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Volume 31 Issue 2
Feb.  2024
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文章导航 >  矿物冶金与材料学报（英文）  > 2024  >  31(2): 315-322
Daixiang Wei, Wei Wang, Longjin Jiang, Zhidong Chang, Hualei Zhou, Bin Dong, Dekun Gao, Minghui Zhang, and Chaofan Wu, Preferentially selective extraction of lithium from spent LiCoO2 cathodes by medium-temperature carbon reduction roasting, Int. J. Miner. Metall. Mater., 31(2024), No. 2, pp. 315-322. https://doi.org/10.1007/s12613-023-2698-2
Cite this article as:
Daixiang Wei, Wei Wang, Longjin Jiang, Zhidong Chang, Hualei Zhou, Bin Dong, Dekun Gao, Minghui Zhang, and Chaofan Wu, Preferentially selective extraction of lithium from spent LiCoO2 cathodes by medium-temperature carbon reduction roasting, Int. J. Miner. Metall. Mater., 31(2024), No. 2, pp. 315-322. https://doi.org/10.1007/s12613-023-2698-2
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研究论文

中温碳还原焙烧从废LiCoO2正极中优先选择性提锂

  • 1)

    北京科技大学化学与生物工程学院, 北京 100083, 中国

  • 2)

    中国科学院过程工程研究所生化工程国家重点实验室, 北京 100190, 中国

  • 3)

    安徽超越环保科技股份有限公司, 滁州 239060, 中国

  • 4)

    安徽惠宏科技有限公司, 滁州 239060, 中国



  • 通讯作者:

    王威    E-mail: weiwang@ipe.ac.cn

    常志东    E-mail: zdchang@ustb.edu.cn

文章亮点

  • (1) 中温碳还原焙烧破坏了LiCoO2的层状结构，释放层状结构中的Li
  • (2) 通过湿法研磨和超声波破碎焙烧产物中形成的Co金属团聚结构，释放被夹带的Li，以提高Li的回收率
  • (3) 最终Li的回收率为99.10%，得到纯度为99.55%的Li2CO3
  • 由于锂的价格骤增，从废锂离子电池（LIB）中回收Li变得越来越重要。本工作报道了一种中温碳还原焙烧方法，旨在从废LiCoO2（LCO）正极材料中优先选择性提Li以克服回收过程中Li的不完全回收和损失问题。在合适的温度下，控制氧化钴还原状态以破坏LCO的层状结构，Li被完全转化为水溶性的Li2CO3，Co被转化成水不溶性的CoO/Co。中温焙烧过程中形成Co易聚集形成Co金属团聚体而夹杂部分Li，湿法研磨和超声波可以将其破碎以释放被夹带的Li从而提高Li的回收率。结果表明，99.10%的Li以Li2CO3的形式回收，纯度为99.55%。这项研究为从废锂离子电池正极中优先选择性提取锂提供了一个新的视角。
    • Research Article

    Preferentially selective extraction of lithium from spent LiCoO2 cathodes by medium-temperature carbon reduction roasting

    + Author Affiliations
      Abstract
    • Lithium recovery from spent lithium-ion batteries (LIBs) have attracted extensive attention due to the skyrocketing price of lithium. The medium-temperature carbon reduction roasting was proposed to preferential selective extraction of lithium from spent LiCoO2 (LCO) cathodes to overcome the incomplete recovery and loss of lithium during the recycling process. The LCO layered structure was destroyed and lithium was completely converted into water-soluble Li2CO3 under a suitable temperature to control the reduced state of the cobalt oxide. The Co metal agglomerates generated during medium-temperature carbon reduction roasting were broken by wet grinding and ultrasonic crushing to release the entrained lithium. The results showed that 99.10% of the whole lithium could be recovered as Li2CO3 with a purity of 99.55%. This work provided a new perspective on the preferentially selective extraction of lithium from spent lithium batteries.
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