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Volume 31 Issue 4
Apr.  2024
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文章导航 >  矿物冶金与材料学报（英文）  > 2024  >  31(4): 697-711
Baosheng Liu, Jiali Wei, Shaohua Zhang, Yuezhong Zhang, Pengpeng Wu, Daqing Fang,  and Guorui Ma, Microstructures, corrosion behavior and mechanical properties of as-cast Mg–6Zn–2X(Fe/Cu/Ni) alloys for plugging tool applications, Int. J. Miner. Metall. Mater., 31(2024), No. 4, pp. 697-711. https://doi.org/10.1007/s12613-023-2775-6
Cite this article as:
Baosheng Liu, Jiali Wei, Shaohua Zhang, Yuezhong Zhang, Pengpeng Wu, Daqing Fang,  and Guorui Ma, Microstructures, corrosion behavior and mechanical properties of as-cast Mg–6Zn–2X(Fe/Cu/Ni) alloys for plugging tool applications, Int. J. Miner. Metall. Mater., 31(2024), No. 4, pp. 697-711. https://doi.org/10.1007/s12613-023-2775-6
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研究论文

用作封堵工具的铸态Mg–6Zn–2X（Fe/Cu/Ni）合金的微观组织、腐蚀行为和力学性能

  • 1)

    太原科技大学材料科学与工程学院，太原 030024，中国

  • 2)

    西安交通大学材料力学行为国家重点实验室, 西安 710049, 中国

  • 3)

    中国科学院珠海先进技术研究院智能装备研发中心, 珠海519080, 中国

  • 4)

    珠海鼎镁医疗科技有限公司, 珠海519080, 中国


  • 通讯作者:

    刘宝胜    E-mail: liubaosheng@tyust.edu.cn

文章亮点

  • (1) 系统地比较了添加溶解元素（Fe/Cu/Ni）的Mg合金。
  • (2) Fe的加入改善了Mg–Zn基合金的力学性能。
  • (3) Mg–6Zn–2Ni合金在3.0 wt%的KCl溶液中降解速率最快，为932.9 mm/a。
  • 通过半连续铸造制备了 Mg–6Zn–2X(Fe/Cu/Ni)合金，以确定一种适合用于压裂球的可降解镁（Mg）合金。对比分析了Cu和Ni的添加的影响，导致了晶粒细化和电偶腐蚀位点的形成。扫描电子显微镜表明，析出相聚集在晶界处，形成半连续的网络结构，其结构加速了 Mg–6Zn–2Cu 和 Mg–6Zn–2Ni 合金腐蚀过程中电解质离子的渗透。在 Mg–6Zn–2Fe 中观察到了点蚀现象，而在 Mg–6Zn–2Cu 和 Mg–6Zn–2Ni 合金中，电偶腐蚀被确定为主要机制。在试验合金中，Mg–6Zn–2Ni合金的腐蚀速率最高（约 932.9 mm/a）。力学测试表明，Mg–6Zn–2Ni 合金具有合适的抗压强度，是可降解压裂球的潜在候选材料，有效解决了压裂应用中强度和降解率的平衡难题。
    • Research Article

    Microstructures, corrosion behavior and mechanical properties of as-cast Mg–6Zn–2X(Fe/Cu/Ni) alloys for plugging tool applications

