma, Zhijie Chen, Tianwen Zhang, Xueqian Zhang, Yuan Ma, Yanqing Guo, Yiyong Wei, Mengyuan Ge, Zhiguo Hou, and Zhenfa Zi, Efficient utilization of glass fiber separator for low-cost sodium-ion batteries, Int. J. Miner. Metall. Mater., 30(2023), No. 10, pp. 1878-1886. https://doi.org/10.1007/s12613-023-2691-9

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Xiaohang Ma, Zhijie Chen, Tianwen Zhang, Xueqian Zhang, Yuan Ma, Yanqing Guo, Yiyong Wei, Mengyuan Ge, Zhiguo Hou, and Zhenfa Zi, Efficient utilization of glass fiber separator for low-cost sodium-ion batteries, Int. J. Miner. Metall. Mater., 30(2023), No. 10, pp. 1878-1886. https://doi.org/10.1007/s12613-023-2691-9

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研究论文

低成本钠离子电池玻璃纤维隔膜的高效利用

1)
合肥师范学院物理与材料工程学院, 合肥 230601, 中国
2)
中国科学技术大学化学与材料科学学院, 合肥 230026, 中国

通讯作者:
訾振发 E-mail: zfzi@issp.ac.cn

文章亮点

(1) 提出了利用低成本、高韧性的滤纸复合改性高成本、低强度的玻璃纤维的设计思路。

(2) 开发了一种简单的流浆过筛工艺用以制备新型复合隔膜。

(3) 系统研究了滤纸与玻璃纤维不同复合比例对制备隔膜性能的影响。

中文摘要

隔膜是钠离子电池的关键组成部分，其性能极大影响着钠离子电池的电化学性能和安全特性。常规使用的玻璃纤维滤纸因高成本和差的机械性能而不能满足钠离子电池大规模应用的要求。本文以玻璃纤维隔膜边角料和普通定性滤纸为原料，通过简单的流浆过筛工艺制备出了一系列新型复合隔膜。当玻璃纤维与滤纸复合质量比例为1:1时，复合隔膜获得了优异的综合性能，其拉伸强度达到15.8 MPa，孔隙率为74.3%，离子电导率为1.57 × 10⁻³ S·cm⁻¹，并且该隔膜可在210°C保持良好的尺寸稳定性。组装的钠离子电池同样显示出了良好的循环性能（1C下500次循环后容量保持率为94.1%）和倍率性能（10C下放电比容量保持率为87.3%），并与电极保持了良好的界面稳定性。以上结果为高性能、低成本钠离子电池的隔膜设计提供了一些新思路。

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Research Article

Efficient utilization of glass fiber separator for low-cost sodium-ion batteries

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Abstract

Abstract

The separator is a key component of sodium-ion battery, which greatly affects the electrochemical performances and safety characteristics of the battery. Conventional glass fiber separator cannot meet the requirements of large-scale application because of high cost and poor mechanical properties. Herein, the novel composite separators are prepared by a simple slurry sieving process using glass fiber separator scraps and ordinary qualitative filter paper as raw materials. As the composite mass ratio is 1:1, the composite separator has excellent comprehensive properties, including tensile strength of 15.8 MPa, porosity of 74.3%, ionic conductivity of 1.57 × 10⁻³ S·cm⁻¹ and thermal stability at 210°C. The assembled sodium-ion battery shows superior cycling performance (capacity retention of 94.1% after 500 cycles at 1C) and rate capacity (retention rate of 87.3% at 10C), and it maintains fine interface stability. The above results provide some new ideas for the separator design of high-performance and low-cost sodium-ion batteries.
- separator;
- glass fiber;
- low cost;
- sodium-ion batteries

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