双极板设计对质子交换膜燃料电池和水电解槽中腐蚀、传质和传热的影响：综述

张久宏; 罗谢景; 丁英语; 常璐琦; 董超芳

doi:10.1007/s12613-023-2803-6

Volume 31 Issue 7

Jul. 2024

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文章导航 > 矿物冶金与材料学报（英文） > 2024 > 31(7): 1599-1616

Jiuhong Zhang, Xiejing Luo, Yingyu Ding, Luqi Chang, and Chaofang Dong, Effect of bipolar-plates design on corrosion, mass and heat transfer in proton-exchange membrane fuel cells and water electrolyzers: A review, Int. J. Miner. Metall. Mater., 31(2024), No. 7, pp. 1599-1616. https://doi.org/10.1007/s12613-023-2803-6

Cite this article as:

Jiuhong Zhang, Xiejing Luo, Yingyu Ding, Luqi Chang, and Chaofang Dong, Effect of bipolar-plates design on corrosion, mass and heat transfer in proton-exchange membrane fuel cells and water electrolyzers: A review, Int. J. Miner. Metall. Mater., 31(2024), No. 7, pp. 1599-1616. https://doi.org/10.1007/s12613-023-2803-6

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特约综述

双极板设计对质子交换膜燃料电池和水电解槽中腐蚀、传质和传热的影响：综述

1)
北京科技大学新材料技术研究院教育部腐蚀与防护重点实验室, 北京 100083, 中国
2)
北京材料基因工程高精尖创新中心, 北京 100083, 中国

通讯作者:
董超芳 E-mail: cfdong@ustb.edu.cn

文章亮点

(1) 系统剖析了质子交换膜燃料电池与水电解槽内部设计差异。

(2) 评述了双极板材料选取与流场设计之间的综合考量。

(3) 展望了为满足双极板更高性能要求而采用的新设计理念和新制造方法。

中文摘要

氢能开发作为实现脱碳化和构建可持续能源体系的关键途径，对于应对全球能源危机具有至关重要的作用。质子交换膜电解水技术因其制氢效率高、反应速度快且电解槽结构紧凑等优点，被认为是一项极具发展潜力的技术。双极板在质子交换膜水电解槽中占据较高的成本和重量比例，其优化设计变得格外关键。本文综述了近年来双极板在材料选取和流场设计方面的研究现状。首先，对比了质子交换膜燃料电池与水电解槽内部的工况差异，包括化学反应、运行温度、压力、质量流速和工作电位。随后，系统回顾了双极板基材和表面涂层的研究现状，并重点介绍了一些典型的槽-肋流场和多孔流场等。同时，探讨了材料选取对传质和传热的影响以及通过改进流场结构来减少腐蚀的可能性。最后，展望了双极板设计的未来发展趋势，其中包括利用3D打印技术优化流场结构以提升传质和传热效率，以及借助计算材料学方法优化表面涂层成分以提高耐蚀性和导电性等方面的探索。

关键词:

Invited Review

Effect of bipolar-plates design on corrosion, mass and heat transfer in proton-exchange membrane fuel cells and water electrolyzers: A review

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Abstract

Abstract

Attaining a decarbonized and sustainable energy system, which is the core solution to global energy issues, is accessible through the development of hydrogen energy. Proton-exchange membrane water electrolyzers (PEMWEs) are promising devices for hydrogen production, given their high efficiency, rapid responsiveness, and compactness. Bipolar plates account for a relatively high percentage of the total cost and weight compared with other components of PEMWEs. Thus, optimization of their design may accelerate the promotion of PEMWEs. This paper reviews the advances in materials and flow-field design for bipolar plates. First, the working conditions of proton-exchange membrane fuel cells (PEMFCs) and PEMWEs are compared, including reaction direction, operating temperature, pressure, input/output, and potential. Then, the current research status of bipolar-plate substrates and surface coatings is summarized, and some typical channel-rib flow fields and porous flow fields are presented. Furthermore, the effects of materials on mass and heat transfer and the possibility of reducing corrosion by improving the flow field structure are explored. Finally, this review discusses the potential directions of the development of bipolar-plate design, including material fabrication, flow-field geometry optimization using three-dimensional printing, and surface-coating composition optimization based on computational materials science.
- bipolar-plates;
- flow design;
- mass and heat transfer;
- corrosion;
- water electrolyzers;
- fuel cells

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