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Volume 30 Issue 10
Oct.  2023
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文章导航 >  矿物冶金与材料学报（英文）  > 2023  >  30(10): 1986-2005
Yun Fan, Cheng Chen, Siyao Zhang, Suoying Zhang, Fengwei Huo,  and Weina Zhang, Crystalline framework nanosheets as platforms for functional materials, Int. J. Miner. Metall. Mater., 30(2023), No. 10, pp. 1986-2005. https://doi.org/10.1007/s12613-023-2696-4
Cite this article as:
Yun Fan, Cheng Chen, Siyao Zhang, Suoying Zhang, Fengwei Huo,  and Weina Zhang, Crystalline framework nanosheets as platforms for functional materials, Int. J. Miner. Metall. Mater., 30(2023), No. 10, pp. 1986-2005. https://doi.org/10.1007/s12613-023-2696-4
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特约综述

作为功能材料平台的晶体骨架纳米片

  • 南京工业大学柔性电子重点实验室和先进材料研究院, 南京 211816, 中国


  • 通讯作者:

    张伟娜    E-mail: iamwnzhang@njtech.edu.cn

文章亮点

  • （1）介绍了功能晶体骨架纳米片的种类、性质和优势。
  • （2）总结了目前功能晶体骨架纳米片的制备方法包括原位合成法和合成后修饰以及在催化、分离、传感和能源存储领域的应用。
  • （3）对功能晶体骨架纳米片的制备方法的探索、种类的扩展、稳定性的提高以及应用前景提出了展望。
  • 通过整合具有独特性能的有机和无机材料而产生的新兴功能纳米材料已被广泛应用于诸多领域。近年来，由于功能晶体骨架纳米片兼具功能物种和晶体骨架纳米片材料的优点及具有协同效应，其得到了广泛的探索和研究。晶体骨架纳米片是一种由单体通过配位或共价键组装而成的多孔晶体材料，优势包括高度可接近的活性位点、大的横向尺寸、超薄的厚度和柔性，在诸多应用中表现出优异的性能。将晶体骨架纳米片与功能物种如手性分子、荧光分子、酶、聚合物和纳米颗粒等结合制备功能晶体骨架纳米片，可提高晶体骨架纳米片的性能和扩大其应用范围。因此，本文重点介绍了功能晶体骨架纳米片的制备方法和应用。首先，我们介绍了晶体骨架纳米片的优点和性质，并讨论了将功能物种与纳米片结合以形成功能晶体骨架纳米片的重要性。然后，从原位合成和合成后修饰两个方面综述了功能晶体骨架纳米片的制备方法。随后，讨论了与各种功能物种结合赋予晶体骨架纳米片的性质，并总结了它们在催化、分离、传感和能源存储方面的应用。最后，我们对目前功能晶体骨架纳米片研究领域存在的挑战提出了自己的见解，希望为优化制备方法、扩大类别、提高稳定性和探索潜在应用提供启示。
    • Invited Review

    Crystalline framework nanosheets as platforms for functional materials

    + Author Affiliations
      Abstract
    • The integration of organic and inorganic materials has been widely used in various applications to generate novel functional nanomaterials characterized by unique properties. Functional crystalline framework nanosheets and their synergistic effects have been studied recently for possessing the advantages of functional species as well as crystalline framework nanosheets. Hence, we have focused on the preparation methods and applications of functional crystalline framework nanosheets in this review. We introduced crystalline framework nanosheets and discussed the importance of integrating functional species with nanosheets to form functional crystalline framework nanosheets. Then, two aspects of the preparation methods of functional crystalline framework nanosheets were reviewed: in situ synthesis and post-synthesis modification. Subsequently, we discussed the properties of the crystalline framework nanosheets combined with various functional species and summarized their applications in catalysis, sensing, separation, and energy storage. Finally, we have shared our insights on the challenges of functional crystalline framework nanosheets, hoping to contribute to the knowledge base for optimizing the preparation methods, expanding categories, improving stability, and exploring potential applications.
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