Cong-cong Yang, De-qing Zhu, Jian Pan, Si-wei Li, and Hong-yu Tian, A novel process for Fe recovery and Zn, Pb removal from a low-grade pyrite cinder with high Zn and Pb contents, Int. J. Miner. Metall. Mater., 25(2018), No. 9, pp. 981-989. https://doi.org/10.1007/s12613-018-1648-x
Cite this article as:
Cong-cong Yang, De-qing Zhu, Jian Pan, Si-wei Li, and Hong-yu Tian, A novel process for Fe recovery and Zn, Pb removal from a low-grade pyrite cinder with high Zn and Pb contents, Int. J. Miner. Metall. Mater., 25(2018), No. 9, pp. 981-989. https://doi.org/10.1007/s12613-018-1648-x
Research Article

A novel process for Fe recovery and Zn, Pb removal from a low-grade pyrite cinder with high Zn and Pb contents

+ Author Affiliations
  • Corresponding author:

    Jian Pan    E-mail: pjcsu@csu.edu.cn

  • Received: 12 January 2018Revised: 28 March 2018Accepted: 2 April 2018
  • Comprehensive utilization of pyrite cinders is increasingly important because of their huge annual outputs and potential valuable metals recovery to cope with the gradual depletion of high-grade mineral resources. In this work, a new process, i.e., a high-temperature chlorination-magnetizing roasting-magnetic separation process, was proposed for recovering Fe and removing Zn, Pb from a low-grade pyrite cinder containing 49.90wt% Fe, 1.23wt% Zn, and 0.29wt% Pb. Various parameters, including the chlorinating conditions (dosage of CaCl2, temperature, and time) and the magnetization roasting conditions (amount of coal, temperature, and time) were investigated. The results indicate that the proposed process is effective for Fe recovery and Zn, Pb removal from the pyrite cinder. Through this process, 97.06% Zn, 96.82% Pb, and approximately 90% S can be removed, and 89.74% Fe is recovered as magnetite into the final product under optimal conditions. A purified magnetite concentrate containing 63.07wt% Fe, 0.16wt% P, 0.26wt% S, and trace amounts of nonferrous metals (0.005wt% Cu, 0.013wt% Pb, and 0.051wt% Zn) was obtained. The concentrate can be potentially used as a high-quality feed material for producing oxidized pellets by blending with other high-grade iron ore concentrates.
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  • [1]
    M. Giunti, D. Baroni, and E. Bacci, Hazard assessment to workers of trace metal content in pyrite cinders, Bull. Environ. Contam. Toxicol., 72(2004), No. 2, p. 352.
    [2]
    T. Vamerali, M. Bandiera, L. Coletto, F. Zanetti, N.M. Dickinson, and G. Mosca, Phytoremediation trials on metal-and arsenic-contaminated pyrite wastes (Torviscosa, Italy), Environ. Pollut., 157(2009), No. 3, p. 887.
    [3]
    T. Vamerali, M. Bandiera, and G. Mosca, In situ phytoremediation of arsenic-and metal-polluted pyrite waste with field crops:effects of soil management, Chemosphere, 83(2011), No. 9, p. 1241.
    [4]
    L.I. Levin, N.M. Iakubtsiner, V.M. Sholeninov, and G.F. Grigor'evykh, Application of pyrite cinders in the production of high-basicity sinter, Metallurgist, 2(1958), No. 6, p. 278.
    [5]
    D.Q. Zhu, Z.Y. Ruan, T.J. Chun, and J. Pan, Utilization of high sulfur raw materials in iron ore pellets, J. Iron. Steel Res. Int., 20(2013), No. 10, p. 32.
    [6]
    T.J. Chun, D.Q. Zhu, and J. Pan, Influence of sulfur content in raw materials on oxidized pellets, J. Cent. South Univ. Technol., 18(2011), No. 6, p. 1924.
    [7]
    D.Q. Zhu, T.J. Chun, J. Pan, and Z.Q. Guo, Preparation of oxidised pellets using pyrite cinders as raw material, Ironmaking Steelmaking, 40(2013), No. 6, p. 430.
    [8]
    S.L. Liu, Industrialized application of pelletizing technology with high proportion of pyrite residue of Tongling non-ferrous Co., Sinter. Pellet., 35(2010), No. 1, p. 5.
    [9]
    M.K. Jha, V. Kumar, and R.J. Singh, Review of hydrometallurgical recovery of zinc from industrial wastes, Resour. Conserv. Recycl., 33(2001), No. 1, p. 1.
    [10]
    Y. Li, F.C. Zhou, Z.X. Zhou, Z.H. Tian, C. Yang, and X.K. Tian, An innovative approach to separate iron oxide concentrate from high-sulfur and low-grade pyrite cinders, J. Iron. Steel Res. Int., 23(2016), No. 8, p. 756.
    [11]
    J.T. Wei, G.Y. Yan, B.K. Guo, and G.L. Gao, Extracting gold from pyrite roster cinder by ultra-fine-grinding and resin-in-pulp, J. Cent. South Univ. Technol., 10(2003), No. 1, p. 27.
    [12]
    Y. Okubo, Kowa Seiko pelletizing chlorination process-integral utilization of iron pyrites, JOM, 20(1968), No. 3, p. 63.
    [13]
