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Volume 31 Issue 11
Nov.  2024
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文章导航 >  矿物冶金与材料学报（英文）  > 2024  >  31(11): 2327-2344
Yifan Zhao, Zhiyuan Li, Shijie Li, Weili Song, and Shuqiang Jiao, A review of in-situ high-temperature characterizations for understanding the processes in metallurgical engineering, Int. J. Miner. Metall. Mater., 31(2024), No. 11, pp. 2327-2344. https://doi.org/10.1007/s12613-024-2891-y
Cite this article as:
Yifan Zhao, Zhiyuan Li, Shijie Li, Weili Song, and Shuqiang Jiao, A review of in-situ high-temperature characterizations for understanding the processes in metallurgical engineering, Int. J. Miner. Metall. Mater., 31(2024), No. 11, pp. 2327-2344. https://doi.org/10.1007/s12613-024-2891-y
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综述

冶金工程过程中的高温原位表征综述

  • 1)

    北京理工大学先进结构技术研究院, 北京 100081, 中国

  • 2)

    北京科技大学绿色低碳钢铁冶金全国重点实验室, 北京 100083, 中国


  • 通讯作者:

    李世杰    E-mail: sli@ustb.edu.cn

    宋维力    E-mail: weilis@bit.edu.cn

文章亮点

  • (1) 讨论了原位高温表征技术的最新进展。
  • (2) 阐述了高温化学/电化学冶金过程的各种原位表征方法的重要性。
  • (3) 总结了对冶金工程过程认识的进展。
  • 为了合理控制高温冶金工程的生产质量，需要了解黑箱化学/电化学的反应过程。为克服这一问题，近年来开发了各种原位表征方法，以用来研究高温电化学电极和熔盐的成分、微观结构和固–液界面之间的相互作用。本综述讨论了原位高温表征技术的最新进展，总结了冶金工程中反应过程的进展。原位高温技术和分析方法主要包括同步辐射X射线衍射 (s-XRD)、激光共聚焦显微镜 (LSCM) 和 X 射线计算显微层析成像 (X-ray µ-CT)，是分析电极结构和形态的重要平台，可揭示电极界面的复杂性和变化性。此外，激光诱导击穿光谱（LIBS）、高温拉曼显微光谱和紫外–可见光谱（UV–Vis）可提供熔盐成分和结构的微观表征。更重要的是，X-ray µ-CT 和 s-XRD 技术的结合可以研究两相界面的化学反应机制。因此，这些原位方法对于分析高温反应过程的化学/电化学动力学至关重要，可为化学/电化学冶金过程的高效稳定运行建立理论原则。
    • Review

    A review of in-situ high-temperature characterizations for understanding the processes in metallurgical engineering

    + Author Affiliations
      Abstract
    • For the rational manipulation of the production quality of high-temperature metallurgical engineering, there are many challenges in understanding the processes involved because of the black box chemical/electrochemical reactors. To overcome this issue, various in-situ characterization methods have been recently developed to analyze the interactions between the composition, microstructure, and solid–liquid interface of high-temperature electrochemical electrodes and molten salts. In this review, recent progress of in-situ high-temperature characterization techniques is discussed to summarize the advances in understanding the processes in metallurgical engineering. In-situ high-temperature technologies and analytical methods mainly include synchrotron X-ray diffraction (s-XRD), laser scanning confocal microscopy, and X-ray computed microtomography (X-ray µ-CT), which are important platforms for analyzing the structure and morphology of the electrodes to reveal the complexity and variability of their interfaces. In addition, laser-induced breakdown spectroscopy, high-temperature Raman spectroscopy, and ultraviolet–visible absorption spectroscopy provide microscale characterizations of the composition and structure of molten salts. More importantly, the combination of X-ray µ-CT and s-XRD techniques enables the investigation of the chemical reaction mechanisms at the two-phase interface. Therefore, these in-situ methods are essential for analyzing the chemical/electrochemical kinetics of high-temperature reaction processes and establishing the theoretical principles for the efficient and stable operation of chemical/electrochemical metallurgical processes.
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