    + Author Affiliations
      Abstract
    • Mg–6Zn–2X(Fe/Cu/Ni) alloys were prepared through semi-continuous casting, with the aim of identifying a degradable magnesium (Mg) alloy suitable for use in fracturing balls. A comparative analysis was conducted to assess the impacts of adding Cu and Ni, which result in finer grains and the formation of galvanic corrosion sites. Scanner electronic microscopy examination revealed that precipitated phases concentrated at grain boundaries, forming a semi-continuous network structure that facilitated corrosion penetration in Mg–6Zn–2Cu and Mg–6Zn–2Ni alloys. Pitting corrosion was observed in Mg–6Zn–2Fe, while galvanic corrosion was identified as the primary mechanism in Mg–6Zn–2Cu and Mg–6Zn–2Ni alloys. Among the tests, the Mg–6Zn–2Ni alloy exhibited the highest corrosion rate (approximately 932.9 mm/a) due to its significant potential difference. Mechanical testing showed that Mg–6Zn–2Ni alloy possessed suitable ultimate compressive strength, making it a potential candidate material for degradable fracturing balls, effectively addressing the challenges of balancing strength and degradation rate in fracturing applications.
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    • [1]
      Z.Y. Xu, G. Agrawal, and B.J. Salinas, Smart nanostructured materials deliver high reliability completion tools for gas shale fracturing, [in] the SPE Annual Technical Conference and Exhibition, Denver, Colorado, 2011, art. No. SPE-146586-MS.
      [2]
      D. Themig, New technologies enhance efficiency of horizontal, multistage fracturing, J. Petrol. Technol., 63(2011), No. 4, p. 26. doi: 10.2118/0411-0026-JPT
      [3]
      D.R. Watson, D.G. Durst, T. Harris, and J.D. Contreras, One-trip multistage completion technology for unconventional gas formations, [in] the SPE Unconventional Resources Conference /Gas Technology Symposium, Calgary, Alberta, 2008, art. No. SPE-114973-MS.
      [4]
      C. Franco, R. Solares, H. Marri, and H. Hussain, The use of stagefrac new technology to complete and stimulate horizontal wells: Field case, [in] the SPE Kingdom of Saudi Arabia Annual Technical Symposium and Exhibition, Al-Khobar, Saudi Arabia, 2008, art. No. SPE-120806-MS.
      [5]
      N.J. Jin and Q.J. Zeng, Dissolvable tools in multistage stimulation, [in] the SPE /IATMI Asia Pacific Oil & Gas Conference and Exhibition, Jakarta, Indonesia, 2017, art. No. SPE-186184-MS.
      [6]
      D.H. Xiao, Z.W. Geng, L. Chen, et al., Effects of alloying elements on microstructure and properties of magnesium alloys for tripling ball, Metall. Mater. Trans. A, 46(2015), No. 10, p. 4793. doi: 10.1007/s11661-015-3053-7
      [7]
      D. Kumar, E.D. Hernaez, J.S. Sanchez, and Z.Y. Xu, Temporary coating for dissolving frac-balls used in multi-stage fracturing systems, [in] the Offshore Technology Conference, Houston, Texas, 2018, art. No. OTC-28862-MS.
      [8]
      W.X. Li, Magnesium and Magnesium Alloys, Central South University Press, Changsha, 2005, p. 501.
      [9]
      H. Xie, G.H. Wu, X.L. Zhang, et al., Microstructural evolution and mechanical performance of cast Mg–3Nd–0.2Zn–0.5Zr alloy with Y additions, Trans. Nonferrous Met. Soc. China, 32(2022), No. 10, p. 3222. doi: 10.1016/S1003-6326(22)66015-1
      [10]
      Z.W. Geng, D.H. Xiao, and L. Chen, Microstructure, mechanical properties, and corrosion behavior of degradable Mg–Al–Cu–Zn–Gd alloys, J. Alloys Compd., 686(2016), p. 145. doi: 10.1016/j.jallcom.2016.05.288
      [11]
      H.C. Chen, T.C. Xie, Q. Liu, et al., Mechanism and prediction of aging time related thermal conductivity evolution of Mg–Zn alloys, J. Alloys Compd., 930(2023), art. No. 167392. doi: 10.1016/j.jallcom.2022.167392
