Ze-yun Cai, Bo Song, Long-fei Li, Zhen Liu,  and Xiao-kang Cui, Effect of CeO2 on heat transfer and crystallization behavior of rare earth alloy steel mold fluxes, Int. J. Miner. Metall. Mater., 26(2019), No. 5, pp. 565-572. https://doi.org/10.1007/s12613-019-1765-1
Cite this article as:
Ze-yun Cai, Bo Song, Long-fei Li, Zhen Liu,  and Xiao-kang Cui, Effect of CeO2 on heat transfer and crystallization behavior of rare earth alloy steel mold fluxes, Int. J. Miner. Metall. Mater., 26(2019), No. 5, pp. 565-572. https://doi.org/10.1007/s12613-019-1765-1
Research Article

Effect of CeO2 on heat transfer and crystallization behavior of rare earth alloy steel mold fluxes

+ Author Affiliations
  • Corresponding author:

    Bo Song    E-mail: songbo@matall.ustb.edu.cn

  • Received: 26 September 2018Revised: 24 November 2018Accepted: 30 November 2018
  • To improve the heat transfer capability and the crystallization property of the traditional mold flux, CaF2 was replaced with B2O3. Then, the influences of CeO2 on the heat transfer and the crystallization of the CaF2-bearing mold flux and the new mold flux with 10wt% B2O3 were studied using a slag film heat flux simulator and X-ray diffraction (XRD). The results revealed that the addition of CeO2 reduced the heat transfer by increasing the solid slag thickness and the crystallization of two mold fluxes. However, CeO2 had less effect on the B2O3-containing mold flux compared with the CaF2-bearing mold flux. According to the analyses, the CeO2 contents in the CaF2-bearing mold flux and the B2O3-containing mold flux should not exceed 8wt% and 12wt%, respectively. Therefore, these experimental results are beneficial to improve and develop the mold flux for casting rare earth alloy steels.
  • loading
  • [1]
    G. Xia, H.P. Narzt, Ch. Fürst, K. Mörwald, J. Moertl, P. Reisinger, and L. Lindenberger, Investigation of mould thermal behaviour by means of mould instrumentation, Ironmaking Steelmaking, 31(2004), No. 5, p. 364.
    [2]
    J. Mahmoudi, Mathematical modelling of fluid flow, heat transfer and solidification in a strip continuous casting process, Int. J. Cast Met. Res., 19(2006), No. 4, p. 223.
    [3]
    J. Diao, B. Xie, J.P. Xiao, and C.Q. Ji, Radiative heat transfer in transition metal oxides contained in mold fluxes, ISIJ Int., 49(2009), No. 11, p. 1710.
    [4]
    X.D. Wang, L.W. Kong, F.M. Du, Y. Liu, X.Y. Zang, and M. Yao, Prediction on lubrication and friction of mold flux based on inverse problem in a continuous slab casting process, ISIJ Int., 54(2014), No. 12, p. 2806.
    [5]
    L.M. Wang, Q. Lin, L.J. Yue, L. Liu, F. Guo, and F.M. Wang, Study of application of rare earth elements in advanced low alloy steels, J. Alloys Compd., 451(2008), No. 1-2, p. 534.
    [6]
    Y. Huang, G.G. Cheng, and Y. Xie, Modification mechanism of cerium on the inclusions in drill steel, Acta Metall. Sin., 54(2018), No. 9, p. 1253.
    [7]
    H. Torkamani, S. Raygan, C. Garcia-Mateo, J. Rassizadehghani, Y. Palizdar, and D. San-Martin, Evolution of pearlite microstructure in Low-Carbon cast microalloyed steel due to the addition of La and Ce, Metall. Mater. Trans. A, 49(2018), No. 10, p. 4495.
    [8]
    X.H. Li, C.L. Li, and Y.S. Wang. Influence of rare earth on the mould flux peoperties, Chin. Rare Earths, 24(2003), No. 5, p. 18.
    [9]
    D.Y. Wang, M.F. Jiang, C.J. Liu, P.Y. Shi, Y.K. Yao, and H.H. Wang, Effects of rare earth oxide on viscosity of mold fluxes for continuous casting, J. Rare Earths, 23(2005), No. 1, p. 68.
    [10]
    F. Zhang, Y. Chen, Y.C. Wang, F. Dong, and M.Q. Wu, Influence of La2O3 on crystallization behavior of free-fluoride mould flux and heat transfer of slag films, J. Rare Earths, 29(2011), No. 2, p. 173.
    [11]
    J. Qi, C.J. Liu, C.L. Li, and M.F. Jiang, Viscous properties of new mould flux based on aluminate system with CeO2 for continuous casting of RE alloyed heat resistant steel, J. Rare Earths, 34(2016), No. 3, p. 328.
    [12]
    J. Qi, C.J. Liu, C. Zhang, and M.F. Jiang, Effect of Ce2O3 on structure, viscosity, and crystalline phase of CaO-Al2O3-Li2O-Ce2O3 slags, Metall. Mater. Trans. B, 48(2017), No. 1, p. 11.
    [13]
