Zuo-li Li, Jun Zhao, Jia-lin Sun, Feng Gong, and Xiu-ying Ni, Reinforcing effect of graphene on the mechanical properties of Al2O3/TiC ceramics, Int. J. Miner. Metall. Mater., 24(2017), No. 12, pp. 1403-1411. https://doi.org/10.1007/s12613-017-1533-z
Cite this article as:
Zuo-li Li, Jun Zhao, Jia-lin Sun, Feng Gong, and Xiu-ying Ni, Reinforcing effect of graphene on the mechanical properties of Al2O3/TiC ceramics, Int. J. Miner. Metall. Mater., 24(2017), No. 12, pp. 1403-1411. https://doi.org/10.1007/s12613-017-1533-z
Research Article

Reinforcing effect of graphene on the mechanical properties of Al2O3/TiC ceramics

+ Author Affiliations
  • Corresponding author:

    Jun Zhao    E-mail: zhaojun@sdu.edu.cn

  • Received: 10 April 2017Revised: 14 July 2017Accepted: 9 August 2017
  • Multilayer graphene (MLG)-reinforced Al2O3/TiC ceramics were fabricated through hot pressing sintering, and the reinforcing effect of MLG on the microstructure and mechanical properties of the composites was investigated by experiment and simulation. The simulation of dynamic crack initiation and propagation was investigated based on the cohesive zone method. The results show that the composite added with 0.2wt% MLG has excellent flexural strength and high fracture toughness. The major reinforcing mechanisms are the synergistic effect by strong and weak bonding interfaces, MLG pull-out, and grain refinement resulting from the addition of MLG. In addition, the aggravating of crack deflection, branching, blunting, and bridging have indispensable contribution to the improvement of the as-designed materials.
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  • [1]
    K. Zimmermann, G.A. Schneider, A.K. Bhattacharya, and W. Hintze, Surface modification of Al2O3/TiC cutting ceramics, J. Am. Ceram. Soc., 90(2007), No. 12, p. 3773.
    [2]
    Y.H. Fei, C.Z. Huang, H.L. Liu, and B. Zhou, Mechanical properties of Al2O3-TiC-TiN ceramic tool materials, Ceram. Int., 40(2014), No. 7, p. 10205.
    [3]
    K.F. Cai, D.S. Mclachlan, N. Axen, and R. Manyatsa, Preparation, microstructures and properties of Al2O3-TiC composites, Ceram. Int., 28(2002), No. 2, p. 217.
    [4]
    W.H. Tuan, R.Z. Chen, T.C. Wang, C.H. Cheng, and P.S. Kuo, Mechanical properties of Al2O3/ZrO2 composites, J. Eur. Ceram. Soc., 22(2002), No. 16, p. 2827.
    [5]
    S.X. Song, X. Ai, J. Zhao, and Q. Wu, Mechanical properties toughening and strengthening mechanisms of Al2O3/TiC nanocomposite, Mater. Mech. Eng., 27(2003), No. 12, p. 35.
    [6]
    Z.B. Yin, C.Z. Huang, B. Zou, H.L. Liu, H.T. Zhu, and J. Wang, Preparation and characterization of Al2O3/TiC micro-nano-composite ceramic tool materials, Ceram. Int., 39(2013), No. 4, p. 4253.
    [7]
    M.H. Bocanegra-Bernal, J. Echeberria, J. Ollo, A. Garcia-Reyes, C. Domínguez-Rios, A. Reyes-Rojas, and A. Aguilar-Elguezabal, A comparison of the effects of multi-wall and single-wall carbon nanotube additions on the properties of zirconia toughened alumina composites, Carbon, 49(2011), No. 5, p. 1599.
    [8]
    P. Michelis and J. Vlachopoulos, Complete CNT disentanglement-dispersion-functionalisation in a pulsating micro-structured reactor, Chem. Eng. Sci., 90(2013), No. 10, p. 10.
    [9]
    H. Porwal, S. Grasso, and M.J. Reece, Review of graphene-ceramic matrix composites, Adv. Appl. Ceram., 112(2013), No. 8, p. 443.
    [10]
    X. Jiang and L.T. Drzal, Multifunctional high density polyethylene nanocomposites produced by incorporation of exfoliated graphite nanoplatelets 1:Morphology and mechanical properties, Polym. Compos., 31(2009), No. 6, p. 1091.
    [11]
    A. Bianco, H.M. Cheng, T. Enoki, Y. Gogotsi, R.H. Hurt, N. Koratkar, T. Kyotani, M. Monthioux, C.R. Park, J.M.D. Tascon, and J. Zhang, All in the graphene family-A recommended nomenclature for two-dimensional carbon materials, Carbon, 65(2013), No. 6, p. 1.
    [12]
    J. Liu, H.X. Yan, and K. Jiang, Mechanical properties of graphene platelet-reinforced alumina ceramic composites, Ceram. Int., 39(2013), No. 6, p. 6215.
    [13]
