铜铁矿AgFeO<sub>2</sub>纳米粒子用于超级电容器电极的电化学性能

Choulong Veann; Thongsuk Sichumsaeng; Ornuma Kalawa; Narong Chanlek; Pinit Kidkhunthod; Santi Maensiri

doi:10.1007/s12613-024-2992-7

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文章导航 > 矿物冶金与材料学报（英文） > 2025 > 32(1): 201-213

Choulong Veann, Thongsuk Sichumsaeng, Ornuma Kalawa, Narong Chanlek, Pinit Kidkhunthod, and Santi Maensiri, Structure and electrochemical performance of delafossite AgFeO₂ nanoparticles for supercapacitor electrodes, Int. J. Miner. Metall. Mater., 32(2025), No. 1, pp. 201-213. https://doi.org/10.1007/s12613-024-2992-7

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Choulong Veann, Thongsuk Sichumsaeng, Ornuma Kalawa, Narong Chanlek, Pinit Kidkhunthod, and Santi Maensiri, Structure and electrochemical performance of delafossite AgFeO2 nanoparticles for supercapacitor electrodes, Int. J. Miner. Metall. Mater., 32(2025), No. 1, pp. 201-213. https://doi.org/10.1007/s12613-024-2992-7

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研究论文

铜铁矿AgFeO₂纳米粒子用于超级电容器电极的电化学性能

1)
School of Physics, Institute of Science, Suranaree University of Technology, Nakhon Ratchasima 30000, Thailand
2)
SUT Center of Excellence on Advanced Functional Materials, Suranaree University of Technology, Nakhon Ratchasima 30000, Thailand
3)
Synchrotron Light Research Institute, Nakhon Ratchasima 30000, Thailand
4)
Department of Physics, Universitas Negeri Malang, Malang 65145, Indonesia

通讯作者:
Choulong Veann E-mail: veannchoulong168@gmail.com

中文摘要

采用简单的共沉淀法成功制备了具有2H和3R相混合六方结构的铜铁矿AgFeO₂纳米粒子。将所得前驱体在100、200、300、400和500°C的温度下煅烧，以获得铜铁矿AgFeO₂相。通过场发射扫描电子显微镜（FESEM）、透射电子显微镜（TEM）、Brunauer-Emmett-Teller N₂吸附–解吸、X射线吸收光谱（XAS）和X射线光电子能谱（XPS）技术对制备的AgFeO₂样品的形态和微观结构进行了表征。采用三电极系统研究了铜铁矿AgFeO₂纳米粒子在3 M KOH电解质中的电化学性能。在100°C下煅烧的铜铁矿AgFeO₂纳米粒子（AFO100）显示出的高比表面积（28.02 m²∙g^–1）和出色的电化学性能，在电流密度为1 A∙g^–1时比电容为229.71 F∙g^–1，在扫描速率为2 mV∙s⁻¹时比容量为358.32 F∙g⁻¹，且在1000次充电/放电循环后，电容保持率为82.99%，比功率和比能量值分别为797.46 W∙kg⁻¹和72.74 Wh∙kg⁻¹。这些发现表明，铜铁矿AgFeO₂作为超级电容器应用的电极材料具有巨大的潜力。

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Research Article

Structure and electrochemical performance of delafossite AgFeO₂ nanoparticles for supercapacitor electrodes

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Abstract

Abstract

Delafossite AgFeO₂ nanoparticles with a mixture of 2H and 3R phases were successfully fabricated by using a simple co-precipitation method. The resulting precursor was calcined at temperatures of 100, 200, 300, 400, and 500°C to obtain the delafossite AgFeO₂ phase. The morphology and microstructure of the prepared AgFeO₂ samples were characterized by using field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), N₂ adsorption/desorption, X-ray absorption spectroscopy (XAS), and X-ray photoelectron spectroscopy (XPS) techniques. A three-electrode system was employed to investigate the electrochemical properties of the delafossite AgFeO₂ nanoparticles in a 3 M KOH electrolyte. The delafossite AgFeO₂ nanoparticles calcined at 100°C (AFO100) exhibited the highest surface area of 28.02 m²∙g⁻¹ and outstanding electrochemical performance with specific capacitances of 229.71 F∙g⁻¹ at a current density of 1 A∙g⁻¹ and 358.32 F∙g⁻¹ at a scan rate of 2 mV∙s⁻¹. This sample also demonstrated the capacitance retention of 82.99% after 1000 charge/discharge cycles, along with superior specific power and specific energy values of 797.46 W∙kg⁻¹ and 72.74 Wh∙kg⁻¹, respectively. These findings indicate that delafossite AgFeO₂ has great potential as an electrode material for supercapacitor applications.
- nanoparticles;
- delafossite;
- electrochemical properties;
- X-ray absorption spectroscopy;
- co-precipitation;
- supercapacitor

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铜铁矿AgFeO₂纳米粒子用于超级电容器电极的电化学性能

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Structure and electrochemical performance of delafossite AgFeO₂ nanoparticles for supercapacitor electrodes

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铜铁矿AgFeO2纳米粒子用于超级电容器电极的电化学性能

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Structure and electrochemical performance of delafossite AgFeO2 nanoparticles for supercapacitor electrodes

Abstract

References

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铜铁矿AgFeO₂纳米粒子用于超级电容器电极的电化学性能

Structure and electrochemical performance of delafossite AgFeO₂ nanoparticles for supercapacitor electrodes