      [12]
      M. Yin, J.L. Sun, T.Y. Bao, et al., Research progress in effect of alloying elements on corrosion resistance of magnesium alloys, J. Mater. Eng., 49(2021), No. 12, p. 28. doi: 10.11868/j.issn.1001-4381.2021.000289
      [13]
      D. Bairagi, P. Duley, M. Paliwal, and S. Mandal, Influence of second phase precipitates on mechanical and in-vitro corrosion behaviour of Mg–4Zn–0.5Ca–0.8Mn alloy in optimum homogenized conditions, J. Magnes. Alloys, 11(2023), No. 4, p. 1343. doi: 10.1016/j.jma.2022.11.011
      [14]
      L. Chen, Z. Wu, D.H. Xiao, Z.W. Geng, and P.F. Zhou, Effects of copper on the microstructure and properties of Mg–17Al–3Zn alloys, Mater. Corros., 66(2015), No. 10, p. 1159. doi: 10.1002/maco.201408090
      [15]
      H. Pan, F. Pan, X. Wang, et al., High conductivity and high strength Mg–Zn–Cu alloy, Mater. Sci. Technol., 30(2014), No. 7, p. 759. doi: 10.1179/1743284713Y.0000000400
      [16]
      H.Y. Niu, K.K. Deng, K.B. Nie, F.F. Cao, X.C. Zhang, and W.G. Li, Microstructure, mechanical properties and corrosion properties of Mg–4Zn– xNi alloys for degradable fracturing ball applications, J. Alloys Compd., 787(2019), p. 1290. doi: 10.1016/j.jallcom.2019.02.089
      [17]
      H.R. Bakhsheshi-Rad, E. Hamzah, A. Fereidouni-Lotfabadi, et al., Microstructure and bio-corrosion behavior of Mg–Zn and Mg–Zn–Ca alloys for biomedical applications, Mater. Corros., 65(2014), No. 12, p. 1178. doi: 10.1002/maco.201307588
      [18]
      B.S. Liu, Y.F. Kuang, D.Q. Fang, Y.S. Chai, and Y.Z. Zhang, Microstructure and properties of hot extruded Mg–3Zn–Y– xCu ( x = 0, 1, 3, 5) alloys, Int. J. Mater. Res., 108(2017), No. 4, p. 262. doi: 10.3139/146.111476
      [19]
      Y.Z. Zhang, X.Y. Wang, Y.F. Kuang, B.S. Liu, K.W. Zhang, and D.Q. Fang, Enhanced mechanical properties and degradation rate of Mg–3Zn–1Y based alloy by Cu addition for degradable fracturing ball applications, Mater. Lett., 195(2017), p. 194. doi: 10.1016/j.matlet.2017.02.024
      [20]
      C.J. Boehlert and K. Knittel, The microstructure, tensile properties, and creep behavior of Mg–Zn alloys containing 0–4.4wt.% Zn, Mater. Sci. Eng. A, 417(2006), No. 1-2, p. 315. doi: 10.1016/j.msea.2005.11.006
      [21]
      W.T. Liu, B.S. Liu, S.H. Zhang, et al., Microstructure and mechanical properties of extruded Mg–6Al–2X (X = Cu/Ni/Fe) alloy used degradable bridge plugs, Adv. Compos. Hybrid Mater., 6(2023), No. 5, art. No. 181. doi: 10.1007/s42114-023-00753-x
      [22]
      S.Y. Zhong, D.F. Zhang, Y.Q. Wang, et al., Microstructures, mechanical properties and degradability of Mg–2Gd–0.5(Cu/Ni) alloys: A comparison study, J. Mater. Sci. Technol., 128(2022), p. 44. doi: 10.1016/j.jmst.2022.03.027
      [23]
      Z.M. Shi and A. Atrens, An innovative specimen configuration for the study of Mg corrosion, Corros. Sci., 53(2011), No. 1, p. 226. doi: 10.1016/j.corsci.2010.09.016
      [24]
      Y. Dai, X.H. Chen, T. Yan, et al., Improved corrosion resistance in AZ61 magnesium alloys induced by impurity reduction, Acta Metall. Sin. Engl. Lett., 33(2020), No. 2, p. 225. doi: 10.1007/s40195-019-00914-2
      [25]
      K. Gusieva, C.H.J. Davies, J.R. Scully, and N. Birbilis, Corrosion of magnesium alloys: The role of alloying, Int. Mater. Rev., 60(2015), No. 3, p. 169. doi: 10.1179/1743280414Y.0000000046
      [26]
      M. Lotfpour, M. Emamy, C. Dehghanian, and K. Tavighi, Influence of Cu addition on the structure, mechanical and corrosion properties of cast Mg–2%Zn alloy, J. Mater. Eng. Perform., 26(2017), No. 5, p. 2136. doi: 10.1007/s11665-017-2672-0
