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Volume 31 Issue 10
Oct.  2024
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文章导航 >  矿物冶金与材料学报（英文）  > 2024  >  31(10): 2253-2262
Sarfraz, Shahzad Rasool, Muhammad Khalid, M.A.K. Yousaf Shah, Bin Zhu, Jung-Sik Kim, Muhammad Imran Asghar, Nabeela Akbar, and Wenjing Dong, Al3+ doped CeO2 for proton conducting fuel cells, Int. J. Miner. Metall. Mater., 31(2024), No. 10, pp. 2253-2262. https://doi.org/10.1007/s12613-024-2910-z
Cite this article as:
Sarfraz, Shahzad Rasool, Muhammad Khalid, M.A.K. Yousaf Shah, Bin Zhu, Jung-Sik Kim, Muhammad Imran Asghar, Nabeela Akbar, and Wenjing Dong, Al3+ doped CeO2 for proton conducting fuel cells, Int. J. Miner. Metall. Mater., 31(2024), No. 10, pp. 2253-2262. https://doi.org/10.1007/s12613-024-2910-z
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研究论文

用于质子导电燃料电池的Al3+掺杂CeO2研究

  • 1)

    江苏省太阳能技术/联合储能研究中心, 东南大学能源与环境学院, 南京 210096, 中国

  • 2)

    湖北大学微电子学院, 武汉 430062, 中国

  • 3)

    北京航空航天大学中法工程师学院/国际通用工程学院, 北京 100191, 中国

  • 4)

    Renewable Energy Technologies Group, Faculty of Engineering and Natural Sciences, Tampere University, FI-33014, Finland


  • 通讯作者:

    朱斌    E-mail: zhu-bin@seu.edu.cn

    Nabeela Akbar    E-mail: nabeela4426@gmail.com

    董文静    E-mail: wenjingd@hubu.edu.cn

文章亮点

  • (1) 通过直接烧结法成功制备了萤石结构Al掺杂CeO2。
  • (2) Al掺杂使CeO2中形成了大量的氧空位。
  • (3) Al掺杂使CeO2在500°C下获得了0.15 S/cm的电导率。
  • (4) 500°C下获得了923 mW/cm2的电池性能。
  • (5) 通过氧离子阻挡层证实了Al掺杂CeO2的质子导电能力。
  • 开发具有高离子导电性的电解质是质子导电燃料电池（PCFCs）实际应用的关键。本研究探讨了铝掺杂对氧化铈的结构、形貌、电学和电化学性能的影响。Al掺杂使氧化铈中形成大量的氧空位，进而使得基于该电解质的PCFCs在低温范围（300–500°C）下具备快速离子传导能力。X射线衍射（XRD）精修确定了铝掺杂氧化铈（ADC）材料属于纯立方萤石结构，并证实了铝离子成功掺入氧化铈晶格。研究了材料中不同含量铝掺杂氧化铈（10ADC、20ADC和30ADC）的电子结构，结果表明，30ADC电解质是最优组分，其具有最多的晶格氧空位。以其制备的PCFC在500°C时的最大输出功率密度为923 mW/cm2。此外，利用氧离子阻挡层证明了铝掺杂铈基燃料电池具有质子导电能力。
    • Research Article

    Al3+ doped CeO2 for proton conducting fuel cells

    + Author Affiliations
      Abstract
    • Developing high ionic conducting electrolytes is crucial for applying proton-conducting fuel cell (PCFCs) practically. The current study investigates the effect of alumina on the structural, morphological, electrical, and electrochemical properties of CeO2. Lattice oxygen vacancies are induced in CeO2 by a general doping concept that enables fast ionic conduction at low-temperature ranges (300–500°C) for PCFCs. Rietveld refinement of the X-ray diffraction (XRD) patterns established the pure cubic fluorite structure of Al-doped CeO2 (ADC) samples and confirmed Al ions’ fruitful integration in the CeO2 lattice. The electronic structure of the alumina-doped ceria of the materials (10ADC, 20ADC, and 30ADC) has been investigated. As a result, it was found that the best composition of 30ADC-based electrolytes induced maximum lattice oxygen vacancies. The corresponding PCFC exhibited a maximum power output of 923 mW/cm2 at 500°C. Moreover, the investigation proves the proton-conducting ability of alumina-doped ceria-based fuel cells by using an oxide ion-blocking layer.
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