富镍层状氧化物及锂离子电池正极材料研究进展

Boyang Fu; Maciej Moździerz; Andrzej Kulka; Konrad Świerczek

doi:10.1007/s12613-024-2948-y

Volume 31 Issue 11

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文章导航 > 矿物冶金与材料学报（英文） > 2024 > 31(11): 2345-2367

Boyang Fu, Maciej Moździerz, Andrzej Kulka, and Konrad Świerczek, Recent progress in Ni-rich layered oxides and related cathode materials for Li-ion cells, Int. J. Miner. Metall. Mater., 31(2024), No. 11, pp. 2345-2367. https://doi.org/10.1007/s12613-024-2948-y

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Boyang Fu, Maciej Moździerz, Andrzej Kulka, and Konrad Świerczek, Recent progress in Ni-rich layered oxides and related cathode materials for Li-ion cells, Int. J. Miner. Metall. Mater., 31(2024), No. 11, pp. 2345-2367. https://doi.org/10.1007/s12613-024-2948-y

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富镍层状氧化物及锂离子电池正极材料研究进展

1)
Faculty of Energy and Fuels, AGH University of Krakow, al. A. Mickiewicza 30, 30-059 Krakow, Poland
2)
AGH Centre of Energy, AGH University of Krakow, ul. Czarnowiejska 36, 30-054 Krakow, Poland

通讯作者:
Konrad Świerczek E-mail: xi@agh.edu.pl

中文摘要

毫无疑问，近年来富镍层状正极材料的巨大进步对于推动锂离子电池(LIB)技术的发展至关重要。在能量密度、可循环性、充电速度、降低成本以及安全性和稳定性方面取得的进步，已经为LIB的广泛采用做出了贡献，如今它已从移动电子产品、电动工具和电动汽车扩展到新的应用范围，包括电网存储解决方案等。因为大量关于富镍氧化物的论文和广泛的综述已经发表了，本综述更多地关注参考文献中提出的最新进展和新思想。本文涵盖的主题包括掺杂和成分优化，先进涂层，浓度梯度和单晶材料，以及新电解质及其改性的创新和富镍阴极在固态电池中的应用。文章简要介绍了相关的正极材料，并提出了高熵方法和零应变概念。对尚未解决的问题进行了批判性的概述，并对进一步的研究方向和预期的成果提出了看法。

关键词:

ReviewOpen Access

Recent progress in Ni-rich layered oxides and related cathode materials for Li-ion cells

+ Author Affiliations

1)
Faculty of Energy and Fuels, AGH University of Krakow, al. A. Mickiewicza 30, 30-059 Krakow, Poland
2)
AGH Centre of Energy, AGH University of Krakow, ul. Czarnowiejska 36, 30-054 Krakow, Poland

Konrad Świerczek is the Executive Editor-in-Chief of this journal and was not involved in the editorial review or the decision to publish this article. All authors declare that they have no conflicts of interest.
Open Access Funding provided by the Poland ICM.
Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons licensee, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/ by/4.0/.

Corresponding author:
Konrad Świerczek E-mail: xi@agh.edu.pl
Received: 23 March 2024; Revised: 27 May 2024; Accepted: 31 May 2024; Available online: 4 June 2024

Abstract

Abstract

Undoubtedly, the enormous progress observed in recent years in the Ni-rich layered cathode materials has been crucial in terms of pushing boundaries of the Li-ion battery (LIB) technology. The achieved improvements in the energy density, cyclability, charging speed, reduced costs, as well as safety and stability, already contribute to the wider adoption of LIBs, which extends nowadays beyond mobile electronics, power tools, and electric vehicles, to the new range of applications, including grid storage solutions. With numerous published papers and broad reviews already available on the subject of Ni-rich oxides, this review focuses more on the most recent progress and new ideas presented in the literature references. The covered topics include doping and composition optimization, advanced coating, concentration gradient and single crystal materials, as well as innovations concerning new electrolytes and their modification, with the application of Ni-rich cathodes in solid-state batteries also discussed. Related cathode materials are briefly mentioned, with the high-entropy approach and zero-strain concept presented as well. A critical overview of the still unresolved issues is given, with perspectives on the further directions of studies and the expected gains provided.
- lithium-ion batteries;
- cathode materials;
- nickel-rich layered oxides;
- recent progress;
- critical issues;
- improvement strategies

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富镍层状氧化物及锂离子电池正极材料研究进展

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Recent progress in Ni-rich layered oxides and related cathode materials for Li-ion cells

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