Berhe Goitom Gebreyohannes, Velázquez del Rosario Alberto, Abubeker Yimam, Girma Woldetinsae, and Bogale Tadesse, Alternative beneficiation of tantalite and removal of radioactive oxides from Ethiopian Kenticha pegmatite-spodumene ores, Int. J. Miner. Metall. Mater., 24(2017), No. 7, pp. 727-735. https://doi.org/10.1007/s12613-017-1456-8
Cite this article as:
Berhe Goitom Gebreyohannes, Velázquez del Rosario Alberto, Abubeker Yimam, Girma Woldetinsae, and Bogale Tadesse, Alternative beneficiation of tantalite and removal of radioactive oxides from Ethiopian Kenticha pegmatite-spodumene ores, Int. J. Miner. Metall. Mater., 24(2017), No. 7, pp. 727-735. https://doi.org/10.1007/s12613-017-1456-8
Research Article

Alternative beneficiation of tantalite and removal of radioactive oxides from Ethiopian Kenticha pegmatite-spodumene ores

+ Author Affiliations
  • Corresponding author:

    Berhe Goitom Gebreyohannes    E-mail: goitish2500@gmail.com

  • Received: 26 October 2016Revised: 10 December 2016Accepted: 13 December 2016
  • The beneficiation methods for Ethiopian Kenticha pegmatite-spodumene ores were assessed through mineralogical and quantitative analyses with X-ray diffraction (XRD) and energy-dispersive X-ray fluorescence (EDXRF). The tantalite in the upper zone of the Kenticha pegmatite-spodumene deposit is 58.7wt% higher than that in the inner zone. XRD analysis revealed that the upper zone is dominated by manganocolumbite, whereas the inner zone is predominantly tantalite-Mn. Repeated cleaning and beneficiation of the upper-zone ore resulted in concentrate compositions of 57.34wt% of Ta2O5 and 5.41wt% of Nb2O5. Washing the tantalite concentrates using 1vol% KOH and 1 M H2SO4 led to the removal of thorium and uranium radioactive oxides from the concentrate. The findings of this study suggest that the beneficiation and alkaline washing of Kenticha pegmatite-spodumene ores produce a high-grade export-quality tantalite concentrate with negligible radioactive oxides.
  • loading
  • [1]
    A.A. Baba, F.A. Adekola, O.I. Dele-Ige, and R.B. Bale, Investigation of dissolution kinetics of a Nigerian tantalite ore in nitric acid, J. Miner. Mater. Charact. Eng., 7(2007), No. 1, p. 83.
    [2]
    S. Bernstein, D. Frei, R.K. McLimans, C. Knudsen, and V.N. Vasudev, Application of CCSEM to heavy mineral deposits, Source of high-Ti ilmenite sand deposits of South Kerala beaches, SW India, J. Geochem. Explor., 96(2008), No. 1, p. 25.
    [3]
    F. Melcher, T. Graupner, H.E. Gäbler, M. Sitnikova, F. Henjes-Kunst, T. Oberthür, A. Gerdes, and S. Dewaele, Tantalum-(niobium-tin) mineralisation in African pegmatites and rare metal granites:Constraints from Ta-Nb oxide mineralogy, geochemistry and U-Pb geochronology, Ore Geol. Rev., 64(2015), p. 667.
    [4]
    M.O.H. Amuda, D.E. Esezobor, and G.I. Lawal, Adaptable technologies for life-cycle processing of tantalum bearing minerals, J. Miner. Mater. Charact. Eng., 6(2007), No. 1, p. 69.
    [5]
    H.H. Htwe and K.T. Lwin, Study on extraction of niobium oxide from columbite-tantalite concentrate, Int. J. Chem. Mol. Nucl. Mater. Metall. Eng., 2(2008), No. 10, p. 223.
    [6]
    E.V. Badanina, M.A. Sitnikova, V.V. Gordienko, F. Melcher, H.-E. Gäbler, J. Lodziak, and L.F. Syritso, Mineral chemistry of columbite-tantalite from spodumene pegmatites of Kolmozero, Kola Peninsula (Russia), Ore Geol. Rev., 64(2015), p. 720.
    [7]
    M. Van Lichtervelde, Rare-element pegmatites-from natural systems to the experimental lab, Mitt. Österr. Miner. Ges., 160(2014), p. 13.
    [8]
    H. Beurlen, A. Müller, D. Silva, and M.R.R. Da Silva, Petrogenetic significance of LA-ICP-MS trace-element data on quartz from the Borborema Pegmatite Province, northeast Brazil, Mineral. Mag., 75(2011), No. 5, p. 2703.
    [9]
    R.H. Mitchell, Primary and secondary niobium mineral deposits associated with carbonatites, Ore Geol. Rev., 64(2015), p. 626.
    [10]
    F. Melcher, M.A. Sitnikova, T. Graupner, N. Martin, T. Oberthür, F. Henjes-Kunst, E. Gäbler, A. Gerdes, H. Brätz, D.W. Davis, and S. Dewaele, Fingerprinting of conflict minerals:columbite-tantalite ("coltan") ores, SGA News, 2008, No. 23, p. 7.
    [11]