    C.L. Li, Y.S. Wang, J.J. Chen, C.J. Liu, and M.F. Jiang, Effects of rare earth on structure and mechanical properties of clean BNbRE steel, J. Rare Earths, 23(2005), No. 4, p. 470.
    [14]
    L.M. Wang, Q. Lin, J.W. Ji, and D.N. Lan, New study concerning development of application of rare earth metals in steels, J. Alloys Compd., 408-412(2006), p. 384.
    [15]
    C.J. Liu, Y.H. Huang, and M.F. Jiang, Effects and mechanisms of RE on impact toughness and fracture toughness of clean heavy rail steel, J. Iron Steel Res. Int., 18(2011), No. 3, p. 52.
    [16]
    S.M. Shariff, T.K. Pal, G. Padmanabham, and S.V. Joshi, Influence of chemical composition and prior microstructure on diode laser hardening of railroad steels, Surf. Coat. Technol., 228(2013), p. 14.
    [17]
    M.L. Cheng, Y.S. Song, L. Xu, X.F. Shi, B.C. Liu, C. Lu, and S. Chen, Effect of RE compound modification on properties and as-cast microstructure of high carbon-chromium alloy steel, Spec. Cast. Nonferrous Alloys, 34(2014), No. 7, p. 700.
    [18]
    A.B. Fox, K.C. Mills, D. Lever, C. Bezerra, C. Valadares, I. Unamuno, J.J. Laraudogoitia, and J. Gisby, Development of fluoride-free fluxes for billet casting, ISIJ Int., 45(2005), No. 7, p. 1051.
    [19]
    X. Yu, G.H. Wen, P. Tang, and H. Wang, Investigation on viscosity of mould fluxes during continuous casting of aluminium containing TRIP steels, Ironmaking Steelmaking, 36(2009), No. 8, p. 623.
    [20]
    L.J. Zhou, W.L. Wang, B.X. Lu, G.H. Wen, and J. Yang, Effect of basicity and B2O3 on viscosity, melting and crystallization behaviors of low fluorine mold fluxes for casting medium carbon steels, Met. Mater. Int., 21(2015), No. 1, p. 126.
    [21]
    K.C. Mills, Structure and properties of slags used in the continuous casting of steel:Part 2 specialist mould powders, ISIJ Int., 56(2016), No. 1, p. 14.
    [22]
    D.T. Stone and B.G. Thomas, Measurement and modeling of heat transfer across interfacial mold flux layers, Can. Metall. Q., 38(1999), No. 5, p. 363.
    [23]
    C.A.M. Pinheiro, I.V. Samarasekera, J.K. Brimacombe, and B.N. Walker, Mould heat transfer and continuously cast billet quality with mould flux lubrication Part 1 Mould heat transfer, Ironmaking Steelmaking, 27(2000), No. 1, p. 37.
    [24]
    B.X. Lu, W.L. Wang, J. Li, H. Zhao, and D.Y. Huang, Effects of basicity and B2O3 on the crystallization and heat transfer behaviors of low fluorine mold flux for casting medium carbon steels, Metall. Mater. Trans. B, 44(2013), No. 2, p. 365.
    [25]
    J.M. González de la C., T.M. Flores F., and A.H. Castillejos E., Study of shell-mold thermal resistance:Laboratory measurements, estimation from compact strip production plant data, and observation of simulated flux-mold interface, Metall. Mater. Trans. B, 47(2016), No. 4, p. 2509.
    [26]
    H.H. Zhang and W.L. Wang, Mold simulator study of heat transfer phenomenon during the initial solidification in continuous casting mold, Metall. Mater. Trans. B, 48(2017), No. 2, p. 779.
    [27]
    G.H. Wen, S. Sridhar, P. Tang, X. Qi, and Y.Q. Liu, Development of fluoride-free mold powders for peritectic steel slab casting, ISIJ Int., 47(2007), No. 8, p. 1117.
    [28]
    G.H. Wen, P. Tang, B. Yang, and X.B. Zhu, Simulation and characterization on heat transfer through mould slag film, ISIJ Int., 52(2012), No. 7, p. 1179.
    [29]
    K.C. Mills and A.B. Fox, The role of mould fluxes in continuous casting-so simple yet so complex, ISIJ Int., 43(2003), No. 10, p. 1479.
    [30]
    Y. Meng and B.G. Thomas, Heat-transfer and solidification model of continuous slab casting:CON1D, Metall. Mater. Trans. B, 34(2003), No. 5, p. 685.
    [31]
    W.L. Wang amd A.W. Cramb, Study of the effects of the mold surface and solid mold flux crystallization on radiative heat transfer rates in continuous casting, Steel Res. Int., 81(2010), No. 6, p. 446.
    [32]
    M. Susa, A. Kushimoto, R. Endo, and Y. Kobayashi, Controllability of radiative heat flux across mould flux films by cuspidine grain size, ISIJ Int., 51(2011), No. 10, p. 1587.
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Share Article

    Article Metrics

    Article Views(560) PDF Downloads(22) Cited by()
    Proportional views

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return