Jian-bin Zhuand Hong Yan, Microstructure and properties of mullite-based porous ceramics produced from coal fly ash with added Al2O3, Int. J. Miner. Metall. Mater., 24(2017), No. 3, pp. 309-315. https://doi.org/10.1007/s12613-017-1409-2
Cite this article as:
Jian-bin Zhuand Hong Yan, Microstructure and properties of mullite-based porous ceramics produced from coal fly ash with added Al2O3, Int. J. Miner. Metall. Mater., 24(2017), No. 3, pp. 309-315. https://doi.org/10.1007/s12613-017-1409-2
Research Article

Microstructure and properties of mullite-based porous ceramics produced from coal fly ash with added Al2O3

+ Author Affiliations
  • Corresponding author:

    Hong Yan    E-mail: hyan@ncu.edu.cn

  • Received: 11 July 2016Revised: 1 November 2016Accepted: 2 November 2016
  • Using coal fly ash slurry samples supplemented with different amounts of Al2O3, we fabricated mullite-based porous ceramics via a dipping-polymer-replica approach, which is a popular method suitable for industrial application. The microstructure, phase composition, and compressive strength of the sintered samples were investigated. Mullite was identified in all of the prepared materials by X-ray diffraction analysis. The microstructure and compressive strength were strongly influenced by the content of Al2O3. As the Al/Si mole ratio in the starting materials was increased from 0.84 to 2.40, the amount of amorphous phases in the sintered microstructure decreased and the compressive strength of the sintered samples increased. A further increase in the Al2O3 content resulted in a decrease in the compressive strength of the sintered samples. The mullite-based porous ceramic with an Al/Si molar ratio of 2.40 exhibited the highest compressive strength and the greatest shrinkage among the investigated samples prepared using coal fly ash as the main starting material.
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  • [1]
    X.G. Deng, J.K. Wang, J.H. Liu, H.J. Zhang, F.L. Li, H.J. Duan, L.L Lu, Z. Huang, W.G. Zhao, and S.W. Zhang, Preparation and characterization of porous mullite ceramics via foam-gelcasting, Ceram. Int., 41(2015), No. 7, p. 9009.
    [2]
    M.H. Talou and M.A. Camerucci, Processing of porous mullite ceramics using novel routes by starch consolidation casting, J. Eur. Ceram. Soc., 35(2015), No. 3, p. 1021.
    [3]
    M.L. Chen, L. Zhu, Y.C. Dong, L.L. Li, and J. Liu, Waste-to-resource strategy to fabricate highly porous whisker-structured mullite ceramic membrane for simulated oil-in-water emulsion wastewater treatment, ACS Sustain. Chem. Eng., 4(2016), No. 4, p. 2098.
    [4]
    G.L. Chen, H. Qi, W.H. Xing, and N.P. Xu, Direct preparation of macroporous mullite supports for membranes by in situ reaction sintering, J. Membr. Sci., 318(2008), No. 1-2, p. 38.
    [5]
    Y.C. Dong, S. Hampshire, J.E. Zhou, B. Lin, Z.L. Ji, X.Z. Zhang, and G.Y. Meng, Recycling of fly ash for preparing porous mullite membrane supports with titania addition, J. Hazard. Mater., 180(2010), No. 1-3, p. 173.
    [6]
    J.J. Cao, X.F. Dong, L.L. Li, Y.C. Dong, and S. Hampshire, Recycling of waste fly ash for production of porous mullite ceramic membrane supports with increased porosity, J. Eur. Ceram. Soc., 34(2014), No. 13, p. 3181.
    [7]
    L. Zhu, Y.C. Dong, S. Hampshire, S. Cerneaux, and L. Winnubst, Waste-to-resource preparation of a porous ceramic membrane support featuring elongated mullite whiskers with enhanced porosity and permeance, J. Eur. Ceram. Soc., 35(2015), No. 2, p. 711.
    [8]
    L. Zhu, Y.C. Dong, L.L. Li, J. Liu, and S.J. You, Coal fly ash industrial waste recycling for fabrication of mullite-whisker-structured porous ceramic membrane supports, RSC Adv., 5(2015), No. 15, p. 11163.
