对比溶胶–凝胶法和静电纺丝法制备的混合P2/O′3型层状镍锰酸钠正极材料的结构和电化学性能：Na过剩量的影响

Thongsuk Sichumsaeng; Atchara Chinnakorn; Ornuma Kalawa; Jintara Padchasri; Pinit Kidkhunthod; and Santi Maensiri

doi:10.1007/s12613-023-2702-x

Volume 30 Issue 10

Oct. 2023

Turn off MathJax

图(7) / 表(1)

数据统计

计量

文章访问数: 344
HTML全文浏览量: 133
PDF下载量: 32
被引次数: 0

文章导航 > 矿物冶金与材料学报（英文） > 2023 > 30(10): 1887-1896

Thongsuk Sichumsaeng, Atchara Chinnakorn, Ornuma Kalawa, Jintara Padchasri, Pinit Kidkhunthod, and Santi Maensiri, Comparative structural and electrochemical properties of mixed P2/O′3-layered sodium nickel manganese oxide prepared by sol–gel and electrospinning methods: Effect of Na-excess content, Int. J. Miner. Metall. Mater., 30(2023), No. 10, pp. 1887-1896. https://doi.org/10.1007/s12613-023-2702-x

Cite this article as:

Thongsuk Sichumsaeng, Atchara Chinnakorn, Ornuma Kalawa, Jintara Padchasri, Pinit Kidkhunthod, and Santi Maensiri, Comparative structural and electrochemical properties of mixed P2/O′3-layered sodium nickel manganese oxide prepared by sol–gel and electrospinning methods: Effect of Na-excess content, Int. J. Miner. Metall. Mater., 30(2023), No. 10, pp. 1887-1896. https://doi.org/10.1007/s12613-023-2702-x

Citation:

PDF( 10442 KB)

引用本文 PDF XML SpringerLink

研究论文

对比溶胶–凝胶法和静电纺丝法制备的混合P2/O′3型层状镍锰酸钠正极材料的结构和电化学性能：Na过剩量的影响

1)
School of Physics, Institute of Science, Suranaree University of Technology, Nakhon Ratchasima 30000, Thailand
2)
SUT CoE on Advanced Functional Materials, Suranaree University of Technology, Nakhon Ratchasima 30000, Thailand
3)
Research Network NANOTEC-SUT on Advanced Nanomaterials and Characterization, Suranaree University of Technology, Nakhon Ratchasima 30000, Thailand
4)
Synchrotron Light Research Institute (Public Organization), 111 University Avenue, Muang District, Nakhon Ratchasima 30000, Thailand

通讯作者:
and Santi Maensiri E-mail: santimaensiri@gmail.com

关键词:

Research Article

Comparative structural and electrochemical properties of mixed P2/O′3-layered sodium nickel manganese oxide prepared by sol–gel and electrospinning methods: Effect of Na-excess content

+ Author Affiliations

1)
School of Physics, Institute of Science, Suranaree University of Technology, Nakhon Ratchasima 30000, Thailand
2)
SUT CoE on Advanced Functional Materials, Suranaree University of Technology, Nakhon Ratchasima 30000, Thailand
3)
Research Network NANOTEC-SUT on Advanced Nanomaterials and Characterization, Suranaree University of Technology, Nakhon Ratchasima 30000, Thailand
4)
Synchrotron Light Research Institute (Public Organization), 111 University Avenue, Muang District, Nakhon Ratchasima 30000, Thailand

All authors confirm that they have no competing interests or financial ties that could influence the outcomes or interpretation of this research.
The online version contains supplementary material available at https://doi.org/10.1007/s12613-023-2702-x

Corresponding author:
Santi Maensiri E-mail: santimaensiri@gmail.com
Received: 12 January 2023; Revised: 4 July 2023; Accepted: 5 July 2023; Available online: 7 July 2023