    W. Kim, H.S. Oh, and I.J. Shon, The effect of graphene reinforcement on the mechanical properties of Al2O3 ceramics rapidly sintered by high-frequency induction heating, Int. J. Refract. Met. Hard Mater., 48(2015), p. 376.
    [14]
    Y. Fan, M. Estili, G. Igarashi, W. Jiang, and A. Kawasaki, The effect of homogeneously dispersed few-layer graphene on microstructure and mechanical properties of Al2O3 nanocomposites, J. Eur. Ceram. Soc., 34(2014), No. 2, p. 443.
    [15]
    H. Porwal, P. Tatarko, S. Grasso, J. Khaliq, I. Dlouhý, and M.J. Reece, Graphene reinforced alumina nano-composites, Carbon, 64(2013), No. 11, p. 359.
    [16]
    P. Kun, O. Tapasztó, F. Wéber, and C. Balázsi, Determination of structural and mechanical properties of multilayer graphene added silicon nitride-based composites, Ceram. Int., 38(2012), No. 1, p. 211.
    [17]
    K. Jiang, J. Li, and J. Liu, Spark plasma sintering and characterization of graphene platelet/ceramic composites, Adv. Eng. Mater., 17(2015), No. 5, p. 716.
    [18]
    Y. Cheng, Y. Zhang, T.Y. Wan, Z.B. Yin, and J.A. Wang, Mechanical properties and toughening mechanisms of graphene platelets reinforced Al2O3/TiC composite ceramic tool materials by microwave sintering, Mater. Sci. Eng. A, 680(2017), p. 190.
    [19]
    J. Liu, H.X. Yan, M.J. Reece, and K. Jiang, Toughening of zirconia/alumina composites by the addition of graphene platelets, J. Eur. Ceram. Soc., 32(2012), No. 16, p. 4185.
    [20]
    C. Ramirez and M.I. Osendi, Toughening in ceramics containing graphene fillers, Ceram. Int., 40(2014), No. 7, p. 11187.
    [21]
    M. Sebastiani, K.E. Johanns, E.G. Herbert, and G.M. Pharr, Measurement of fracture toughness by nanoindentation methods:recent advances and future challenges, Curr. Opin. Solid State Mater. Sci., 19(2015), No. 6, p. 324.
    [22]
    I. Benedetti and M.H. Aliabadi, A three-dimensional cohesive-frictional grain-boundary micromechanical model for intergranular degradation and failure in polycrystalline materials, Comput. Methods Appl. Mech. Eng., 265(2013), No. 9, p. 36.
    [23]
    M.L. Bauccio, ASM Engineered Materials Reference Book, 2nd Ed, Ohio:ASM international, 1994.
    [24]
    C.G. Lee, X.D. Wei, J.W. Kysar, and J. Hone, Measurement of the elastic properties and intrinsic strength of monolayer graphene, Science, 321(2008), No. 5887, p. 385.
    [25]
    P. Zhang, L.L. Ma, F.F. Fan, Z. Zeng, C. Peng, P.E. Loya, Z. Liu, Y.J. Gong, J.N. Zhang, X.X. Zhang, P.M. Ajayan, T. Zhu, and J. Lou, Fracture toughness of graphene, Nat. Commun., 5(2014), No. 4, p. 3782.
    [26]
    J.S. Zhao, Preparation and Properties of Al2O3/TiC/CNTs Composites[Dissertation], Shandong Jianzhu University, Jinan, 2012, p. 21.
    [27]
    S.G. Nyembe, Improvement of Alumina Mechanical and Electrical Properties using Multi-Walled Carbon Nanotubes and Titanium Carbide as a Secondary Phase[Dissertation], University of Witwatersrand, Johannesburg, 2013, p. 80.
    [28]
    M. Kostecki, M. Grybczuk, P. Klimczyk, T. Cygan, J. Woźniak, T. Wejrzanowski, L. Jaworska, J. Morgiel, and A. Olszyna, Structural and mechanical aspects of multilayer graphene addition in alumina matrix composites-validation of computer simulation model, J. Eur. Ceram. Soc., 36(2016), No.16, p. 4171.
    [29]
    R. Rao, R. Podila, R. Tsuchikawa, J. Katochet, D. Tishler, A.M. Rao, and M. Ishigami, Effects of layer stacking on the combination Raman modes in graphene, ACS Nano, 5(2011), No. 3, p. 1594.
    [30]
    X.L. Meng, C.H. Xu, G.C. Xiao, M.D. Yi, and Y.B. Zhang, Microstructure and anisotropy of mechanical properties of graphene nanoplate toughened Al2O3-based ceramic composite, Ceram. Int., 42(2016), No. 14, p. 16090.
    [31]
    Y. Ji and J.A. Yeomans, Processing and mechanical properties of Al2O3-5vol% Cr nanocomposites, J. Eur. Ceram. Soc., 22(2002), No. 12, p. 1927.
    [32]
    N. Claussen and J. Steeb, Toughening of ceramic composites by oriented nucleation of microcracks, J. Am. Ceram. Soc., 59(1976), No. 9-10, p. 457.
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