含橄榄石类铜镍渣基胶凝材料二氧化碳矿化潜力探究

王倩倩; 姚泽群; 郭利杰; 沈晓冬

doi:10.1007/s12613-023-2743-1

Volume 31 Issue 3

Mar. 2024

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文章导航 > 矿物冶金与材料学报（英文） > 2024 > 31(3): 562-573

Qianqian Wang, Zequn Yao, Lijie Guo, and Xiaodong Shen, Exploring the potential of olivine-containing copper–nickel slag for carbon dioxide mineralization in cementitious materials, Int. J. Miner. Metall. Mater., 31(2024), No. 3, pp. 562-573. https://doi.org/10.1007/s12613-023-2743-1

Cite this article as:

Qianqian Wang, Zequn Yao, Lijie Guo, and Xiaodong Shen, Exploring the potential of olivine-containing copper–nickel slag for carbon dioxide mineralization in cementitious materials, Int. J. Miner. Metall. Mater., 31(2024), No. 3, pp. 562-573. https://doi.org/10.1007/s12613-023-2743-1

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研究论文

含橄榄石类铜镍渣基胶凝材料二氧化碳矿化潜力探究

1)
南京工业大学材料科学与工程学院, 南京 211816, 中国
2)
材料化学工程国家重点实验室, 南京 211816, 中国
3)
矿冶科技集团有限公司, 北京 100160, 中国

通讯作者:
王倩倩 E-mail: qqwang@njtech.edu.cn

郭利杰 E-mail: guolijie@bgrimm.com

文章亮点

(1) 系统采用不同活化方式活化铜镍渣并制备高掺量铜镍渣基胶凝材料

(2) 探讨了不同有机酸对铜镍渣中橄榄石矿物相的溶解效率及反应机理

(3) 研究了不同碳化工艺条件下高掺量铜镍渣基胶凝材料的固碳潜力及产物演变过程

中文摘要

富含橄榄石矿物相的水淬铜镍冶金渣具有制备二氧化碳矿化胶凝材料的潜力。本文采用不同的化学活化方法制备了大掺量铜镍渣基胶凝材料(CNCM)，以提高其水化反应性和二氧化碳矿化能力，并研究了养护龄期和碳化反应工艺条件对于其固碳及力学性能的影响。基于热重–差示扫描量热法和X射线衍射法评估了CNCM的二氧化碳吸附量和碳化产物。利用背散射电子成像（BSE）和能谱X射线分析技术对碳化CNCM试块的微观结构进行了研究。研究结果表明，经过3天水养护的CNCM样品在80°C和72小时的碳化反应条件下，其二氧化碳封存量最高，为8.51wt%，同时抗压强度为39.07 MPa。这一结果表明，1吨这种CNCM可以封存85.1公斤的CO₂并具有高抗压强度。尽管柠檬酸的添加并未改善强度发展，但在相同的碳化条件下有利于增加二氧化碳在硬化体的扩散和吸附量。这项工作为利用大量含有橄榄石矿物的冶金渣制备二氧化碳矿化胶凝材料提供了指导。

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Research Article

Exploring the potential of olivine-containing copper–nickel slag for carbon dioxide mineralization in cementitious materials

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Abstract

Abstract

Water-quenched copper-nickel metallurgical slag enriched with olivine minerals exhibits promising potential for the production of CO₂-mineralized cementitious materials. In this work, copper-nickel slag-based cementitious material (CNCM) was synthesized by using different chemical activation methods to enhance its hydration reactivity and CO₂ mineralization capacity. Different water curing ages and carbonation conditions were explored related to their carbonation and mechanical properties development. Meanwhile, thermogravimetry differential scanning calorimetry and X-ray diffraction methods were applied to evaluate the CO₂ adsorption amount and carbonation products of CNCM. Microstructure development of carbonated CNCM blocks was examined by backscattered electron imaging (BSE) with energy-dispersive X-ray spectrometry. Results showed that among the studied samples, the CNCM sample that was subjected to water curing for 3 d exhibited the highest CO₂ sequestration amount of 8.51wt% at 80°C and 72 h while presenting the compressive strength of 39.07 MPa. This result indicated that 1 t of this CNCM can sequester 85.1 kg of CO₂ and exhibit high compressive strength. Although the addition of citric acid did not improve strength development, it was beneficial to increase the CO₂ diffusion and adsorption amount under the same carbonation conditions from BSE results. This work provides guidance for synthesizing CO₂-mineralized cementitious materials using large amounts of metallurgical slags containing olivine minerals.
- copper–nickel slag;
- fayalite;
- CO₂ sequestration;
- cementitious material;
- admixtures;
- carbonation conditions

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References(46)

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含橄榄石类铜镍渣基胶凝材料二氧化碳矿化潜力探究

文章亮点

中文摘要

Exploring the potential of olivine-containing copper–nickel slag for carbon dioxide mineralization in cementitious materials

Abstract

References

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