      [27]
      M. Lotfpour, C. Dehghanian, M. Emamy, et al., In- vitro corrosion behavior of the cast and extruded biodegradable Mg–Zn–Cu alloys in simulated body fluid (SBF), J. Magnes. Alloys, 9(2021), No. 6, p. 2078. doi: 10.1016/j.jma.2021.01.002
      [28]
      P. Wan, X.M. Fan, S.Y. Hu, and H.Y. Wen, Harmful Effect of Fe on Properties of Magnesium Alloy and Neutr alizing Methods, Foundry Equip. Technol. 1(2008), No. 1, p. 11.
      [29]
      D.D. Gu, J. Peng, J.W. Wang, Z.T. Liu, and F.S. Pan, Effect of Mn modification on the corrosion susceptibility of Mg–Mn alloys by magnesium scrap, Acta Metall. Sin. Engl. Lett., 34(2021), No. 1, p. 1. doi: 10.1007/s40195-020-01058-4
      [30]
      M. Esmaily, J.E. Svensson, S. Fajardo, et al., Fundamentals and advances in magnesium alloy corrosion, Prog. Mater. Sci., 89(2017), p. 92. doi: 10.1016/j.pmatsci.2017.04.011
      [31]
      H.R. Bakhsheshi-Rad, E. Hamzah, M. Medraj, et al., Effect of heat treatment on the microstructure and corrosion behaviour of Mg–Zn alloys, Mater. Corros., 65(2014), No. 10, p. 999. doi: 10.1002/maco.201307492
      [32]
      G.L. Song and A. Atrens, Corrosion mechanisms of magnesium alloys, Adv. Eng. Mater., 1(1999), No. 1, p. 11. doi: 10.1002/(SICI)1527-2648(199909)1:1<11::AID-ADEM11>3.0.CO;2-N
      [33]
      X.H. Shao, Z.Q. Yang, and X.L. Ma, Strengthening and toughening mechanisms in Mg–Zn–Y alloy with a long period stacking ordered structure, Acta Mater., 58(2010), No. 14, p. 4760. doi: 10.1016/j.actamat.2010.05.012
      [34]
      C.L. Zhang, F. Zhang, L. Song, R.C. Zeng, S.Q. Li, and E.H. Han, Corrosion resistance of a superhydrophobic surface on micro-arc oxidation coated Mg–Li–Ca alloy, J. Alloys Compd., 728(2017), p. 815. doi: 10.1016/j.jallcom.2017.08.159
      [35]
      Y. Yan, H.W. Cao, Y.J. Kang, et al., Effects of Zn concentration and heat treatment on the microstructure, mechanical properties and corrosion behavior of as-extruded Mg–Zn alloys produced by powder metallurgy, J. Alloys Compd., 693(2017), p. 1277. doi: 10.1016/j.jallcom.2016.10.017
      [36]
      P. Duley, D. Bairagi, L.R. Bairi, T.K. Bandyopadhyay, and S. Mandal, Effect of microstructural evolution and texture change on the in-vitro bio-corrosion behaviour of hard-plate hot forged Mg–4Zn–0.5Ca–0.16Mn (wt%) alloy, Corros. Sci., 192(2021), art. No. 109860. doi: 10.1016/j.corsci.2021.109860
      [37]
      Y. Wang, M. Wei, J.C. Gao, J.Z. Hu, and Y. Zhang, Corrosion process of pure magnesium in simulated body fluid, Mater. Lett., 62(2008), No. 14, p. 2181. doi: 10.1016/j.matlet.2007.11.045
      [38]
      M.E. Orazem, I. Frateur, B. Tribollet, et al., Dielectric properties of materials showing constant-phase-element (CPE) impedance response, J. Electrochem. Soc., 160(2013), No. 6, p. C215. doi: 10.1149/2.033306jes
      [39]
      G.L. Song, A. Atrens, X.L. Wu, and B. Zhang, Corrosion behaviour of AZ21, AZ501 and AZ91 in sodium chloride, Corros. Sci., 40(1998), No. 10, p. 1769. doi: 10.1016/S0010-938X(98)00078-X
      [40]
      P.R. Cha, H.S. Han, G.F. Yang, et al., Biodegradability engineering of biodegradable Mg alloys: Tailoring the electrochemical properties and microstructure of constituent phases, Sci. Rep., 3(2013), art. No. 2367. doi: 10.1038/srep02367
      [41]
      Y. Zhang, X.H. Feng, Q.Y. Huang, et al., The corrosion characteristics and mechanism of directionally solidified Mg–3Zn– xCa alloys, J. Magnes. Alloys, 11(2023), No. 10, p. 3673. doi: 10.1016/j.jma.2022.02.010
      [42]