    [9]
    H.R. Qian, Y.H. Wang, X.D. Cheng, H.P. Zhang, and R.F. Zhang, Preparation of porous mullite ceramics using fly ash cenosphere as a pore-forming agent by gelcasting process, Int. J. Appl. Ceram. Technol., 11(2014), No. 5, p. 858.
    [10]
    H.S. Guo, W.F. Li, and F.B. Ye, Low-cost porous mullite ceramic membrane supports fabricated from kyanite by casting and reaction sintering, Ceram. Int., 42(2016), No. 4, p. 4819.
    [11]
    J.H. Li, H.W. Ma, and W.H. Huang, Effect of V2O5 on the properties of mullite ceramics synthesized from high-aluminum fly ash and bauxite, J. Hazard. Mater., 166(2009), No. 2-3, p. 1535.
    [12]
    Q.K. Lü, X.F. Dong, Z.W. Zhu, and Y.C. Dong, Environment-oriented low-cost porous mullite ceramic membrane supports fabricated from coal gangue and bauxite, J. Hazard. Mater., 273(2014), No. 6, p. 136.
    [13]
    Z.P. Hou, B.X. Cui, L.L. Liu, and Q. Liu, Effect of the different additives on the fabrication of porous kaolin-based mullite ceramics, Ceram. Int., 42(2016), No. 15, p. 17254.
    [14]
    Y.C. Dong, J. Diwu, X.F. Feng, X.Y. Feng, X.Q. Liu, and G.Y. Meng, Phase evolution and sintering characteristics of porous mullite ceramics produced from the flyash-Al(OH)3 coating powders, J. Alloys Compd., 460(2008), No. 1-2, p. 651.
    [15]
    T.Y. Yang, H.B. Ji, S.Y. Yoon, B.K. Kim, and H.C. Park, Porous mullite composite with controlled pore structure processed using a freeze casting of TBA-based coal fly ash slurries, Resour. Conserv. Recycl., 54(2010), No. 11, p. 816.
    [16]
    J.H. Lee, H.J. Choi, S.Y. Yoon, B.K. Kim, and H. C. Park, Porous mullite ceramics derived from coal fly ash using a freeze-gel casting/polymer sponge technique, J. Porous Mater., 20(2013), No. 1, p. 219.
    [17]
    S.H. Li, H.Y. Du, A.R. Guo, and D. Yang, Preparation of self-reinforcement of porous mullite ceramics through in situ synthesis of mullite whisker in fly ash body, Ceram. Int., 38(2012), No. 2, p. 1027.
    [18]
    R.S. Blissett and N.A. Rowson, A review of the multi-component utilisation of coal fly ash, Fuel, 97(2012), p. 1.
    [19]
    S. Akpinar, I.M. Kusoglu, O. Ertugrul, and K. Onel, In situ mullite foam fabrication using microwave energy, J. Eur. Ceram. Soc., 32(2012), No. 4, p. 843.
    [20]
    Y.C. Dong, X.Y. Feng, X.F. Feng, Y.W. Ding, X.Q. Liu, and G.Y. Meng, Preparation of low-cost mullite ceramics from natural bauxite and industrial waste fly ash, J. Alloys Compd., 460(2008), No. 1-2, p. 599.
    [21]
    L.L. Li, X.F. Dong, Y.C. Dong, Y.M. Zheng, L. Zhu, and J. Liu, Thermal conversion of hazardous metal copper via the preparation of CuAl2O4 spinel-based ceramic membrane for potential stabilization of simulated copper-rich waste, ACS Sustain. Chem. Eng., 3(2015), No. 11, p. 2611.
    [22]
    L.L. Li, X.F Dong, Y.C. Dong, L. Zhu, S.J. You, and Y.F Wang, Incorporation of zinc for fabrication of low-cost spinel-based composite ceramic membrane support to achieve its stabilization, J. Hazard. Mater., 287(2015), p. 188.
    [23]
    J. Liu, Y.C. Dong, X.F. Dong, S. Hampshire, L. Zhu, Z.W. Zhu, and L.L. Li, Feasible recycling of industrial waste coal fly ash for preparation of anorthite-cordierite based porous ceramic membrane supports with addition of dolomite, J. Eur. Ceram. Soc., 36(2016), No. 4, p. 1059.
    [24]
    P. Sarin, W. Yoon, R.P. Haggerty, C. Chiritescu, N.C. Bhorkar, and W.M. Kriven, Effect of transition-metal-ion doping on high temperature thermal expansion of 3:2 mullite:an in situ, high temperature, synchrotron diffraction study, J. Eur. Ceram. Soc., 28(2008), No. 2, p. 353.
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