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Volume 31 Issue 11
Nov.  2024
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文章导航 >  矿物冶金与材料学报（英文）  > 2024  >  31(11): 2508-2517
Yahong Zhang, Yi Zhang, Huimin Liu, Dan Li, Yibo Wang, Chunchao Xu, Yuping Tian,  and Hongjie Meng, TiN/Fe2N/C composite with stable and broadband high-temperature microwave absorption, Int. J. Miner. Metall. Mater., 31(2024), No. 11, pp. 2508-2517. https://doi.org/10.1007/s12613-024-2972-y
Cite this article as:
Yahong Zhang, Yi Zhang, Huimin Liu, Dan Li, Yibo Wang, Chunchao Xu, Yuping Tian,  and Hongjie Meng, TiN/Fe2N/C composite with stable and broadband high-temperature microwave absorption, Int. J. Miner. Metall. Mater., 31(2024), No. 11, pp. 2508-2517. https://doi.org/10.1007/s12613-024-2972-y
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研究论文

具有稳定且宽频高温微波吸收性能的TiN/Fe2N/C复合材料

  • 1)

    河南大学化学与分子科学学院, 开封 475004, 中国

  • 2)

    许昌学院化工与材料学院表面微纳米材料研究所, 河南省微纳米能量储存与转换材料重点实验室, 许昌 461000, 中国

  • 3)

    河南大学能源科学与技术学院, 郑州 450046, 中国



  • 通讯作者:

    田玉平    E-mail: tianyuping@vip.henu.edu.cn

    孟红杰    E-mail: menghongjie@sjtu.edu.cn

文章亮点

  • (1) 采用静电纺丝技术和高温氮化工艺，制备了一系列一维TiN/Fe2N/C复合材料。
  • (2) 一维TiN/Fe2N/C纤维互相搭接，构建出丰富的导电网络，产生可观的导电损耗。
  • (3) 在稳定介电损耗和优异阻抗匹配的协同作用下，TiN/Fe2N/C复合材料表现出优异稳定的高温吸波性能。
  • 面对复杂多变的高温环境，电磁波吸波材料保持稳定高效的吸波性能是必不可少的。本文采用静电纺丝技术和随后的高温氮化工艺，制备了一系列TiN/Fe2N/C复合材料，并对高温吸波性能进行了详细的研究。在制备的复合材料中，TiN/Fe2N/C纤维互相搭接，构建了复杂且发达的导电网络，在电磁场中能够引起可观的导电损耗。与此同时，不同组分之间的非均质界面产生了显著的界面极化。此外，在氮化过程中产生的缺陷部位也会出现了偶极子极化现象。在稳定介电损耗和优异阻抗匹配的协同作用下，TiN/Fe2N/C复合材料在293~453 K的宽温度范围内表现出优异稳定的吸收性能，且在2.1 mm和373 K下，样品TiN/Fe2N/C-15的最小反射损耗高达−48.01 dB，有效吸收带宽可达3.64 GHz。这项工作为开发复杂多变高温条件下高效稳定的电磁波吸收材料提供了新的思路。
    • Research Article

    TiN/Fe2N/C composite with stable and broadband high-temperature microwave absorption

    + Author Affiliations
      Abstract
    • Facing the complex variable high-temperature environment, electromagnetic wave (EMW) absorbing materials maintaining high stability and satisfying absorbing properties is essential. This study focused on the synthesis and EMW absorbing performance evaluation of TiN/Fe2N/C composite materials, which were prepared using electrostatic spinning followed by a high-temperature nitridation process. The TiN/Fe2N/C fibers constructed a well-developed conductive network that generates considerable conduction loss. The heterogeneous interfaces between different components generated a significant level of interfacial polarization. Thanks to the synergistic effect of stable dielectric loss and optimized impedance matching, the TiN/Fe2N/C composite materials demonstrated excellent and stable absorption performance across a wide temperature range (293–453 K). Moreover, TiN/Fe2N/C-15 achieved a minimum reflection loss (RL) of −48.01 dB and an effective absorption bandwidth (EAB) of 3.64 GHz at 2.1 mm and 373 K. This work provides new insights into the development of high-efficiency and stabile EMW absorbing materials under complex variable high-temperature conditions.
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