质子交换膜燃料电池用金属双极板表面耐腐蚀涂层的研究进展

刘佳明; 胡倩; Sandrick Sabola; 张越; 独彪; 王显宗

doi:10.1007/s12613-024-2946-0

Volume 31 Issue 12

Dec. 2024

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文章导航 > 矿物冶金与材料学报（英文） > 2024 > 31(12): 2627-2644

Jiaming Liu, Qian Hu, Sandrick Sabola, Yue Zhang, Biao Du, and Xianzong Wang, Comparative review of corrosion-resistant coatings on metal bipolar plates of proton exchange membrane fuel cells, Int. J. Miner. Metall. Mater., 31(2024), No. 12, pp. 2627-2644. https://doi.org/10.1007/s12613-024-2946-0

Cite this article as:

Jiaming Liu, Qian Hu, Sandrick Sabola, Yue Zhang, Biao Du, and Xianzong Wang, Comparative review of corrosion-resistant coatings on metal bipolar plates of proton exchange membrane fuel cells, Int. J. Miner. Metall. Mater., 31(2024), No. 12, pp. 2627-2644. https://doi.org/10.1007/s12613-024-2946-0

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综述

质子交换膜燃料电池用金属双极板表面耐腐蚀涂层的研究进展

1)
西北工业大学深圳研究院, 深圳 518057, 中国
2)
西北工业大学凝固技术国家重点实验室, 西安 710072, 中国
3)
陕西煤化工产业技术研究院有限公司, 西安 710065, 中国

通讯作者:
王显宗 E-mail: xianzong.wang@nwpu.edu.cn

文章亮点

(1) 系统地对比了八种常用金属双极板涂层的性能及其研究进展

(2) 创新地采用新型坐标体系对涂层性能进行比较

(3) 总结并提出了各类涂层在未来生产和应用中面临的挑战

中文摘要

在质子交换膜燃料电池（PEMFCs）领域中，双极板（BPs）在分配反应气体、收集电流、促进产物水的排出和冷却电堆方面发挥着关键作用。相比传统的石墨双极板，金属双极板具有出色的可加工性、合理的成本、更高的功率密度和机械强度，逐渐成为主流选择。目前，发展金属双极板的主要挑战是提高其在酸性条件下的耐蚀性和导电性，因此需要在表面制备各种涂层以确保优异的性能。本综述总结并对比了八种双极板涂层的研究进展及其性能，包括贵金属、碳化物、氮化物以及a-C/金属化合物复合涂层等，其中特别关注的是双极板涂层长期导电性和耐蚀性之间的平衡问题。在当前的技术参数中，a-C/金属化合物复合涂层同时具有良好且稳定的导电性与耐蚀性，被认为是最有前途的一种金属双极板涂层。文章最后展望并提出了各类涂层未来在PEMFCs中的制造和应用中可能面临的挑战。

关键词:

Review

Comparative review of corrosion-resistant coatings on metal bipolar plates of proton exchange membrane fuel cells

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Abstract

Abstract

In the realm of proton exchange membrane fuel cells (PEMFCs), the bipolar plates (BPs) are indispensable and serve pivotal roles in distributing reactant gases, collecting current, facilitating product water removal, and cooling the stack. Metal BPs, characterized by outstanding manufacturability, cost-effectiveness, higher power density, and mechanical strength, are emerging as viable alternatives to traditional graphite BPs. The foremost challenge for metal BPs lies in enhancing their corrosion resistance and conductivity under acidic conditions, necessitating the application of various coatings on their surfaces to ensure superior performance. This review summarizes and compares recent advancements in the research of eight distinct types of coatings for BPs in PEMFCs, including noble metal, carbide, nitride, and amorphous carbon (a-C)/metal compound composite coatings. The various challenges encountered in the manufacturing and future application of these coatings are also delineated.
- proton exchange membrane fuel cells;
- metallic bipolar plate;
- coatings;
- corrosion resistance;
- interfacial contact resistance

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References(81)

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质子交换膜燃料电池用金属双极板表面耐腐蚀涂层的研究进展

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Comparative review of corrosion-resistant coatings on metal bipolar plates of proton exchange membrane fuel cells

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