Abstract

Abstract

The effect of Na-excess content in the precursor on the structural and electrochemical performances of sodium nickel manganese oxide (NNMO) prepared by sol–gel and electrospinning methods is investigated in this paper. X-ray diffraction results of the prepared NNMO without adding Na-excess content indicate sodium loss, while the mixed phase of P2/O′3-type layered NNMO presented after adding Na-excess content. Compared with the sol–gel method, the secondary phase of NiO is more suppressed by using the electrospinning method, which is further confirmed by field emission scanning electron microscope images. N₂ adsorption–desorption isotherms show no remarkably difference in specific surface areas between different preparation methods and Na-excess contents. The analysis of X-ray absorption near edge structure indicates that the oxidation states of Ni and Mn are +2 and +4, respectively. For the electrochemical properties, superior electrochemical performance is observed in the NNMO electrode with a low Na-excess content of 5wt%. The highest specific capacitance is 36.07 F·g⁻¹ at 0.1 A·g⁻¹ in the NNMO electrode prepared by using the sol–gel method. By contrast, the NNMO electrode prepared using the electrospinning method with decreased Na-excess content shows excellent cycling stability of 100% after charge–discharge measurements for 300 cycles. Therefore, controlling the Na excess in the precursor together with the preparation method is important for improving the electrochemical performance of Na-based electrode materials in supercapacitors.
- sodium nickel manganese oxide;
- mixed P2/O′3-type;
- Na-excess content;
- sol–gel method;
- electrospinning method;
- electrochemical properties

FullText(HTML)

Supplements(1)

Supplementary Information-10.1007s12613-023-2702.docx

References(39)

