Effects of basicity and MgO content on the viscosity of the SiO₂-CaO-MgO-9wt%Al₂O₃ slag system

The effects of basicity and MgO content on the viscosity of SiO₂-CaO-MgO-9wt%Al₂O₃ slags with basicity from 0.4 to 1.0 and MgO content from 13wt% to 19wt% were investigated using the rotating cylinder method. A correlation between the viscosity and the slag structure was determined by Fourier transform infrared (FTIR) spectroscopy. It is indicated that the complex network structure of the slag melt is depolymerized into simpler network units with increasing basicity or MgO content, resulting in a continuous decrease in viscosity of the slag. The viscosity is strongly dependent on the combined action of basic oxide components in the slag. Under the present experimental conditions, increasing the basicity is found to be more effective than increasing the MgO content in decreasing the viscosity of the slag. At higher temperatures, the increase of basicity or MgO content does not appreciably decrease the viscosity of the slag, as it does at lower temperatures. The calculated activation energy of viscous flow is between 154 and 200 kJ·mol⁻¹, which decreases with an increase in basicity from 0.4 to 1.0 at a fixed MgO content in the range of 13wt% to 19wt%.