Reductive recovery of manganese from low-grade manganese dioxide ore using toxic nitrocellulose acid wastewater as reductant

Yong-tao Zhang; Zhi-gang Dan; Ning Duan; Bao-ping Xin

doi:10.1007/s12613-018-1649-9

Volume 25 Issue 9

Sep. 2018

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Article Navigation > International Journal of Minerals, Metallurgy and Materials > 2018 > 25(9): 990-999

Yong-tao Zhang, Zhi-gang Dan, Ning Duan, and Bao-ping Xin, Reductive recovery of manganese from low-grade manganese dioxide ore using toxic nitrocellulose acid wastewater as reductant, Int. J. Miner. Metall. Mater., 25(2018), No. 9, pp. 990-999. https://doi.org/10.1007/s12613-018-1649-9

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Yong-tao Zhang, Zhi-gang Dan, Ning Duan, and Bao-ping Xin, Reductive recovery of manganese from low-grade manganese dioxide ore using toxic nitrocellulose acid wastewater as reductant, Int. J. Miner. Metall. Mater., 25(2018), No. 9, pp. 990-999. https://doi.org/10.1007/s12613-018-1649-9

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Research Article

Reductive recovery of manganese from low-grade manganese dioxide ore using toxic nitrocellulose acid wastewater as reductant

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Corresponding author:
Bao-ping Xin E-mail: xinbaoping@bit.edu.cn
Received: 27 November 2017; Revised: 28 February 2018; Accepted: 25 April 2018

Abstract

Abstract

The hydrometallurgical strategy of extracting Mn from low-grade Mn ores has attracted attention for the production of electrolytic manganese metal (EMM). In this work, the reductive dissolution of low-grade MnO₂ ores using toxic nitrocellulose acidic wastewater (NAW) as a reductant was investigated for the first time. Under the optimized conditions of an MnO₂ ore dosage of 100 g·L^-1, an ore particle size of -200 mesh, concentrated H₂SO₄-to-NAW volume ratio of 0.12, reaction temperature of 90℃, stirring speed at 160 r·min^-1, and a contact time of 120 min, the reductive leaching efficiency of Mn and the total organic carbon (TOC) removal efficiency of NAW reached 97.4% and 98.5%, respectively. The residual TOC of 31.6 mg·L^-1 did not adversely affect the preparation of EMM. The current process offers a feasible route for the concurrent realization of the reductive leaching of Mn and the treatment of toxic wastewater via a simple one-step process.
- low-grade manganese dioxide ore;
- nitrocellulose acid wastewater;
- sulfuric acid leaching;
- Mn reductive dissolution;
- electrolytic manganese metal

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