References

[1]	Z. Cheng, H. Pan, F. Li, et al., Achieving long cycle life for all-solid-state rechargeable Li-I2 battery by a confined dissolution strategy, Nat. Commun., 13(2022), art. No. 125. doi: 10.1038/s41467-021-27728-0
[2]	H.H. Sun, U.H. Kim, J.H. Park, et al., Transition metal-doped Ni-rich layered cathode materials for durable Li-ion batteries, Nat. Commun., 12(2021), art. No. 6552. doi: 10.1038/s41467-021-26815-6
[3]	M.Z. Chen, Y.Y. Zhang, G.C. Xing, and Y.X. Tang, Building high power density of sodium-ion batteries: Importance of multidimensional diffusion pathways in cathode materials, Front. Chem., 8(2020), art. No. 152. doi: 10.3389/fchem.2020.00152
[4]	K. Liu, Y.Y. Liu, D.C. Lin, A. Pei, and Y. Cui, Materials for lithium-ion battery safety, Sci. Adv., 4(2018), No. 6, art. No. eaas9820. doi: 10.1126/sciadv.aas9820
[5]	L.N. Chen, Y.M. Zhang, C.Y. Hao, et al., Interlayer engineering of K_xMnO₂ enables superior alkali metal ion storage for advanced hybrid capacitors, ChemElectroChem, 9(2022), No. 12, art. No. e202200059. doi: 10.1002/celc.202200059
[6]	Z.N. Tian, Y.G. Zou, G. Liu, Y.Z. Wang, J. Yin, J. Ming, and H.N. Alshareef, Electrolyte solvation structure design for sodium ion batteries, Adv. Sci., 9(2022), No. 22, art. No. 2201207. doi: 10.1002/advs.202201207
[7]	E. Gonzalo, M. Zarrabeitia, N.E. Drewett, J.M. López del Amo, and T. Rojo, Sodium manganese-rich layered oxides: Potential candidates as positive electrode for Sodium-ion batteries, Energy Storage Mater., 34(2021), p. 682. doi: 10.1016/j.ensm.2020.10.010
[8]	S. Biswas, A. Chowdhury, and A. Chandra, Performance of Na-ion supercapacitors under non-ambient conditions—From temperature to magnetic field dependent variation in specific capacitance, Front. Mater., 6(2019), art. No. 54. doi: 10.3389/fmats.2019.00054
[9]	A. Chowdhury, S. Biswas, D. Mandal, and A. Chandra, Facile strategy of using conductive additive supported NaMnPO₄ nanoparticles for delivering high performance Na-ion supercapacitors, J. Alloys Compd., 902(2022), art. No. 163733. doi: 10.1016/j.jallcom.2022.163733
[10]	W.N. Xu, J. Wan, W.C. Huo, et al., Sodium ions pre-intercalation stabilized tunnel structure of Na₂Mn₈O₁₆ nanorods for supercapacitors with long cycle life, Chem. Eng. J., 354(2018), p. 1050. doi: 10.1016/j.cej.2018.08.033
[11]	P. Simon and Y. Gogotsi, Perspectives for electrochemical capacitors and related devices, Nat. Mater., 19(2020), No. 11, p. 1151. doi: 10.1038/s41563-020-0747-z
[12]	Q.H. Shi, R.J. Qi, X.C. Feng, et al., Niobium-doped layered cathode material for high-power and low-temperature sodium-ion batteries, Nat. Commun., 13(2022), art. No. 3205. doi: 10.1038/s41467-022-30942-z
[13]	B. Hu, F.S. Geng, C. Zhao, et al., Deciphering the origin of high electrochemical performance in a novel Ti-substituted P2/O3 biphasic cathode for sodium-ion batteries, ACS Appl. Mater. Interfaces, 12(2020), No. 37, p. 41485. doi: 10.1021/acsami.0c11427
[14]	K.Z. Jiang, X.P. Zhang, H.Y. Li, et al., Suppressed the high-voltage phase transition of P2-type oxide cathode for high-performance sodium-ion batteries, ACS Appl. Mater. Interfaces, 11(2019), No. 16, p. 14848. doi: 10.1021/acsami.9b03326
[15]	M. Keller, D. Buchholz, and S. Passerini, Layered Na-ion cathodes with outstanding performance resulting from the synergetic effect of mixed P- and O-type phases, Adv. Energy Mater., 6(2016), No. 3, art. No. 1501555. doi: 10.1002/aenm.201501555
[16]	Z.G. Liu, K.Z. Jiang, S.Y. Chu, et al., Integrating P2 into O′3 toward a robust Mn-based layered cathode for sodium-ion batteries, J. Mater. Chem. A, 8(2020), No. 45, p. 23820. doi: 10.1039/D0TA08383F
[17]	G.K. Veerasubramani, Y. Subramanian, M.S. Park, et al., Enhanced sodium-ion storage capability of P2/O3 biphase by Li-ion substitution into P2-type Na_0.5Fe_0.5Mn_0.5O₂ layered cathode, Electrochim. Acta, 296(2019), p. 1027. doi: 10.1016/j.electacta.2018.11.160
[18]	S.H. Guo, P. Liu, H.J. Yu, et al., A layered P2- and O₃-Type composite as a high-energy cathode for rechargeable sodium-ion batteries, Angew. Chem., 127(2015), No. 20, p. 5992. doi: 10.1002/ange.201411788
[19]	F. Fu, X. Liu, X.G. Fu, et al., Entropy and crystal-facet modulation of P2-type layered cathodes for long-lasting sodium-based batteries, Nat. Commun., 13(2022), art. No. 2826. doi: 10.1038/s41467-022-30113-0
[20]	B. Pandit, S.R. Rondiya, N.Y. Dzade, et al., High stability and long cycle life of rechargeable sodium-ion battery using manganese oxide cathode: A combined density functional theory (DFT) and experimental study, ACS Appl. Mater. Interfaces, 13(2021), No. 9, p. 11433. doi: 10.1021/acsami.0c21081
[21]	B. Qiu, J. Wang, Y.G. Xia, et al., Effects of Na⁺ contents on electrochemical properties of Li_1.2Ni_0.13Co_0.13Mn_0.54O₂ cathode materials, J. Power Sources, 240(2013), p. 530. doi: 10.1016/j.jpowsour.2013.04.047
