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文章导航 >  矿物冶金与材料学报（英文）  > 2024  > 一校
Zhonghua Lu, Jun Shen, Xin Zhang, Lingcong Chao, Liang Chen, Ding Zhang, Tao Wei, and Shoudong Xu, From waste to wealth: Coal tar residue derived carbon materials as low-cost anodes for potassium-ion batteries, Int. J. Miner. Metall. Mater.,(2024). https://doi.org/10.1007/s12613-024-2930-8
Cite this article as:
Zhonghua Lu, Jun Shen, Xin Zhang, Lingcong Chao, Liang Chen, Ding Zhang, Tao Wei, and Shoudong Xu, From waste to wealth: Coal tar residue derived carbon materials as low-cost anodes for potassium-ion batteries, Int. J. Miner. Metall. Mater.,(2024). https://doi.org/10.1007/s12613-024-2930-8
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研究论文

变废为宝：煤焦油渣衍生炭材料用作低成本钾离子电池负极

  • 1)

    太原理工大学化学工程与技术学院, 太原 030024, 中国

  • 2)

    太原理工大学化学学院, 太原 030024, 中国

  • 3)

    武汉工程大学化工与制药学院, 武汉 430205, 中国

  • 4)

    江苏科技大学能源与动力学院, 镇江 212003, 中国



  • 通讯作者:

    申峻    E-mail: xushoudong@tyut.edu.cn

    魏涛    E-mail: shenjun@tyut.edu.cn

    徐守冬    E-mail: wt863@126.com

文章亮点

  • （1）将煤化工行业固体废物煤焦油渣转变为高附加值炭材料并研究了其作为钾离子电池负极材料的电化学性能。
  • （2）综合对比了不同热解温度下煤焦油渣衍生炭材料的结构特点及电化学性能差异。
  • （3）系统地研究了CTRCs负极材料中K+存储的动力学特征及储钾机理。
  • 煤焦油渣（CTR）是煤化工行业产生的一种固体废物，CTR的富碳特征使其具有高附加值利用的潜能。本文采用直接炭化法，分别在700、800、900和1000°C下制备了CTR衍生炭材料（CTRCs），并将其作为钾离子电池（PIB）的负极材料。通过结构和形貌表征以及电化学性能测试，系统地探讨了炭化温度对CTRCs微观结构和钾离子存储性能的影响。在涡轮层状结构、晶体结构、孔隙结构、官能团和电导率等结构特征和物理性质的共同调控下，900°C制备的炭材料（CTRC-900H）在50 mA·g−1的电流密度下具有265.6 mAh·g−1的可逆比容量，且在循环100周后仍具有93.8%的容量保持率，500 mA·g−1的电流密度下，可逆比容量达171.8 mAh·g−1。通过循环伏安（CV）和恒电流间歇滴定（GITT）等方法测试研究了K+存储的动力学特征以及在CTRCs中的储钾机理。结果表明CTRC电极中K+迁移主要受表面诱导电容过程控制，存储K+的过程符合“吸附–弱插层”机理。本文探索了CTR作为高性能PIBs电极材料的潜力，同时也为CTR的高附加值利用开辟了新的途径。
    • Research Article

    From waste to wealth: Coal tar residue derived carbon materials as low-cost anodes for potassium-ion batteries

    + Author Affiliations
      Abstract
    • Carbon materials are widely recognized as highly promising electrode materials for various energy storage system applications. Coal tar residues (CTR), as a type of carbon-rich solid waste with high value-added utilization, are crucially important for the development of a more sustainable world. In this study, we employed a straightforward direct carbonization method within the temperature range of 700–1000°C to convert the worthless solid waste CTR into economically valuable carbon materials as anodes for potassium-ion batteries (PIBs). The effect of carbonization temperature on the microstructure and the potassium ions storage properties of CTR-derived carbons (CTRCs) were systematically explored by structural and morphological characterization, alongside electrochemical performances assessment. Based on the co-regulation between the turbine layers, crystal structure, pore structure, functional groups, and electrical conductivity of CTR-derived carbon carbonized at 900°C (CTRC-900H), the electrode material with high reversible capacity of 265.6 mAh g−1 at 50 mA·g−1, a desirable cycling stability with 93.8% capacity retention even after 100 cycles, and the remarkable rate performance for PIBs were obtained. Furthermore, cyclic voltammetry (CV) at different scan rates and galvanostatic intermittent titration technique (GITT) have been employed to explore the potassium ions storage mechanism and electrochemical kinetics of CTRCs. Results indicate that the electrode behavior is predominantly governed by surface-induced capacitive processes, particularly under high current densities, with the potassium storage mechanism characterized by an “adsorption–weak intercalation” mechanism. This work highlights the potential of CTR-based carbon as a promising electrode material category suitable for high-performance PIBs electrodes, while also provides valuable insights into the new avenues for the high value-added utilization of CTR.
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