Mineral-phase evolution and sintering behavior of MO-SiO2-Al2O3-B2O3 (M=Ca, Ba) glass-ceramics by low-temperature liquid-phase sintering

Song Chen; Zhen Sun; De-gui Zhu

doi:10.1007/s12613-018-1655-y

Volume 25 Issue 9

Sep. 2018

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Article Navigation > International Journal of Minerals, Metallurgy and Materials > 2018 > 25(9): 1042-1054

Song Chen, Zhen Sun, and De-gui Zhu, Mineral-phase evolution and sintering behavior of MO-SiO₂-Al₂O₃-B₂O₃ (M=Ca, Ba) glass-ceramics by low-temperature liquid-phase sintering, Int. J. Miner. Metall. Mater., 25(2018), No. 9, pp. 1042-1054. https://doi.org/10.1007/s12613-018-1655-y

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Song Chen, Zhen Sun, and De-gui Zhu, Mineral-phase evolution and sintering behavior of MO-SiO2-Al2O3-B2O3 (M=Ca, Ba) glass-ceramics by low-temperature liquid-phase sintering, Int. J. Miner. Metall. Mater., 25(2018), No. 9, pp. 1042-1054. https://doi.org/10.1007/s12613-018-1655-y

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Research Article

Mineral-phase evolution and sintering behavior of MO-SiO₂-Al₂O₃-B₂O₃ (M=Ca, Ba) glass-ceramics by low-temperature liquid-phase sintering

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Corresponding author:
Song Chen E-mail: schen2012@swjtu.edu.cn
Received: 30 December 2017; Revised: 26 February 2018; Accepted: 3 March 2018

Abstract

Abstract

In this work, network former SiO₂ and network intermediate Al₂O₃ were introduced into typical low-melting binary compositions CaO·B₂O₃, CaO·2B₂O₃, and BaO·B₂O₃ via an aqueous solid-state suspension milling route. Accordingly, multiple-phase aluminosilicate glass-ceramics were directly obtained via liquid-phase sintering at temperatures below 950℃. On the basis of liquid-phase sintering theory, mineral-phase evolutions and glass-phase formations were systematically investigated in a wide MO-SiO₂-Al₂O₃-B₂O₃ (M=Ca, Ba) composition range. The results indicate that major mineral phases of the aluminosilicate glass-ceramics are Al₂₀B₄O₃₆, CaAl₂Si₂O₈, and BaAl₂Si₂O₈ and that the glass-ceramic materials are characterized by dense microstructures and excellent dielectric properties.
- glass-ceramics;
- liquid-phase sintering;
- aluminosilicate;
- mineral phase;
- microstructures

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