甘蔗衍生碳材料中合理构建异质界面以实现优异的电磁波吸收

张世杰; 兰笛; 郑嘉俊; 冯爱玲; 裴亚星; 蔡世昌; 杜苏轩; 陈星亮; 吴广磊; 贾梓睿

doi:10.1007/s12613-024-2875-y

Volume 31 Issue 12

Dec. 2024

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文章导航 > 矿物冶金与材料学报（英文） > 2024 > 31(12): 2749-2759

Shijie Zhang, Di Lan, Jiajun Zheng, Ailing Feng, Yaxing Pei, Shichang Cai, Suxuan Du, Xingliang Chen, Guanglei Wu, and Zirui Jia, Rational construction of heterointerfaces in biomass sugarcane-derived carbon for superior electromagnetic wave absorption, Int. J. Miner. Metall. Mater., 31(2024), No. 12, pp. 2749-2759. https://doi.org/10.1007/s12613-024-2875-y

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Shijie Zhang, Di Lan, Jiajun Zheng, Ailing Feng, Yaxing Pei, Shichang Cai, Suxuan Du, Xingliang Chen, Guanglei Wu, and Zirui Jia, Rational construction of heterointerfaces in biomass sugarcane-derived carbon for superior electromagnetic wave absorption, Int. J. Miner. Metall. Mater., 31(2024), No. 12, pp. 2749-2759. https://doi.org/10.1007/s12613-024-2875-y

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研究论文

甘蔗衍生碳材料中合理构建异质界面以实现优异的电磁波吸收

1)
绍兴文理学院浙江省清洁染整技术研究重点实验室, 绍兴 312000, 中国
2)
湖北汽车工业学院材料科学与工程学院, 十堰 442002, 中国
3)
河南工业大学材料科学与工程学院, 郑州 450001, 中国
4)
宝鸡文理学院物理与光电技术学院, 宝鸡 721016, 中国
5)
郑州磨料磨具磨削研究所, 郑州 450002, 中国
6)
青岛大学材料科学与工程学院, 青岛 266071, 中国

通讯作者:
冯爱玲    E-mail: ailing@mail.xjtu.edu.cn

陈星亮    E-mail: chenxlmoon@163.com

贾梓睿    E-mail: jiazirui@qdu.edu.cn

文章亮点

(1) 通过煅烧甘蔗/CoZn–ZIF获得了具有丰富异质界面的碳基杂化材料

(2) 杂化材料中的异质结构提供了大量的有效的极性界面

(3) 优化后的杂化材料能够获得7.28 GHz的有效吸收带宽

(4) 材料优异的吸波性能得益于良好的阻抗匹配和协同效应

中文摘要

第五代移动通信技术的广泛应用正在推动电磁波吸收材料朝向“薄、轻、宽、强”的方向快速发展。吸波材料中异质界面的构建对于提高其电磁波吸收能力至关重要。本文旨在开发一种具有丰富异质界面的吸波材料。本文通过合理设计甘蔗和CoZn-ZIF的异质结构并进行煅烧而制备了一系列具有丰富异质界面的超轻复合材料（Co/ZnO@N-掺杂碳/层堆叠碳、MSC）。研究了所制备的杂化材料的成分和结构，并通过控制前驱体中CoZn-ZIF含量来调节其衍生物的电磁参数。结果表明所得杂化材料都具有良好的电磁波吸收性能，特别是MSC-3样品。在填料负载量为20 wt%，厚度仅为1.6 mm的条件下时，优化后的最小反射损失和有效吸收带可分别达到 -42 dB和7.28 GHz。经过分析材料优异的吸波性能主要归功于材料中丰富异质界面产生的介电损耗和磁性Co单质引起的磁损耗的协同效应，并有效地改善了材料的阻抗匹配。同时，甘蔗衍生的层状堆叠得碳材料形成了连续的导电网络，可以通过多次反射和传导损耗进一步耗散电磁能。此外，模拟得雷达散射截面（RCS）结果表明，MSC-3在现实远场条件下具有出色的电磁波衰减能力。

关键词:

Research Article

Rational construction of heterointerfaces in biomass sugarcane-derived carbon for superior electromagnetic wave absorption

+ Author Affiliations

1)
Key Laboratory of Clean Dyeing and Finishing Technology of Zhejiang Province, Shaoxing Key Laboratory of High Performance Fibers & Products, Shaoxing University, Shaoxing 312000, China
2)
School of Materials Science and Engineering, Hubei University of Automotive Technology, Shiyan 442002, China
3)
School of Material Science and Engineering, Henan University of Technology, Zhengzhou 450001, China
4)
Institute of Physics & Optoelectronics Technology, Baoji University of Arts and Sciences, Baoji 721016, China
5)
Zhengzhou Research Institute for Abrasives and Grinding, Zhengzhou 450002, China
6)
Institute of Materials for Energy and Environment, State Key Laboratory of Bio-fibers and Eco-textiles, College of Materials Science and Engineering, Qingdao University, Qingdao 266071, China

Guanglei Wu is an editorial board member for this journal and was not involved in the editorial review or the decision to publish this article. The authors declare no conflict of interest.

Corresponding authors:
Ailing Feng    E-mail: ailing@mail.xjtu.edu.cn

Xingliang Chen    E-mail: chenxlmoon@163.com

Zirui Jia    E-mail: jiazirui@qdu.edu.cn
Received: 13 January 2024; Revised: 3 March 2024; Accepted: 5 March 2024; Available online: 7 March 2024

Abstract

Abstract

The pervasive adoption of 5th generation mobile communication technology propels electromagnetic wave (EW) absorbents to achieve high-level performance. The heterointerface construction is crucial to the improvement of absorption ability. Herein, a series of ultralight composites with rational heterointerfaces (Co/ZnO@N-doped C/layer-stacked C, MSC) is fabricated by calcination with rational construction of sugarcane and CoZn–zeolitic imidazolate framework (ZIF). The components and structures of as-prepared composites were investigated, and their electromagnetic parameters could be adjusted by the content of CoZn–ZIFs. All composites possess excellent EW absorption performance, especially MSC-3. The optimal minimum reflection loss and effective absorption band of MSC-3 can reach −42 dB and 7.28 GHz at the thickness of only 1.6 mm with 20wt% filler loading. This excellent performance is attributed to the synergistic effect of dielectric loss stemming from the multiple heterointerfaces and magnetic loss induced by magnetic single Co. The sugarcane-derived layer-stacked carbon has formed consecutive conductive networks and has further dissipated the electromagnetic energy through multiple reflection and conduction losses. Moreover, the simulated radar cross section (RCS) technology manifests that MSC-3 possesses outstanding EW attenuation capacity under realistic far-field conditions. This study provides a strategy for building efficient absorbents based on biomass.
- sugarcane-derived carbon;
- heterointerfaces;
- bimetallic metal–organic frameworks;
- EW absorption;
- radar cross section

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