构建片状NiCo<sub>2</sub>O<sub>4</sub>/还原氧化石墨烯/三聚氰胺碳泡沫作为性能优异的微波吸收剂

田恐虎; 杨航; 张超; 疏瑞文; 邵群; 刘晓薇; 高凯鹏

doi:10.1007/s12613-024-3008-3

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文章导航 > 矿物冶金与材料学报（英文） > 2024 > 一校

Konghu Tian, Hang Yang, Chao Zhang, Ruiwen Shu, Qun Shao, Xiaowei Liu, and Kaipeng Gao, Fabrication of flake-like NiCo₂O₄/reduced graphene oxide/melamine-derived carbon foam as an excellent microwave absorber, Int. J. Miner. Metall. Mater.,(2024). https://doi.org/10.1007/s12613-024-3008-3

Cite this article as:

Konghu Tian, Hang Yang, Chao Zhang, Ruiwen Shu, Qun Shao, Xiaowei Liu, and Kaipeng Gao, Fabrication of flake-like NiCo2O4/reduced graphene oxide/melamine-derived carbon foam as an excellent microwave absorber, Int. J. Miner. Metall. Mater.,(2024). https://doi.org/10.1007/s12613-024-3008-3

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研究论文

构建片状NiCo₂O₄/还原氧化石墨烯/三聚氰胺碳泡沫作为性能优异的微波吸收剂

1)
安徽理工大学第一附属医院 (淮南市第一人民医院), 淮南 232001, 中国
2)
安徽理工大学分析测试中心, 淮南 232001, 中国
3)
安徽理工大学材料科学与工程学院, 淮南 232001, 中国
4)
安徽理工大学化工与爆破学院, 淮南 232001, 中国

通讯作者:
田恐虎    E-mail: tkhsuper@163.com

张超    E-mail: chaozhang@mail.bnu.edu.cn

疏瑞文    E-mail: austshuruiwen@126.com

文章亮点

(1) 采用溶剂热法和热解法制备了FNC/RGO/MDCF复合材料。

(2) 通过成分优化和结构设计制备出片状NiCo₂O₄。

(3) FNC/RGO/MDCF的最佳RL_min为−66.44 dB，厚度为2.29 mm。

(4) 在低厚度范围内（1.00–2.80mm），其EAB覆盖整个X和Ku波段。

中文摘要

具有三维结构的碳基泡沫可以作为合理设计和可控制备金属氧化物/碳基复合微波吸收材料的轻量化模板，通过科学选材和特殊结构设计，利用组分间的协同效应可以提高微波吸收材料（MAMs）的综合吸波性能。在本研究中，通过溶剂热和高温热解相结合，成功制备了片状钴酸镍/还原氧化石墨烯/三聚氰胺衍生碳泡沫（FNC/RGO/MDCF）。通过对FNC/RGO/MDCF复合材料的形貌和结构分析，RGO在MDCF骨架中分布均匀，为FNC在其表面的负载生长提供了有效支撑。对该复合材料进行微波吸收性能分析，发现样品S3（S3为溶剂热法制备16 h的FNC/RGO/MDCF复合材料）在厚度为2.29 mm处的最佳反射损耗（RL_min）为−66.44 dB。当厚度在1.50 mm时，最佳有效吸收带宽（EAB）为3.84 GHz。对FNC/RGO/MDCF的吸收机理分析表明，FNC/RGO/MDCF优异的吸波性能主要是由传导损耗、多次反射、散射、界面极化和偶极极化共同作用的结果。

关键词:

Research Article

Fabrication of flake-like NiCo₂O₄/reduced graphene oxide/melamine-derived carbon foam as an excellent microwave absorber

+ Author Affiliations

1)
The First Affiliated Hospital of Anhui University of Science and Technology (Huainan First People’s Hospital), Huainan 232001, China
2)
Analysis and Test Center, Anhui University of Science and Technology, Huainan 232001, China
3)
School of Materials Science and Engineering, Anhui University of Science and Technology, Huainan 232001, China
4)
School of Chemical and Blasting Engineering, Anhui University of Science and Technology, Huainan 232001, China

The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Corresponding authors:
Konghu Tian    E-mail: tkhsuper@163.com

Chao Zhang    E-mail: chaozhang@mail.bnu.edu.cn

Ruiwen Shu    E-mail: austshuruiwen@126.com
Received: 28 June 2024; Revised: 11 September 2024; Accepted: 11 September 2024; Available online: 12 September 2024

Abstract

Abstract

Carbon-based foams with a three-dimensional structure can serve as a lightweight template for the rational design and controllable preparation of metal oxide/carbon-based composite microwave absorption materials. In this study, a flake-like nickel cobaltate/reduced graphene oxide/melamine-derived carbon foam (FNC/RGO/MDCF) was successfully fabricated through a combination of solvothermal treatment and high-temperature pyrolysis. Results indicated that RGO was evenly distributed in the MDCF skeleton, providing effective support for the load growth of FNC on its surface. Sample S3, the FNC/RGO/MDCF composite prepared by solvothermal method for 16 h, exhibited a minimum reflection loss (RL_min) of −66.44 dB at a thickness of 2.29 mm. When the thickness was reduced to 1.50 mm, the optimal effective absorption bandwidth was 3.84 GHz. Analysis of the absorption mechanism of FNC/RGO/MDCF revealed that its excellent absorption performance was primarily attributed to the combined effects of conduction loss, multiple reflection, scattering, interface polarization, and dipole polarization.
- carbon foam;
- reduced graphene oxide;
- flake-like nickel cobaltate;
- microwave absorbing materials

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构建片状NiCo₂O₄/还原氧化石墨烯/三聚氰胺碳泡沫作为性能优异的微波吸收剂

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Fabrication of flake-like NiCo₂O₄/reduced graphene oxide/melamine-derived carbon foam as an excellent microwave absorber

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构建片状NiCo2O4/还原氧化石墨烯/三聚氰胺碳泡沫作为性能优异的微波吸收剂

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中文摘要

Fabrication of flake-like NiCo2O4/reduced graphene oxide/melamine-derived carbon foam as an excellent microwave absorber

Abstract

References

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构建片状NiCo₂O₄/还原氧化石墨烯/三聚氰胺碳泡沫作为性能优异的微波吸收剂

Fabrication of flake-like NiCo₂O₄/reduced graphene oxide/melamine-derived carbon foam as an excellent microwave absorber