    A.L. Nikolaev, N.V. Kirichenko, and V.G. Maiorov, Niobium, tantalum, and titanium fluoride solutions, Russ. J. Inorg. Chem., 54(2009), No. 4, p. 505.
    [12]
    A.R. Adetunji, W.O. Siyanbola, I.I. Funtua, S.O.O. Olusunle, A.A. Afonja, and O.O. Adewoye, Assessment of beneficiation routes of tantalite ores from key locations in Nigeria, J. Miner. Mater. Charact. Eng., 4(2005), No. 2, p. 85.
    [13]
    D. Küster, R.L. Romer, D. Tolessa, D. Zerihun, K. Bheemalingeswara, F. Melcher, and T. Oberthür, The Kenticha rare-element pegamtite, Ethiopia:internal differntiation, U-Pb age and Ta mineralization, Miner. Deposita, 44(2009), p. 723.
    [14]
    E.J. Kim, S.Y. Kim, D.H. Moon, and S.M. Koh, Fractionation and rare-element mineralization of kenticha pegmatite, Southern Ethiopia, Econ. Environ. Geol., 46(2013), No. 5, p. 375.
    [15]
    P. Černý and T.S. Ercit, The classification of granitic pegmatites revisited, Can. Mineral., 43(2005), No. 6, p. 2005.
    [16]
    M.S. Mohammedyasin, Geology, geochemistry and geochronology of the Kenticha rare metal granite pegmatite, Adola Belt, southern Ethiopia:a review, Int. J. Geosci., 8(2017), p. 46.
    [17]
    S. Tadesse and D. Zerihun, Composition, fractionation trend and zoning accretion of the columbite-tantalite group of minerals in the Kenticha rare-metal field (Adola, southern Ethiopia), J. Afr. Earth Sci., 23(1996), No. 3, p. 411.
    [18]
    R. Burt, Beneficiation of tantalum ore-how it is achieved and could it be better?[in] Proceedings of the 125th TMS Annual Meeting and Exhibition, Anaheim, CA, 1996, p. 17.
    [19]
    M. Nete, W. Purcell, and J.T. Nel, Separation and isolation of tantalum and niobium from tantalite using solvent extraction and ion exchange, Hydrometallurgy, 149(2014), p. 31.
    [20]
    T.A. Theron, Quantification of Tantalum in Series of Tantalum-Containing Compounds[Dissertation], University of the Free State, Bloemfontein, 2010, p. 88.
    [21]
    O.M. El-Hussaini and M.A. Mahdy, Sulfuric acid leaching of Kab Amiri niobium-tantalum bearing minerals, Central Eastern Desert, Egypt, Hydrometallurgy, 64(2001), No. 3, p. 219.
    [22]
    X.H. Wang, S.L. Zhang, H.B. Xu, and Y. Zhang, Dissolution behaviors of Ta2O5, Nb2O5 and their mixture in KOH and H2O system, Trans. Nonferrous Met. Soc. China, 20(2010), No. 10, p. 2006.
    [23]
    O.M. EL-Husaini and M.N. EL-Hazek, Removal of radioactive elements from niobium and tantalum ores, Eur. J. Miner. Process. Environ. Prot., 5(2005), No. 1, p. 7.
    [24]
    M. Nete, F. Koko, T. Theron, W. Purcell, and J.T. Nel, Primary beneficiation of tantalite using magnetic separation and acid leaching, Int. J. Miner. Metall. Mater., 21(2014), No. 12, p. 1153.
    [25]
    O.M. El-Hussaini and M.A. Mahdy, Extraction of niobium and tantalum from nitrate and sulfate media by using MIBK, Miner. Process. Extr. Metall. Rev., 22(2010), p. 633.
    [26]
    D.A.R. Mackay and G.J. Simandl, Niobium and tantalum:Geology, markets, and supply chains,[in] Symposium on Critical and Strategic Materials, Victoria, British Columbia, 2015, p. 13.
    [27]
    M.J. Kabangu and P.L. Crouse, Separation of niobium and tantalum from Mozambican tantalite by ammonium bifluoride digestion and octanol solvent extraction, Hydrometallurgy, 129-130(2012), p. 151.
    [28]
    M. Nete, W. Purcell, E. Snyders, J.T. Nel, and G. Beukes, Characterization and alternative dissolution of tantalite mineral samples from Mozambique, J. South Afr. Inst. Min. Metall., 112(2011), No. 12, p. 1079.
    [29]
    X.H. Wang, S.L. Zheng, H.B. Xu, and Y. Zhang, Leaching of niobium and tantalum from a low-grade ore using a KOH roast-water leach system, Hydrometallurgy, 98(2009), No. 3-4, p. 219.
    [30]
    H.M. Zhou, S.L. Zheng, Y. Zhang, and D.Q. Yi, A kinetic study of the leaching of a low-grade niobium-tantalum ore by concentrated KOH solution, Hydrometallurgy, 80(2005), No. 3, p. 170.
    [31]
    D.A.R. Mackay and G.J. Simandl, Geology, market and supply chain of niobium and tantalum-a review, Miner. Deposita, 49(2014), p.1025.
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Share Article

    Article Metrics

    Article Views(567) PDF Downloads(30) Cited by()
    Proportional views

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return