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Volume 31 Issue 9
Sep.  2024
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文章导航 >  矿物冶金与材料学报（英文）  > 2024  >  31(9): 2037-2047
Yang Liu, Yufeng Liu, Sha Zhang, Lin Zhang, Peng Zhang, Shaorong Zhang, Na Liu, Zhou Li, and Xuanhui Qu, Structure characterization of the oxide film on FGH96 superalloy powders with various oxidation degrees, Int. J. Miner. Metall. Mater., 31(2024), No. 9, pp. 2037-2047. https://doi.org/10.1007/s12613-024-2823-x
Cite this article as:
Yang Liu, Yufeng Liu, Sha Zhang, Lin Zhang, Peng Zhang, Shaorong Zhang, Na Liu, Zhou Li, and Xuanhui Qu, Structure characterization of the oxide film on FGH96 superalloy powders with various oxidation degrees, Int. J. Miner. Metall. Mater., 31(2024), No. 9, pp. 2037-2047. https://doi.org/10.1007/s12613-024-2823-x
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研究论文

不同氧化程度FGH96高温合金粉末氧化膜的结构表征

  • 1)

    北京科技大学新材料技术研究院, 北京材料基因工程高精尖创新中心, 北京 100083, 中国

  • 2)

    辽宁材料实验室材料智能技术研究所, 沈阳 110004, 中国

  • 3)

    北京航空材料研究院先进高温结构材料科学与技术实验室, 北京 100095, 中国




  • 通讯作者:

    章林    E-mail: zlin@ustb.edu.cn

    张鹏    E-mail: zpeng@ustb.edu.cn

    曲选辉    E-mail: quxh@ustb.edu.cn

文章亮点

  • (1) FGH96粉末的氧化膜由非晶氧化物层和氧化物颗粒组成。
  • (2) 由于氧平衡压力的影响，合金元素在基体上呈层状分布。
  • (3) 碳化物的氧化形成富Ti氧化物颗粒。
  • (4) 非晶氧化层随氧含量升高变厚。
  • FGH96 合金粉末的氧化膜结构显著影响高温合金的力学性能。在本研究中，采用高分辨率透射电子显微镜和原子探针技术，对不同氧含量的 FGH96 合金粉末进行了研究，以阐明氧化膜随氧含量的结构演变。能量色散光谱分析揭示了合金粉末氧化膜中存在两种不同的组分：在粉末γ基体上方的非晶态氧化层以及位于碳化物上方的非晶氧化物颗粒。合金元素在非晶态氧化层中呈层状分布，由外到内依次为Ni、Co、Cr和Al/Ti，这主要是由于氧从粉末表面扩散到γ基体内部氧平衡压力降低所导致的。另一方面，粉末表面碳化物的氧化、分解造成在其上方形成富Ti氧化物颗粒。氧含量为140、280和340 ppm的合金粉末氧化膜的厚度分别约为9、14、30 nm。合金元素在三种厚度氧化膜内分布规律类似。这些发现为FGH96合金粉末氧化膜的结构分析提供了宝贵的见解。
    • Research Article

    Structure characterization of the oxide film on FGH96 superalloy powders with various oxidation degrees

    + Author Affiliations
      Abstract
    • The structure of the oxide film on FGH96 alloy powders significantly influences the mechanical properties of superalloys. In this study, FGH96 alloy powders with various oxygen contents were investigated using high-resolution transmission electron microscopy and atomic probe technology to elucidate the structure evolution of the oxide film. Energy dispersive spectrometer analysis revealed the presence of two distinct components in the oxide film of the alloy powders: amorphous oxide layer covering the γ matrix and amorphous oxide particles above the carbide. The alloying elements within the oxide layer showed a laminated distribution, with Ni, Co, Cr, and Al/Ti, which was attributed to the decreasing oxygen equilibrium pressure as oxygen diffused from the surface into the γ matrix. On the other hand, Ti enrichment was observed in the oxide particles caused by the oxidation and decomposition of the carbide phase. Comparative analysis of the oxide film with oxygen contents of 140, 280, and 340 ppm showed similar element distributions, while the thickness of the oxide film varies approximately at 9, 14, and 30 nm, respectively. These findings provide valuable insights into the structural analysis of the oxide film on FGH96 alloy powders.
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