Adsorption characteristics of Cd(II) and Ni(II) from aqueous solution using succinylated hay

Peijia Lin; Jiajia Wu; Junmo Ahn; Jaeheon Lee

doi:10.1007/s12613-019-1832-7

Volume 26 Issue 10

Oct. 2019

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Article Navigation > International Journal of Minerals, Metallurgy and Materials > 2019 > 26(10): 1239-1246

Peijia Lin, Jiajia Wu, Junmo Ahn, and Jaeheon Lee, Adsorption characteristics of Cd(II) and Ni(II) from aqueous solution using succinylated hay, Int. J. Miner. Metall. Mater., 26(2019), No. 10, pp. 1239-1246. https://doi.org/10.1007/s12613-019-1832-7

Cite this article as:

Peijia Lin, Jiajia Wu, Junmo Ahn, and Jaeheon Lee, Adsorption characteristics of Cd(II) and Ni(II) from aqueous solution using succinylated hay, Int. J. Miner. Metall. Mater., 26(2019), No. 10, pp. 1239-1246. https://doi.org/10.1007/s12613-019-1832-7

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Research Article

Adsorption characteristics of Cd(II) and Ni(II) from aqueous solution using succinylated hay

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Corresponding author:
Jaeheon Lee E-mail: jaeheon@email.arizona.edu
Received: 9 February 2019; Revised: 11 April 2019; Accepted: 15 April 2019

Abstract

Abstract

An environmentally friendly organic biosorbent was fabricated using hay by succinylation. Metallic cation adsorption tests were performed using synthetic nickel(Ⅱ) and cadmium(Ⅱ) solutions to simulate heavy-metal recovery from aqueous solution. The adsorption efficiency was greater than 98% for both cadmium and nickel ions when the biosorbent concentration was 5.0 g/L and the initial metal concentrations were 50 mg/L. The surface of the biosorbent was characterized using Fourier transform infrared spectroscopy to investigate the changes in the surface functional groups. The functional groups changed according to the surface treatment, resulting in an effective biosorbent. The kinetics of the metals adsorption revealed that the reactions are pseudo-second order, and the adsorption isotherm well followed the Langmuir model. The maximum adsorption capacities predicted by the Langmuir model were 75.19 mg/g and 57.77 mg/g for cadmium and nickel, respectively. The fabricated biosorbent was regenerated using NaCl multiple times, with 2.1% for Cd and 4.0% for Ni in adsorption capacity after three regeneration cycles. The proposed biosorbent can be a good alternative to resin or other chemical adsorbents for heavy-metal recovery in metallurgical processing or municipal water treatment.
- cadmium;
- nickel;
- biosorbent;
- succinylation;
- hay;
- langmuir adsorption

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