晶格中含镍针铁矿的表面性质在水杨基羟肟酸的作用下演变:实验和密度泛函理论研究

Levie Mweene; Gilsang Hong; Hee-Eun Jeong; Hee-won Kang; Hyunjung Kim

doi:10.1007/s12613-023-2813-4

Volume 31 Issue 4

Apr. 2024

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文章导航 > 矿物冶金与材料学报（英文） > 2024 > 31(4): 665-677

Levie Mweene, Gilsang Hong, Hee-Eun Jeong, Hee-won Kang, and Hyunjung Kim, Insights into the changes in the surface properties of goethite with Ni in the lattice in the presence of salicylhydroxamic acid: Experimental and density functional theory studies, Int. J. Miner. Metall. Mater., 31(2024), No. 4, pp. 665-677. https://doi.org/10.1007/s12613-023-2813-4

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Levie Mweene, Gilsang Hong, Hee-Eun Jeong, Hee-won Kang, and Hyunjung Kim, Insights into the changes in the surface properties of goethite with Ni in the lattice in the presence of salicylhydroxamic acid: Experimental and density functional theory studies, Int. J. Miner. Metall. Mater., 31(2024), No. 4, pp. 665-677. https://doi.org/10.1007/s12613-023-2813-4

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研究论文

晶格中含镍针铁矿的表面性质在水杨基羟肟酸的作用下演变:实验和密度泛函理论研究

Department of Earth Resources and Environmental Engineering, Hanyang University, 222 Wangsimni-ro, Seongdong-gu, Seoul 04763, Republic of Korea

* 共同第一作者

通讯作者:
Hyunjung Kim E-mail: kshjkim@hanyang.ac.kr

中文摘要

对针铁矿(GT)和晶格中含镍针铁矿(GTN) 在水杨基羟肟酸(SA)存在条件下的表面化学变化进行了对比实验和理论分析。结果表明，在100 g SA存在的情况下，GTN和GT的浮选回收率随pH的增加而增加，在pH 为8.3时，两种矿物的浮选回收率均达到最大值98.9%，PH超过该值时，回收率则逐渐降低；除pH = 8.3时外，GTN的回收率均略高于GT。这是因为存在共价键、封闭壳键和常规氢键形成的GTN∙∙∙SA的络合能(−883.87 kJ⋅mol⁻¹)比GT∙∙SA的络合能(−604.23 kJ⋅mol⁻¹)更高。相对于GT, GTN对SA的吸附性更好，这是由于GTN中会形成的π孔，进一步促进捕收剂与矿物之间的相互作用。因此， GT晶格中Ni的存在分别促进和减少了SA在矿物上的吸附和解吸。

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Research Article

Insights into the changes in the surface properties of goethite with Ni in the lattice in the presence of salicylhydroxamic acid: Experimental and density functional theory studies

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Abstract

Abstract

Comparative experiments and theoretical analysis of the surface chemistry changes of goethite (GT) and goethite containing Ni (GTN) in the lattice in the presence of salicylhydroxamic acid (SA) were performed. It was revealed that in the presence of 100 g·t⁻¹ of SA, the flotation recovery of GTN and GT increased with increasing pH, achieving a maximum recovery of 98.9% for both minerals at pH 8.3 and decreasing beyond that pH, with GTN having a slightly higher recovery than GT, except at pH 8.3. This was further confirmed by the higher complexation energies of GTN∙∙∙SA (−883.87 kJ·mol⁻¹) compared with GT∙∙∙SA (−604.23 kJ·mol⁻¹) resulting from covalent, closed-shell, and conventional hydrogen bonding. The higher adsorption of SA onto GTN relative to GT was due to the formation of a π-hole in GTN, thereby promoting a higher interaction of the collector with the mineral. Thus, the presence of Ni in the GT lattice improves and decreases the adsorption and desorption of SA onto and from the mineral, respectively, compared with those onto and from GT.
- nickel;
- goethite;
- adsorption;
- salicylhydroxamic acid;
- recovery

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