    A. Ishimitsu, K. Sugahara, S. Arakawa, and T. Kitazawa, Process of Obtaining A Granular Charge for the Blast Furnace from A Pyrite Cinder and Iron Manufacture Dust or Powdered Iron Ore, USA Patent, Appl. 3482964, 1969.
    [14]
    J. Ding, P.W. Han, C.C. Lü, P. Qian, S.F. Ye, and Y.F. Chen, Utilization of gold-bearing and iron-rich pyrite cinder via a chlorination-volatilization process, Int. J. Miner. Metall. Mater., 24(2017), No. 11, p. 1241.
    [15]
    U. Colombo, G. Sironi, B. Viviani, and A. Colombini, Process for the Purification of Pyrite Cinders from Nonferrous Metals, from Arsenic and from Sulfur, USA Patent, Appl. 3649245, 1972.
    [16]
    D. Chen, D.Q. Zhu, and Y. Chen, Preparation of prereduced pellets by pyrite cinder containing nonferrous metals with high temperature chloridizing-reduction roasting technology, ISIJ Int., 54(2014), No. 10, p. 2162.
    [17]
    D. Chen, D.Q. Zhu, L. Hong, Y. Chen, J.F. Xu, and L. Wu, Preparation of pre-reduced pellet using pyrite cinder containing nonferrous metals with high temperature chloridizing-reduction roasting technology-Effect of CaCl2 additive, J. Cent. South Univ. Technol., 22(2015), No. 11, p. 4154.
    [18]
    D.Q. Zhu, D. Chen, J. Pan, Y. Cui, and X.L. Zhou, ‘One step’ technology to separate copper, zinc, lead from iron in metallurgical slag and pyrite cinder Part 1-Laboratory scale test, Miner. Process. Extr. Metall., 121(2012), No. 2, p. 79.
    [19]
    D. Chen, H.W. Guo, J.F. Xu, Y.N. Lv, Z.M. Xu, and H.J. Huo, Recovery of iron from pyrite cinder containing non-ferrous metals using high-temperature chloridizing-reduction-magnetic separation, Metall. Mater. Trans. B, 48(2017), No. 2, p. 933.
    [20]
    D.Q. Zhu, J. Li, Q.C. Li, J. Pan, X.F. Xu, Y. Zhai, Y.Y. Tang, and Y. Cui, Preparation of high quality magnetite concentrate from pyrite cinder by composite pellet reduction-roasting and magnetic-separation, Chin. J. Nonferrous Met., 17(2007), No. 4, p. 649.
    [21]
    Z.J. Liu, X.D. Xing, J.L. Zhang, M.M. Cao, K.X. Jiao, and S. Ren, Reduction mechanisms of pyrite cinder-carbon composite pellets, Int. J. Miner. Metall. Mater., 19(2012), No. 11, p. 986.
    [22]
    Y. Ohkubo and A. Ishimitsu, Present status and future aspect on the beneficiation of pyritic ores and pyrite cinder into high gade raw materials for iron making, Tetsu-to-Hagane, 58(1972), No. 2, p. 325.
    [23]
    C. Lei, B. Yan, T. Chen, and X.M. Xiao, Recovery of metals from the roasted lead-zinc tailings by magnetizing roasting followed by magnetic separation, J. Cleaner Prod., 158(2017), p. 73.
    [24]
    G.Z. Qiu, T. Jiang, J. Xu, and R. Cai, Direct Reduction of Cold-Bonded Pellets, Central South University Press, Changsha, 2001, p. 63.
    [25]
    H. Matsuura, T. Hamano, and F. Tsukihashi, Removal of Zn and Pb from Fe2O3-ZnFe2O4-ZnO-PbO mixture by selective chlorination and evaporation reactions, ISIJ Int., 46(2006), No. 8, p. 1113.
    [26]
    F. Noguchi, Y. Ueda, T. Kudoh, and H. Nagasue, On the chloridized volatilization pellet from pyrite cinder with CaCl2, Proc. Jpn. Min. Ind. Assoc., 95(1979), No. 1094, p. 219.
    [27]
    T. Guo, X.J. Hu, H. Matsuura, F. Tsukihashi, and G.Z. Zhou, Kinetics of Zn removal from ZnO-Fe2O3-CaCl2 system, ISIJ Int., 50(2010), No. 8, p. 1084.
    [28]
    D. Chen, A Study on the Mechanism and Technology of Preparation of Pre-reduced Pellets from Pyrite Cinders Containing Non-Ferrous Metals[Dissertation], Central South University, Changsha, 2012, p. 108.
    [29]
    X.H. Fan, Q. Deng, M. Gan, and H.B. Wang, Effect of biochar as reductant on magnetizing-roasting behavior of pyrite cinder, J. Iron. Steel Res. Int., 22(2015), No. 5, p. 371.
    [30]
    D.Q. Zhu, D. Chen, and J. Pan, Comparison of pretreating pyrite cinder by high pressure roller grinding with damp milling to improve pelletization, J. Cent. South Univ. Sci. Technol., 42(2011), No. 7, p. 1825.
    [31]
    C.C. Yang, D.Q. Zhu, J. Pan, B.Z. Zhou, and X. Hu, Oxidation and induration characteristics of pellets made from Western Australian ultrafine magnetite concentrates and its utilization strategy, J. Iron. Steel Res. Int., 23(2016), No. 9, p. 924.
    [32]
    D.Q. Zhu, X. Hu, J. Pan, C.C. Yang, M.J. Xu, and Z.Y. Wang, Optimization of feed blends to enhance the roasting performance of pellets made from Western Australian ultrafine magnetite concentrate, Chin. J. Eng., 39(2017), No. 5, p. 683.
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