      M.S. Song, R.C. Zeng, Y.F. Ding, et al., Recent advances in biodegradation controls over Mg alloys for bone fracture management: A review, J. Mater. Sci. Technol., 35(2019), No. 4, p. 535. doi: 10.1016/j.jmst.2018.10.008
      [43]
      H.B. Yao, Y. Li, and A.T.S. Wee, An XPS investigation of the oxidation/corrosion of melt-spun Mg, Appl. Surf. Sci., 158(2000), No. 1-2, p. 112. doi: 10.1016/S0169-4332(99)00593-0
      [44]
      J.C. Li, Y.X. Huang, F.F. Wang, X.C. Meng, L. Wan, and Z.B. Dong, Enhanced strength and ductility of friction-stir-processed Mg–6Zn alloys via Y and Zr co-alloying, Mater. Sci. Eng. A, 773(2020), art. No. 138877. doi: 10.1016/j.msea.2019.138877
      [45]
      W. Fu, R.H. Wang, K. Wu, et al., The influences of multiscale second-phase particles on strength and ductility of cast Mg alloys, J. Mater. Sci., 54(2019), No. 3, p. 2628. doi: 10.1007/s10853-018-2980-2
      [46]
      A. Bahmani, S. Arthanari, and K.S. Shin, Formulation of corrosion rate of magnesium alloys using microstructural parameters, J. Magnes. Alloys, 8(2020), No. 1, p. 134. doi: 10.1016/j.jma.2019.12.001
      [47]
      M. Liu, P. Schmutz, P.J. Uggowitzer, G.L. Song, and A. Atrens, The influence of yttrium (Y) on the corrosion of Mg–Y binary alloys, Corros. Sci., 52(2010), No. 11, p. 3687. doi: 10.1016/j.corsci.2010.07.019
      [48]
      H. Pan, K. Pang, F.Z. Cui, et al., Effect of alloyed Sr on the microstructure and corrosion behavior of biodegradable Mg–Zn–Mn alloy in Hanks’ solution, Corros. Sci., 157(2019), p. 420. doi: 10.1016/j.corsci.2019.06.022
      [49]
      Y.Q. Wang, D.F. Zhang, S.Y. Zhong, et al., Effect of minor Ni addition on the microstructure, mechanical properties and corrosion behavior of Mg–2Gd alloy, J. Mater. Res. Technol., 20(2022), p. 3735. doi: 10.1016/j.jmrt.2022.08.051
      [50]
      H.H. Yu, Y.C. Xin, M.Y. Wang, and Q. Liu, Hall-Petch relationship in Mg alloys: A review, J. Mater. Sci. Technol., 34(2018), No. 2, p. 248. doi: 10.1016/j.jmst.2017.07.022
      [51]
      H.B. Yang, Y.F. Chai, B. Jiang, et al., Simultaneous improvements in strength and ductility of as-extruded Mg–1.0Sn–0.5Zn alloy via Ce addition in combination with pre-twining deformation, J. Alloys Compd., 927(2022), art. No. 166879. doi: 10.1016/j.jallcom.2022.166879
      [52]
      Y.F. Chai, B. Jiang, J.F. Song, et al., Effects of Zn and Ca addition on microstructure and mechanical properties of as-extruded Mg–1.0Sn alloy sheet, Mater. Sci. Eng. A, 746(2019), p. 82. doi: 10.1016/j.msea.2019.01.028
      [53]
      Y. Jiang, Y.S. Li, and F. Liu, Microalloying-modulated strength-ductility trade-offs in as-cast Al–Mg–Si–Cu alloys, Mater. Sci. Eng. A, 855(2022), art. No. 143897. doi: 10.1016/j.msea.2022.143897
      [54]
      Y.W. Song, E.H. Han, D.Y. Shan, C.D. Yim, and B.S. You, The role of second phases in the corrosion behavior of Mg–5Zn alloy, Corros. Sci., 60(2012), p. 238. doi: 10.1016/j.corsci.2012.03.030
      [55]
      R. Arrabal, A. Pardo, M.C. Merino, et al., Effect of Nd on the corrosion behaviour of AM50 and AZ91D magnesium alloys in 3.5 wt.% NaCl solution, Corros. Sci., 55(2012), p. 301. doi: 10.1016/j.corsci.2011.10.033
      [56]
      K. Ma, S.J. Liu, C.N. Dai, et al., Effect of Ni on the microstructure, mechanical properties and corrosion behavior of MgGd1Ni x alloys for fracturing ball applications, J. Mater. Sci. Technol., 91(2021), p. 121. doi: 10.1016/j.jmst.2021.02.043
      [57]
      J.H. Jiang, X. Geng, and X.B. Zhang, Mechanical and corrosion properties of Mg–Gd–Cu–Zr alloy for degradable fracturing ball applications, Metals, 13(2023), No. 3, art. No. 446. doi: 10.3390/met13030446
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