元素粉末反应合成制备多孔TiFe<sub>2</sub>金属间化合物

赵乾; 何真丽; 贺跃辉; 邱悦; 王重贺; 江垚

doi:10.1007/s12613-023-2748-9

Volume 31 Issue 4

Apr. 2024

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文章导航 > 矿物冶金与材料学报（英文） > 2024 > 31(4): 764-772

Qian Zhao, Zhenli He, Yuehui He, Yue Qiu, Zhonghe Wang, and Yao Jiang, Porous TiFe₂ intermetallic compound fabricated via elemental powder reactive synthesis, Int. J. Miner. Metall. Mater., 31(2024), No. 4, pp. 764-772. https://doi.org/10.1007/s12613-023-2748-9

Cite this article as:

Qian Zhao, Zhenli He, Yuehui He, Yue Qiu, Zhonghe Wang, and Yao Jiang, Porous TiFe2 intermetallic compound fabricated via elemental powder reactive synthesis, Int. J. Miner. Metall. Mater., 31(2024), No. 4, pp. 764-772. https://doi.org/10.1007/s12613-023-2748-9

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研究论文

元素粉末反应合成制备多孔TiFe₂金属间化合物

中南大学粉末冶金研究院, 粉末冶金国家重点实验室, 长沙 410083, 中国

* 共同第一作者

通讯作者:
江垚 E-mail: jiangyao@csu.edu.cn

文章亮点

(1) 通过元素粉末反应合成法制备了多孔TiFe₂金属间化合物。

(2) 阐明了多孔TiFe₂金属间化合物反应合成过程中的物相演变和孔隙形成机理。

(3) 多孔TiFe₂金属间化合物比多孔316L不锈钢具有更好的抗腐蚀性能。

中文摘要

金属间化合物兼具了陶瓷和传统金属的特点，表现出良好的抗腐蚀性和结构稳定性，在过滤分离领域以及催化领域具有一定的应用潜力。本文通过元素粉末反应合成法制备了多孔TiFe₂金属间化合物，研究了反应合成过程中的物相演变和孔隙形成机理，以及在碱性溶液中的析氢反应。研究结果表明，通过Ti、Fe元素粉末的扩散反应合成了孔隙度为34.4%–56.4%的多孔TiFe₂金属间化合物，孔隙主要是由拱桥效应和Kirkendall效应共同作用产生。多孔TiFe₂金属间化合物比316L不锈钢具有更好的抗腐蚀性能。多孔TiFe₂金属间化合物作为阴极在10 mA⸱cm⁻²和100 mA⸱cm⁻²电流密度下的过电位分别为220.6 mV和295.6 mV，具有较好的催化性能。因此，合成具有可控孔结构和优异抗腐蚀性能的多孔Fe基金属间化合物在过滤分离领域具有一定的应用潜力。

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Research Article

Porous TiFe₂ intermetallic compound fabricated via elemental powder reactive synthesis

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Abstract

Abstract

Porous intermetallics show potential in the field of filtration and separation as well as in the field of catalysis. Herein, porous TiFe₂ intermetallics were fabricated by the reactive synthesis of elemental powders. The phase transformation and pore formation of porous TiFe₂ intermetallics were investigated, and its corrosion behavior and hydrogen evolution reaction (HER) performance in alkali solution were studied. Porous TiFe₂ intermetallics with porosity in the range of 34.4%–56.4% were synthesized by the diffusion reaction of Ti and Fe elements, and the pore formation of porous TiFe₂ intermetallic compound is the result of a combination of the bridging effect and the Kirkendall effect. The porous TiFe₂ samples exhibit better corrosion resistance compared with porous 316L stainless steel, which is related to the formation of uniform nanosheets on the surface that hinder further corrosion, and porous TiFe₂ electrode shows the overpotential of 220.6 and 295.6 mV at 10 and 100 mA·cm⁻², suggesting a good catalytic performance. The synthesized porous Fe-based intermetallic has a controllable pore structure as well as excellent corrosion resistance, showing its potential in the field of filtration and separation.
- TiFe₂ intermetallic compound;
- porous materials;
- reactive synthesis;
- corrosion behavior;
- hydrogen evolution reaction

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元素粉末反应合成制备多孔TiFe₂金属间化合物

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Porous TiFe₂ intermetallic compound fabricated via elemental powder reactive synthesis

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元素粉末反应合成制备多孔TiFe2金属间化合物

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Porous TiFe2 intermetallic compound fabricated via elemental powder reactive synthesis

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元素粉末反应合成制备多孔TiFe₂金属间化合物

Porous TiFe₂ intermetallic compound fabricated via elemental powder reactive synthesis