ZnO微纳米结构在温和条件下的形态工程及其光电应用

楚亮; 沈浩宇; 魏蝴蝶; 陈红钰; 马国强; 严文生

doi:10.1007/s12613-024-2965-x

Turn off MathJax

图(6)

数据统计

计量

文章访问数: 165
HTML全文浏览量: 81
PDF下载量: 6
被引次数: 0

文章导航 > 矿物冶金与材料学报（英文） > 2024 > 一校

Liang Chu, Haoyu Shen, Hudie Wei, Hongyu Chen, Guoqiang Ma, and Wensheng Yan, Morphology engineering of ZnO micro/nanostructures under mild conditions for optoelectronic application, Int. J. Miner. Metall. Mater.,(2024). https://doi.org/10.1007/s12613-024-2965-x

Cite this article as:

Liang Chu, Haoyu Shen, Hudie Wei, Hongyu Chen, Guoqiang Ma, and Wensheng Yan, Morphology engineering of ZnO micro/nanostructures under mild conditions for optoelectronic application, Int. J. Miner. Metall. Mater.,(2024). https://doi.org/10.1007/s12613-024-2965-x

Citation:

PDF( 2888 KB)

引用本文 PDF XML SpringerLink

研究论文

ZnO微纳米结构在温和条件下的形态工程及其光电应用

1)
杭州电子科技大学碳中和新能源研究院 & 电子信息学院, 杭州310018, 中国
2)
五邑大学应用物理与材料学院, 江门 529020, 中国

通讯作者:
楚亮    E-mail: chuliang@hud.edu.cn

马国强    E-mail: mgq1103@163.com

严文生    E-mail: wensheng.yan@hdu.edu.cn

文章亮点

(1) 开发了一种在低温甚至室温下制备ZnO微/纳米结构的简便溶液法

(2) 深入研究了合成过程中氨水添加量和反应温度对ZnO结构和形貌的影响机制

(3) ZnO微花应用于紫外探测器展现出良好的三维光捕获能力和光电探测性能

中文摘要

锌氧化物（ZnO）是一种重要的功能半导体，具有约3.37 eV的宽直接带隙。常采用溶剂热反应法合成ZnO微纳米结构，该方法成本低、操作简单且易于实现。此外，通过稍微改变反应过程中的条件，尤其是在室温下，ZnO的形态工程是被期望的。在本研究中，通过在低温（甚至室温）下改变氨水的添加量，在溶液中合成了ZnO微纳米结构。氨水能够在前驱体中形成Zn²⁺络合物，以控制反应速率，从而实现ZnO的形态工程，生成如纳米颗粒、纳米片、微花和单晶等不同形态。最终，ZnO微花和纳米片被应用于紫外探测器的光电应用中。

关键词:

Research Article

Morphology engineering of ZnO micro/nanostructures under mild conditions for optoelectronic application

+ Author Affiliations

Abstract

Abstract

Zinc oxide (ZnO) serves as a crucial functional semiconductor with a wide direct bandgap of approximately 3.37 eV. Solvothermal reaction is commonly used in the synthesis of ZnO micro/nanostructures, given its low cost, simplicity, and easy implementation. Moreover, ZnO morphology engineering has become desirable through the alteration of minor conditions in the reaction process, particularly at room temperature. In this work, ZnO micro/nanostructures were synthesized in a solution by varying the amounts of the ammonia added at low temperatures (including room temperature). The formation of Zn²⁺ complexes by ammonia in the precursor regulated the reaction rate of the morphology engineering of ZnO, which resulted in various structures, such as nanoparticles, nanosheets, microflowers, and single crystals. Finally, the obtained ZnO was used in the optoelectronic application of ultraviolet detectors.
- morphology engineering;
- low temperature;
- ZnO nanosheets;
- microflowers;
- ultraviolet detector

FullText(HTML)

Supplements(1)

Supplementary Information-s12613-024-2965-x.docx

References(27)

