升级再造废旧锂电材料为高电压双离子电池正极

杜苗; 吕红艳; 杜凯迪; 郑硕航; 王晓彤; 邓晓桐; 曾荣华; 吴兴隆

doi:10.1007/s12613-023-2807-2

Volume 31 Issue 7

Jul. 2024

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文章导航 > 矿物冶金与材料学报（英文） > 2024 > 31(7): 1745-1751

Miao Du, Hongyan Lü, Kaidi Du, Shuohang Zheng, Xiaotong Wang, Xiaotong Deng, Ronghua Zeng, and Xinglong Wu, Upcycling the spent graphite/LiCoO₂ batteries for high-voltage graphite/LiCoPO₄-co-workable dual-ion batteries, Int. J. Miner. Metall. Mater., 31(2024), No. 7, pp. 1745-1751. https://doi.org/10.1007/s12613-023-2807-2

Cite this article as:

Miao Du, Hongyan Lü, Kaidi Du, Shuohang Zheng, Xiaotong Wang, Xiaotong Deng, Ronghua Zeng, and Xinglong Wu, Upcycling the spent graphite/LiCoO2 batteries for high-voltage graphite/LiCoPO4-co-workable dual-ion batteries, Int. J. Miner. Metall. Mater., 31(2024), No. 7, pp. 1745-1751. https://doi.org/10.1007/s12613-023-2807-2

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研究论文

升级再造废旧锂电材料为高电压双离子电池正极

1)
东北师范大学紫外光发射材料与技术教育部重点实验室, 长春130024, 中国
2)
东北师范大学化学学院, 长春130024, 中国
3)
华南师范大学化学学院, 广州510006, 中国

通讯作者:
吴兴隆 E-mail: xinglong@nenu.edu.cn

文章亮点

(1) 针对废旧锂离子电池材料，提出了一种新型的正、负电极同步回收策略

(2) 将废旧石墨/钴酸锂电池的正负极同步回收，开发了阴阳离子接力储能的双离子电池

(3) 巧妙地利用廉价易得的废旧石墨提升磷酸钴锂材料的电子导电率及电化学性能

中文摘要

电化学储能技术作为化石能源向清洁能源过渡的最先进的方法之一，正在以越来越快的速度发展，推动着碳中和未来的实现。其中，锂离子电池凭借优异的电化学性能和良好的安全性能已广泛应用于电动工具和便携式电子产品中。与此同时，废旧锂离子电池的数量也急剧增加，预计到2030年将会产生1100万吨的废旧锂离子电池。然而，目前传统的回收方法（湿法和火法回收法）仍然存在一定的局限性（消耗大量化学试剂，产生二次污染和能耗高）。因此，该论文提出了一种生态友好且可持续的双回收策略，即将废锂离子电池的钴酸锂正极和石墨负极材料同步回收，并将回收的钴酸锂升级处理为磷酸钴锂。随后，将磷酸钴锂和石墨以1：1的质量比混合，并用于锂离子/六氟磷酸根共脱嵌的双离子电池中。在25 mA g^-1 的电流密度下，该双离子电池可发挥出86.2 mAh g^-1的放电比容量，且循环 400 次后的容量保持率为69%。对废旧锂离子电池的正负极进行双重回收可避免资源浪费，并获得性能优异的正极材料，从而为设计新型二次电池提供了一种生态友好和可持续发展的途径。

关键词:

Research Article

Upcycling the spent graphite/LiCoO₂ batteries for high-voltage graphite/LiCoPO₄-co-workable dual-ion batteries

+ Author Affiliations

Abstract

Abstract

The worldwide proliferation of portable electronics has resulted in a dramatic increase in the number of spent lithium-ion batteries (LIBs). However, traditional recycling methods still have limitations because of such huge amounts of spent LIBs. Therefore, we proposed an ecofriendly and sustainable double recycling strategy to concurrently reuse the cathode (LiCoO₂) and anode (graphite) materials of spent LIBs and recycled LiCoPO₄/graphite (RLCPG) in $ {\text{L}\text{i}}^{+}/{{\text{P}\text{F}}}_{6}^{-} $ co-de/intercalation dual-ion batteries. The recycle-derived dual-ion batteries of Li/RLCPG show impressive electrochemical performance, with an appropriate discharge capacity of 86.2 mAh·g⁻¹ at 25 mA·g⁻¹ and 69% capacity retention after 400 cycles. Dual recycling of the cathode and anode from spent LIBs avoids wastage of resources and yields cathode materials with excellent performance, thereby offering an ecofriendly and sustainable way to design novel secondary batteries.
- recycle;
- lithium cobalt oxide;
- lithium cobalt phosphate;
- graphite;
- dual-ion batteries;
- spent lithium-ion batteries

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References(47)

References

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升级再造废旧锂电材料为高电压双离子电池正极

文章亮点

中文摘要

Upcycling the spent graphite/LiCoO₂ batteries for high-voltage graphite/LiCoPO₄-co-workable dual-ion batteries

Abstract

References

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