水系锌离子电池MXene基正极材料的研究进展和展望

武爱多; 王天浩; 张隆; 陈晨; 李侨敏; 曲选辉; 刘永畅

doi:10.1007/s12613-024-2859-y

Volume 31 Issue 7

Jul. 2024

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文章导航 > 矿物冶金与材料学报（英文） > 2024 > 31(7): 1752-1765

Aiduo Wu, Tianhao Wang, Long Zhang, Chen Chen, Qiaomin Li, Xuanhui Qu, and Yongchang Liu, Recent advances and perspectives in MXene-based cathodes for aqueous zinc-ion batteries, Int. J. Miner. Metall. Mater., 31(2024), No. 7, pp. 1752-1765. https://doi.org/10.1007/s12613-024-2859-y

Cite this article as:

Aiduo Wu, Tianhao Wang, Long Zhang, Chen Chen, Qiaomin Li, Xuanhui Qu, and Yongchang Liu, Recent advances and perspectives in MXene-based cathodes for aqueous zinc-ion batteries, Int. J. Miner. Metall. Mater., 31(2024), No. 7, pp. 1752-1765. https://doi.org/10.1007/s12613-024-2859-y

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特约综述

水系锌离子电池MXene基正极材料的研究进展和展望

1)
北京材料基因工程高精尖创新中心, 北京科技大学新材料技术研究院, 新金属材料国家重点实验室, 北京 100083, 中国
2)
北京科技大学材料科学与工程学院, 北京 100083, 中国
3)
北京科技大学经济与管理学院, 北京 100083, 中国

* 共同第一作者

通讯作者:
张隆    E-mail: zhanglong@ustb.edu.cn

李侨敏    E-mail: qli091@ustb.edu.cn

刘永畅    E-mail: liuyc@ustb.edu.cn

文章亮点

(1) 系统地总结了水系锌离子电池MXenes基正极材料的最新研究进展。

(2) 通过介绍MXenes材料的晶体结构、储锌机理，改性策略阐明了其构效关系。

(3) 提出了目前MXenes基水系储锌正极材料面临的挑战并对其未来发展作了展望。

中文摘要

水系锌离子电池凭借其本征安全、成本低廉、环境友好和优异的电化学性能，在大规模储能领域展现出巨大应用潜力。然而，二价锌离子与宿主材料之间的强静电相互作用限制能够高效、快速、稳定储存锌离子的先进正极材料的开发。MXenes及其衍生物具有较大的层间距、良好的亲水性、出色的电子导电性和高氧化还原活性，被认为是水系锌离子电池正极材料的“明日之星”。本文全面综述了MXenes基材料作为水系锌离子电池正极的最新研究进展，包括其晶体结构、储锌机制、表面改性、层间工程和导电网络设计等方面，进而阐明其成分、结构与电化学性能之间的构效关系。此外，我们提出了目前MXenes基水系锌离子电池正极面临的挑战，例如迫切需要改进有毒的制备方法、探索潜在的新型MXene基正极材料以及抑制层状MXene在电化学循环过程中的再堆叠。最后，对未来发展高性能水系锌离子电池MXenes基正极材料的前景作出了展望。

关键词:

Invited Review

Recent advances and perspectives in MXene-based cathodes for aqueous zinc-ion batteries

+ Author Affiliations

1)
Beijing Advanced Innovation Center for Materials Genome Engineering, Institute for Advanced Materials and Technology, State Key Laboratory for Advanced Metals and Materials, University of Science and Technology Beijing, Beijing 100083, China
2)
School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China
3)
School of Economics and Management, University of Science and Technology Beijing, Beijing 100083, China

Yongchang Liu and Xuanhui Qu are editorial board members for this journal and were not involved in the editorial review or the decision to publish this article. All authors declare that there are no competing interests.
* These authors contributed equally to this work.

Corresponding authors:
Long Zhang    E-mail: zhanglong@ustb.edu.cn

Qiaomin Li    E-mail: qli091@ustb.edu.cn

Yongchang Liu    E-mail: liuyc@ustb.edu.cn
Received: 23 December 2023; Revised: 2 February 2024; Accepted: 22 February 2024; Available online: 23 February 2024

Abstract

Abstract

Aqueous zinc-ion batteries (AZIBs) show great potential for applications in grid-scale energy storage, given their intrinsic safety, cost effectiveness, environmental friendliness, and impressive electrochemical performance. However, strong electrostatic interactions exist between zinc ions and host materials, and they hinder the development of advanced cathode materials for efficient, rapid, and stable Zn-ion storage. MXenes and their derivatives possess a large interlayer spacing, excellent hydrophilicity, outstanding electronic conductivity, and high redox activity. These materials are considered “rising star” cathode candidates for AZIBs. This comprehensive review discusses recent advances in MXenes as AZIB cathodes from the perspectives of crystal structure, Zn-storage mechanism, surface modification, interlayer engineering, and conductive network design to elucidate the correlations among their composition, structure, and electrochemical performance. This work also outlines the remaining challenges faced by MXenes for aqueous Zn-ion storage, such as the urgent need for improved toxic preparation methods, exploration of potential novel MXene cathodes, and suppression of layered MXene restacking upon cycling, and introduces the prospects of MXene-based cathode materials for high-performance AZIBs.
- aqueous zinc-ion batteries;
- MXenes;
- terminal groups;
- interlayer engineering;
- conductive network design

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