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Volume 31 Issue 4
Apr.  2024
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文章导航 >  矿物冶金与材料学报（英文）  > 2024  >  31(4): 697-711
Baosheng Liu, Jiali Wei, Shaohua Zhang, Yuezhong Zhang, Pengpeng Wu, Daqing Fang, and Guorui Ma, Microstructures, corrosion behavior and mechanical properties of as-cast Mg–6Zn–2X(Fe/Cu/Ni) alloys for plugging tool applications, Int. J. Miner. Metall. Mater., 31(2024), No. 4, pp. 697-711. https://doi.org/10.1007/s12613-023-2775-6
Cite this article as:
Baosheng Liu, Jiali Wei, Shaohua Zhang, Yuezhong Zhang, Pengpeng Wu, Daqing Fang, and Guorui Ma, Microstructures, corrosion behavior and mechanical properties of as-cast Mg–6Zn–2X(Fe/Cu/Ni) alloys for plugging tool applications, Int. J. Miner. Metall. Mater., 31(2024), No. 4, pp. 697-711. https://doi.org/10.1007/s12613-023-2775-6
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研究论文

用作封堵工具的铸态Mg–6Zn–2X（Fe/Cu/Ni）合金的微观组织、腐蚀行为和力学性能

  • 1)

    太原科技大学材料科学与工程学院，太原 030024，中国

  • 2)

    西安交通大学材料力学行为国家重点实验室, 西安 710049, 中国

  • 3)

    中国科学院珠海先进技术研究院智能装备研发中心, 珠海519080, 中国

  • 4)

    珠海鼎镁医疗科技有限公司, 珠海519080, 中国


  • 通讯作者:

    刘宝胜    E-mail: liubaosheng@tyust.edu.cn

文章亮点

  • (1) 系统地比较了添加溶解元素（Fe/Cu/Ni）的Mg合金。
  • (2) Fe的加入改善了Mg–Zn基合金的力学性能。
  • (3) Mg–6Zn–2Ni合金在3.0 wt%的KCl溶液中降解速率最快，为932.9 mm/a。
  • 通过半连续铸造制备了 Mg–6Zn–2X(Fe/Cu/Ni)合金，以确定一种适合用于压裂球的可降解镁（Mg）合金。对比分析了Cu和Ni的添加的影响，导致了晶粒细化和电偶腐蚀位点的形成。扫描电子显微镜表明，析出相聚集在晶界处，形成半连续的网络结构，其结构加速了 Mg–6Zn–2Cu 和 Mg–6Zn–2Ni 合金腐蚀过程中电解质离子的渗透。在 Mg–6Zn–2Fe 中观察到了点蚀现象，而在 Mg–6Zn–2Cu 和 Mg–6Zn–2Ni 合金中，电偶腐蚀被确定为主要机制。在试验合金中，Mg–6Zn–2Ni合金的腐蚀速率最高（约 932.9 mm/a）。力学测试表明，Mg–6Zn–2Ni 合金具有合适的抗压强度，是可降解压裂球的潜在候选材料，有效解决了压裂应用中强度和降解率的平衡难题。
    • Research Article

    Microstructures, corrosion behavior and mechanical properties of as-cast Mg–6Zn–2X(Fe/Cu/Ni) alloys for plugging tool applications

    + Author Affiliations
      Abstract
    • Mg–6Zn–2X(Fe/Cu/Ni) alloys were prepared through semi-continuous casting, with the aim of identifying a degradable magnesium (Mg) alloy suitable for use in fracturing balls. A comparative analysis was conducted to assess the impacts of adding Cu and Ni, which result in finer grains and the formation of galvanic corrosion sites. Scanner electronic microscopy examination revealed that precipitated phases concentrated at grain boundaries, forming a semi-continuous network structure that facilitated corrosion penetration in Mg–6Zn–2Cu and Mg–6Zn–2Ni alloys. Pitting corrosion was observed in Mg–6Zn–2Fe, while galvanic corrosion was identified as the primary mechanism in Mg–6Zn–2Cu and Mg–6Zn–2Ni alloys. Among the tests, the Mg–6Zn–2Ni alloy exhibited the highest corrosion rate (approximately 932.9 mm/a) due to its significant potential difference. Mechanical testing showed that Mg–6Zn–2Ni alloy possessed suitable ultimate compressive strength, making it a potential candidate material for degradable fracturing balls, effectively addressing the challenges of balancing strength and degradation rate in fracturing applications.
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