References

[1]	Y.D. Gu, W.J. Mai, and P. Jiang, Characterization of structural and electrical properties of ZnO tetrapods, Int. J. Miner. Metall. Mater., 18(2011), No. 6, p. 686. doi: 10.1007/s12613-011-0497-7
[2]	S. Suwanboon, P. Amornpitoksuk, P. Bangrak, and C. Randorn, Physical and chemical properties of multifunctional ZnO nanostructures prepared by precipitation and hydrothermal methods, Ceram. Int., 40(2014), No. 1, p. 975. doi: 10.1016/j.ceramint.2013.06.094
[3]	E. Moyen, J.H. Kim, J. Kim, and J. Jang, ZnO nanoparticles for quantum-dot-based light-emitting diodes, ACS Appl. Nano Mater., 3(2020), No. 6, p. 5203. doi: 10.1021/acsanm.0c00639
[4]	G.C. Park, S.M. Hwang, S.M. Lee, et al., Hydrothermally grown in-doped ZnO nanorods on p-GaN films for color-tunable heterojunction light-emitting-diodes, Sci. Rep., 5(2015), art. No. 10410. doi: 10.1038/srep10410
[5]	Y. Li, F. Della Valle, M. Simonnet, I. Yamada, and J.J. Delaunay, High-performance UV detector made of ultra-long ZnO bridging nanowires, Nanotechnology, 20(2009), No. 4, art. No. 045501. doi: 10.1088/0957-4484/20/4/045501
[6]	Y. Ning, Z.M. Zhang, F. Teng, and X.S. Fang, Novel transparent and self-powered UV photodetector based on crossed ZnO nanofiber array homojunction, Small, 14(2018), No. 13, art. No. 1703754. doi: 10.1002/smll.201703754
[7]	S.K. Gupta, A. Joshi, and M. Kaur, Development of gas sensors using ZnO nanostructures, J. Chem. Sci., 122(2010), No. 1, p. 57. doi: 10.1007/s12039-010-0006-y
[8]	S.J. Li, Y. Lin, W.W. Tan, et al., Preparation and performance of dye-sensitized solar cells based on ZnO-modified TiO₂ electrodes, Int. J. Miner. Metall. Mater., 17(2010), No. 1, p. 92. doi: 10.1007/s12613-010-0116-z
[9]	V. Consonni, J. Briscoe, E. Kärber, X. Li, and T. Cossuet, ZnO nanowires for solar cells: A comprehensive review, Nanotechnology, 30(2019), No. 36, art. No. 362001. doi: 10.1088/1361-6528/ab1f2e
[10]	P. Fan, D.Y. Zhang, Y. Wu, J.S. Yu, and T.P. Russell, Polymer-modified ZnO nanoparticles as electron transport layer for polymer-based solar cells, Adv. Funct. Mater., 30(2020), No. 32, art. No. 2002932. doi: 10.1002/adfm.202002932
[11]	K. Lim, W.S. Chow, and S.Y. Pung, Enhancement of thermal stability and UV resistance of halloysite nanotubes using zinc oxide functionalization via a solvent-free approach, Int. J. Miner. Metall. Mater., 26(2019), No. 6, p. 787. doi: 10.1007/s12613-019-1781-1
[12]	H.M. Shao, X.Y. Shen, X.T. Li, et al., Growth mechanism and photocatalytic evaluation of flower-like ZnO micro-structures prepared with SDBS assistance, Int. J. Miner. Metall. Mater., 28(2021), No. 4, p. 729. doi: 10.1007/s12613-020-2138-5
[13]	V. Gerbreders, M. Krasovska, E. Sledevskis, et al., Hydrothermal synthesis of ZnO nanostructures with controllable morphology change, CrystEngComm, 22(2020), No. 8, p. 1346. doi: 10.1039/C9CE01556F
[14]	L.V. Podrezova, S. Porro, V. Cauda, M. Fontana, and G. Cicero, Comparison between ZnO nanowires grown by chemical vapor deposition and hydrothermal synthesis, Appl. Phys. A, 113(2013), No. 3, p. 623. doi: 10.1007/s00339-013-7838-5
