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Volume 2 Issue 2
Sep.  1995
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CHENG GUOGUANGand ZHANG JIAN, CALCULATING MODEL OF MASS ACTION CONCENTRATIONS FOR Cd-Sb ALLOY MELT, J. Univ. Sci. Technol. Beijing, 2(1995), No. 2, pp. 92-96.
Cite this article as:
CHENG GUOGUANGand ZHANG JIAN, CALCULATING MODEL OF MASS ACTION CONCENTRATIONS FOR Cd-Sb ALLOY MELT, J. Univ. Sci. Technol. Beijing, 2(1995), No. 2, pp. 92-96.
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Cd—Sb合金熔体作用浓度计算模型

  • 根据Cd-Sn合金相图、电阻率、热容量、偏摩尔熵和粘度,确定该合金熔体的结构单元为Cd原子,Sb原子以及Cd3Sb2,Cd4Sb3和CdSb化合物。基于以上结构单元,并依据含化合物金属熔体的共存理论,推导了Cd-Sb合金熔体的作用浓度计算模型。理论计算的NCd,与实测的Cd的活度值aCd,完全一致。同时也计算出了以上3种化合物的标准自由能。
  • CALCULATING MODEL OF MASS ACTION CONCENTRATIONS FOR Cd-Sb ALLOY MELT

    + Author Affiliations
    • According to the Cd-Sb alloy phase diagram, resistivity, heat capacity, partial molar entropy and viscosity,the structural units of this alloy melt have been determined as Cd and Sb atoms as well as Cd3Sb2, Cd4Sb3 and CdSb compounds.Based on these structural units and the coexistence theory of metallic melt structure involing compound formation,a calculating model of mass action concentrations has been deduced.The calculated mass action concentrations NCd are in good agreement with measured activities aCd. The Gibbs standard free energy of formatioin for above three compunds have been obtained too.
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