[22]	Q. Huang, P.G. He, L. Xiao, et al., Effect of sodium content on the electrochemical performance of Li-substituted, manganese-based, sodium-ion layered oxide cathodes, ACS Appl. Mater. Interfaces, 12(2020), No. 2, p. 2191. doi: 10.1021/acsami.9b12984
[23]	L.F. Yang, C. Chen, S. Xiong, et al., Multiprincipal component P2-Na_0.6(Ti_0.2Mn_0.2Co_0.2Ni_0.2Ru_0.2)O₂ as a high-rate cathode for sodium-ion batteries, JACS Au, 1(2021), No. 1, p. 98. doi: 10.1021/jacsau.0c00002
[24]	D.D. Yuan, Y.X. Wang, Y.L. Cao, X.P. Ai, and H.X. Yang, Improved electrochemical performance of Fe-substituted NaNi_0.5Mn_0.5O₂ cathode materials for sodium-ion batteries, ACS Appl. Mater. Interfaces, 7(2015), No. 16, p. 8585. doi: 10.1021/acsami.5b00594
[25]	V. Petříček, M. Dušek, and L. Palatinus, Crystallographic computing system JANA2006: General features, Z. Kristallogr., 229(2014), No. 5, p. 345.
[26]	L.F. Pfeiffer, N. Jobst, C. Gauckler, et al., Layered P2-Na_xMn_3/4Ni_1/4O₂ cathode materials for sodium-ion batteries: Synthesis, electrochemistry and influence of ambient storage, Front. Energy Res., 10(2022), art. No. 910842. doi: 10.3389/fenrg.2022.910842
[27]	C.J. Zhou, L.C. Yang, C.G. Zhou, et al., Co-substitution enhances the rate capability and stabilizes the cyclic performance of O3-Type cathode NaNi_0.45–xMn_0.25Ti_0.3Co_xO₂ for sodium-ion storage at high voltage, ACS Appl. Mater. Interfaces, 11(2019), No. 8, p. 7906. doi: 10.1021/acsami.8b17945
[28]	Z.J. Huang, Z.X. Wang, X.B. Zheng, et al., Structural and electrochemical properties of Mg-doped nickel based cathode materials LiNi_0.6Co_0.2Mn_0.2−xMg_xO₂ for lithium ion batteries, RSC Adv., 5(2015), No. 108, p. 88773. doi: 10.1039/C5RA16633K
[29]	L.G. Wang, J.J. Wang, X.Y. Zhang, et al., Unravelling the origin of irreversible capacity loss in NaNiO₂ for high voltage sodium ion batteries, Nano Energy, 34(2017), p. 215. doi: 10.1016/j.nanoen.2017.02.046
[30]	R.B. Dang, M.M. Chen, Q. Li, et al., Na⁺-conductive Na₂Ti₃O₇-modified P2-type Na_2/3Ni_1/3Mn_2/3O₂ via a smart in situ coating approach: Suppressing Na⁺/vacancy ordering and P2–O2 phase transition, ACS Appl. Mater. Interfaces, 11(2019), No. 1, p. 856. doi: 10.1021/acsami.8b17976
[31]	G.X. Wang, W. Xiao, and J.G. Yu, High-efficiency dye-sensitized solar cells based on electrospun TiO₂ multi-layered composite film photoanodes, Energy, 86(2015), p. 196. doi: 10.1016/j.energy.2015.03.127
[32]	F. Zhang, H.C. Liu, Z.F. Wu, et al., Polyacrylamide gel-derived nitrogen-doped carbon foam yields high performance in supercapacitor electrodes, ACS Appl. Energy Mater., 4(2021), No. 7, p. 6719. doi: 10.1021/acsaem.1c00777
[33]	T. Risthaus, L.F. Chen, J. Wang, et al., P3 Na_0.9Ni_0.5Mn_0.5O₂ cathode material for sodium ion batteries, Chem. Mater., 31(2019), No. 15, p. 5376. doi: 10.1021/acs.chemmater.8b03270
[34]	L.Q. Mai, H. Li, Y.L. Zhao, et al., Fast ionic diffusion-enabled nanoflake electrode by spontaneous electrochemical pre-intercalation for high-performance supercapacitor, Sci. Rep., 3(2013), art. No. 1718. doi: 10.1038/srep01718
[35]	A. Singh and A. Chandra, Enhancing specific energy and power in asymmetric supercapacitors - A synergetic strategy based on the use of redox additive electrolytes, Sci. Rep., 6(2016), art. No. 25793. doi: 10.1038/srep25793
[36]	S. Birgisson, T.L. Christiansen, and B.B. Iversen, Exploration of phase compositions, crystal structures, and electrochemical properties of Na_xFe_yMn_1–yO₂ sodium ion battery materials, Chem. Mater., 30(2018), No. 19, p. 6636. doi: 10.1021/acs.chemmater.8b01566
[37]	M.D. Jiang, G.N. Qian, X.Z. Liao, et al., Revisiting the capacity-fading mechanism of P2-type sodium layered oxide cathode materials during high-voltage cycling, J. Energy Chem., 69(2022), p. 16. doi: 10.1016/j.jechem.2022.01.010
[38]	Q.L. Fan, K.J. Lin, S.D. Yang, et al., Constructing effective TiO₂ nano-coating for high-voltage Ni-rich cathode materials for lithium ion batteries by precise kinetic control, J. Power Sources, 477(2020), art. No. 228745. doi: 10.1016/j.jpowsour.2020.228745
[39]	Y.J. Zhang, K. Du, Y.B. Cao, et al., Hydrothermal preparing agglomerate LiNi_0.8Co_0.1Mn_0.1O₂ cathode material with submicron primary particle for alleviating microcracks, J. Power Sources, 477(2020), art. No. 228701. doi: 10.1016/j.jpowsour.2020.228701

Relative Articles

Cited By

Proportional views

数据统计

姓名
邮箱
手机号码
标题
留言内容
验证码

留言板

数据统计

分享

计量

对比溶胶–凝胶法和静电纺丝法制备的混合P2/O′3型层状镍锰酸钠正极材料的结构和电化学性能：Na过剩量的影响

Comparative structural and electrochemical properties of mixed P2/O′3-layered sodium nickel manganese oxide prepared by sol–gel and electrospinning methods: Effect of Na-excess content

Abstract

References

数据统计

Catalog