Shi-xian Zhao, Bin-li Cai, Hong-gang Sun, Gang Wang, Hong-xia Li, and Xiao-yan Song, Thermodynamic simulation of the effect of slag chemistry on the corrosion behavior of alumina–chromia refractory, Int. J. Miner. Metall. Mater., 23(2016), No. 12, pp.1458-1465. https://dx.doi.org/10.1007/s12613-016-1370-5
Cite this article as:
Shi-xian Zhao, Bin-li Cai, Hong-gang Sun, Gang Wang, Hong-xia Li, and Xiao-yan Song, Thermodynamic simulation of the effect of slag chemistry on the corrosion behavior of alumina–chromia refractory, Int. J. Miner. Metall. Mater., 23(2016), No. 12, pp.1458-1465. https://dx.doi.org/10.1007/s12613-016-1370-5
Shi-xian Zhao, Bin-li Cai, Hong-gang Sun, Gang Wang, Hong-xia Li, and Xiao-yan Song, Thermodynamic simulation of the effect of slag chemistry on the corrosion behavior of alumina–chromia refractory, Int. J. Miner. Metall. Mater., 23(2016), No. 12, pp.1458-1465. https://dx.doi.org/10.1007/s12613-016-1370-5
Cite this article as:
Shi-xian Zhao, Bin-li Cai, Hong-gang Sun, Gang Wang, Hong-xia Li, and Xiao-yan Song, Thermodynamic simulation of the effect of slag chemistry on the corrosion behavior of alumina–chromia refractory, Int. J. Miner. Metall. Mater., 23(2016), No. 12, pp.1458-1465. https://dx.doi.org/10.1007/s12613-016-1370-5
1) State Key Laboratory of Advanced Refractories, Sinosteel Luoyang Institute of Refractories Research Co., Ltd., Luoyang, 471039, China
2) School of Materials Science and Engineering, Beijing University of Technology, Beijing, 100124, China
Funds:
This work was financially supported by the Preliminary Research Project for National Basic Research Program of China (No. 2012CB724607) and the Research Planning Project of Basic and Advanced Technology of Henan Province, China (No.162300410043).
Received:
19 July 2016;
Revised:
08 September 2016;
Accepted:
11 September 2016;
The corrosion behavior of alumina–chromia refractory against two kinds of industrial slags (coal slag and iron smelting slag) at 1550°C was investigated via thermodynamic simulations. In the proposed simulation model, the initial slag first attacks the matrix and surface aggregates and subsequently attacks the inner aggregates. The simulation results indicate that the slag chemistry strongly affects the phase formation and corrosion behavior of the refractory brick. Greater amounts of alumina were dissolved and spinel solid phases formed when the brick interacted with iron smelting slag. These phenomena, as well as the calculated lower viscosity, may lead to much deeper penetration than that exhibited by coal slag and to more severe corrosion compared to that induced by coal slag. The thermodynamic calculations well match the experimental observations, demonstrating the efficiency of the proposed simulation model for evaluating the corrosion behavior of alumina–chromia refractory.
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