通过磁性能调控实现高熵铁氧体优异的微波吸收能力

霍毓瑛; 王政炎; 张妍兰; 王永祯

doi:10.1007/s12613-024-2883-y

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文章导航 > 矿物冶金与材料学报（英文） > 2024 > 二校

Yuying Huo, Zhengyan Wang, Yanlan Zhang, and Yongzhen Wang, High-entropy ferrite with tunable magnetic properties for excellent microwave absorption, Int. J. Miner. Metall. Mater.,(2024). https://doi.org/10.1007/s12613-024-2883-y

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Yuying Huo, Zhengyan Wang, Yanlan Zhang, and Yongzhen Wang, High-entropy ferrite with tunable magnetic properties for excellent microwave absorption, Int. J. Miner. Metall. Mater.,(2024). https://doi.org/10.1007/s12613-024-2883-y

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研究论文

通过磁性能调控实现高熵铁氧体优异的微波吸收能力

1)
太原理工大学材料科学与工程学院, 太原 030024, 中国
2)
山西省煤基固废资源化与绿色生态发展联合实验室, 太原 030024, 中国

通讯作者:
张妍兰 E-mail: zhangyanlan@tyut.edu.cn

王永祯 E-mail: wangyongzhen@tyut.edu.cn

文章亮点

(1) 成功合成了一种新型高熵铁氧体材料。

(2) 系统探究了Co–Ni含量对高熵铁氧体材料微观结构、磁性能和电磁参数的影响规律。

(3) 获得了一种提升高熵铁氧体材料吸波性能的方法，并系统研究了吸波性能提升机制。

中文摘要

尖晶石型铁氧体材料具有优异的磁损耗，被广泛用于电磁波吸收领域。然而，厚的匹配厚度和窄的吸收带宽限制了其作为吸波材料的独立应用。近年来，高熵材料因其具有独特的结构和前所未有的应用潜力，正引起越来越多的关注。本文通过固相反应法成功合成了一系列具有不同Co–Ni含量的新型高熵铁氧体材料：(CoNi)_x/2(CuZnAl)_(1−x)/3Fe₂O₄ （x = 0.25、0.34、0.40、0.50），系统地研究了Co–Ni元素含量对材料微观结构、磁性能和电磁参数的影响，并分析了其在2–18 GHz频率范围内的电磁波吸收特性。结果表明，Co–Ni含量对材料的矫顽力和自然共振频率有显著影响。当x = 0.50时，材料具有更宽的有效吸收带宽和更薄的匹配厚度。

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Research Article

High-entropy ferrite with tunable magnetic properties for excellent microwave absorption

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Abstract

Abstract

High-entropy design is attracting growing interest as it offers unique structures and unprecedented application potential for materials. In this article, a novel high-entropy ferrite (CoNi)_x/2(CuZnAl)_(1−x)/3Fe₂O₄ (x = 0.25, 0.34, 0.40, 0.50) with a single spinel phase of space group $ Fd\bar{3}m $ was successfully developed by the solid-state reaction method. By tuning the Co–Ni content, the magnetic properties of the material, especially the coercivity, changed regularly, and the microwave absorption properties were improved. In particular, the effective absorption bandwidth of the material increased from 4.8 to 7.2 GHz, and the matched thickness decreased from 3.9 to 2.3 mm, while the minimum reflection loss remained below −20 dB. This study provides a practical method for modifying the properties of ferrites used to absorb electromagnetic waves.
- high-entropy oxide;
- spinel ferrite;
- oxygen vacancy;
- radar cross section

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