[15]	Y.P. Zhao, C.C. Li, M.M. Chen, et al., Growth of aligned ZnO nanowires via modified atmospheric pressure chemical vapor deposition, Phys. Lett. A, 380(2016), No. 47, p. 3993. doi: 10.1016/j.physleta.2016.06.030
[16]	Y.B. He, L.H. Wang, L. Zhang, et al., Solubility limits and phase structures in epitaxial ZnOS alloy films grown by pulsed laser deposition, J. Alloys Compd., 534(2012), p. 81. doi: 10.1016/j.jallcom.2012.04.040
[17]	Y. Zhou, D. Li, X.C. Zhang, J.L. Chen, and S.Y. Zhang, Facile synthesis of ZnO micro-nanostructures with controllable morphology and their applications in dye-sensitized solar cells, Appl. Surf. Sci., 261(2012), p. 759. doi: 10.1016/j.apsusc.2012.07.160
[18]	C.K. Xu, P. Shin, L.L. Cao, and D. Gao, Preferential growth of long ZnO nanowire array and its application in dye-sensitized solar cells, J. Phys. Chem. C, 114(2010), No. 1, p. 125. doi: 10.1021/jp9085415
[19]	Y.F. Gao, M. Nagai, T.C. Chang, and J.J. Shyue, Solution-derived ZnO nanowire array film as photoelectrode in dye-sensitized solar cells, Cryst. Growth Des., 7(2007), No. 12, p. 2467. doi: 10.1021/cg060934k
[20]	J.M. Wang and L. Gao, Synthesis and characterization of ZnO nanoparticles assembled in one-dimensional order, Inorg. Chem. Commun., 6(2003), No. 7, p. 877. doi: 10.1016/S1387-7003(03)00134-5
[21]	Y.F. Chen, X.J. Yang, and S.H. Zhou, Structure and photoluminescence of ZnO/niobate composites self-assembled from Zn (NH₃) ${}_{4}^{2+} $ solution with different pH and contents, J. Non-Cryst. Solids, 356(2010), No. 9-10, p. 509. doi: 10.1016/j.jnoncrysol.2009.12.020
[22]	G. Sathishkumar, C. Rajkuberan, K. Manikandan, S. Prabukumar, J. DanielJohn, and S. Sivaramakrishnan, Facile biosynthesis of antimicrobial zinc oxide (ZnO) nanoflakes using leaf extract of Couroupita guianensis Aubl. , Mater. Lett., 188(2017), p. 383.
[23]	H. Savaloni and R. Savari, Nano-structural variations of ZnO: N thin films as a function of deposition angle and annealing conditions: XRD, AFM, FESEM and EDS analyses, Mater. Chem. Phys., 214(2018), p. 402. doi: 10.1016/j.matchemphys.2018.04.099
[24]	J. Safaei and G.X. Wang, Progress and prospects of two-dimensional materials for membrane-based osmotic power generation, Nano Res. Energy, 1(2022), art. No. e9120008. doi: 10.26599/NRE.2022.9120008
[25]	Z. Chen, J.F. Li, T.Z. Li, et al., A CRISPR/Cas12a-empowered surface plasmon resonance platform for rapid and specific diagnosis of the Omicron variant of SARS–CoV–2, Natl. Sci. Rev., 9(2022), No. 8, art. No. nwac104. doi: 10.1093/nsr/nwac104
[26]	X.H. Zhang, X.Y. Han, J. Su, Q. Zhang, and Y.H. Gao, Well vertically aligned ZnO nanowire arrays with an ultra-fast recovery time for UV photodetector, Appl. Phys. A, 107(2012), No. 2, p. 255. doi: 10.1007/s00339-012-6886-6
[27]	D. Gedamu, I. Paulowicz, S. Kaps, et al., Rapid fabrication technique for interpenetrated ZnO nanotetrapod networks for fast UV sensors, Adv. Mater., 26(2014), No. 10, p. 1541. doi: 10.1002/adma.201304363

Relative Articles

Cited By

Proportional views

数据统计

姓名
邮箱
手机号码
标题
留言内容
验证码

留言板

数据统计

分享

计量

ZnO微纳米结构在温和条件下的形态工程及其光电应用

文章亮点

中文摘要

Morphology engineering of ZnO micro/nanostructures under mild conditions for optoelectronic application

Abstract

References

数据统计

Catalog