Structural, morphological, and optical properties of tin(IV) oxide nanoparticles synthesized using <i>Camellia sinensis</i> extract:a green approach

J. Celina Selvakumari; M. Ahila; M. Malligavathy; D. Pathinettam Padiyan

doi:10.1007/s12613-017-1494-2

Volume 24 Issue 9

Sep. 2017

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Article Navigation > International Journal of Minerals, Metallurgy and Materials > 2017 > 24(9): 1043-1051

J. Celina Selvakumari, M. Ahila, M. Malligavathy, and D. Pathinettam Padiyan, Structural, morphological, and optical properties of tin(IV) oxide nanoparticles synthesized using Camellia sinensis extract:a green approach, Int. J. Miner. Metall. Mater., 24(2017), No. 9, pp. 1043-1051. https://doi.org/10.1007/s12613-017-1494-2

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J. Celina Selvakumari, M. Ahila, M. Malligavathy, and D. Pathinettam Padiyan, Structural, morphological, and optical properties of tin(IV) oxide nanoparticles synthesized using Camellia sinensis extract:a green approach, Int. J. Miner. Metall. Mater., 24(2017), No. 9, pp. 1043-1051. https://doi.org/10.1007/s12613-017-1494-2

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Research Article

Structural, morphological, and optical properties of tin(IV) oxide nanoparticles synthesized using Camellia sinensis extract:a green approach

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Corresponding author:
D. Pathinettam Padiyan E-mail: dppadiyan@msuniv.ac.in
Received: 28 November 2016; Revised: 26 April 2017; Accepted: 28 April 2017

Abstract

Abstract

Tin oxide (SnO₂) nanoparticles were cost-effectively synthesized using nontoxic chemicals and green tea (Camellia sinensis) extract via a green synthesis method. The structural properties of the obtained nanoparticles were studied using X-ray diffraction, which indicated that the crystallite size was less than 20 nm. The particle size and morphology of the nanoparticles were analyzed using scanning electron microscopy and transmission electron microscopy. The morphological analysis revealed agglomerated spherical nanoparticles with sizes varying from 5 to 30 nm. The optical properties of the nanoparticles' band gap were characterized using diffuse reflectance spectroscopy. The band gap was found to decrease with increasing annealing temperature. The O vacancy defects were analyzed using photoluminescence spectroscopy. The increase in the crystallite size, decreasing band gap, and the increasing intensities of the UV and visible emission peaks indicated that the green-synthesized SnO₂ may play future important roles in catalysis and optoelectronic devices.
- tin oxide;
- nanoparticles;
- Camellia sinensis;
- band gap;
- photoluminescence

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