Chong-yu Liu, Guang-biao Teng, Zong-yi Ma, Li-li Wei, Bing Zhang,  and Yong Chen, Effects of Sc and Zr microalloying on the microstructure and mechanical properties of high Cu content 7xxx Al alloy, Int. J. Miner. Metall. Mater., 26(2019), No. 12, pp. 1559-1569. https://doi.org/10.1007/s12613-019-1840-7
Cite this article as:
Chong-yu Liu, Guang-biao Teng, Zong-yi Ma, Li-li Wei, Bing Zhang,  and Yong Chen, Effects of Sc and Zr microalloying on the microstructure and mechanical properties of high Cu content 7xxx Al alloy, Int. J. Miner. Metall. Mater., 26(2019), No. 12, pp. 1559-1569. https://doi.org/10.1007/s12613-019-1840-7
Research Article

Effects of Sc and Zr microalloying on the microstructure and mechanical properties of high Cu content 7xxx Al alloy

+ Author Affiliations
  • Corresponding authors:

    Chong-yu Liu    E-mail: lcy261@glut.edu.cn

    Zong-yi Ma    E-mail: zyma@imr.ac.cn

  • Received: 1 January 2019Revised: 5 March 2019Accepted: 6 March 2019
  • The effects of Sc and Zr microalloying on the microstructure and mechanical properties of a 7xxx Al alloy with high Cu content (7055) during casting, deformation, and heat treatment were investigated. The addition of Sc and Zr not only refined the grains but also transformed the θ-phase into the W-phase in the 7055 alloy. Minor Sc and Zr additions enhanced the hardness and yield strength of the 7055-T6 alloy by strengthening the grain boundaries and Al3(Sc,Zr) precipitates. However, a further increase in the Sc and Zr fractions did not refine the grains but instead resulted in the formation of the large-sized W-phase and primary coarse Al3(Sc,Zr) phase and subsequently deteriorated the mechanical properties of the alloys. The 7055 alloy with 0.25Sc addition exhibited the best mechanical property among the prepared alloys.
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  • [1]
    Y. Buranova, V. Kulitskiy, M. Peterlechner, A. Mogucheva, R. Kaibyshev, S.V. Divinski, and G. Wilde, Al3(Sc,Zr)-based precipitates in Al-Mg alloy:Effect of severe deformation, Acta Mater., 124(2017), p. 210.
    [2]
    T. Liu, C.N. He, G. Li, X. Meng, C.S. Shi, and N.Q. Zhao, Microstructural evolution in Al-Zn-Mg-Cu-Sc-Zr alloys during short-time homogenization, Int. J. Miner. Metall. Mater., 22(2015), No. 5, p. 516.
    [3]
    J.H. Li, M. Wiessner, M. Albu, S.Wurster, B. Sartory, F. Hofer, and P. Schumacher, Correlative characterization of primary Al3(Sc,Zr) phase in an Al-Zn-Mg based alloy, Mater. Charact., 102(2015), p. 62.
    [4]
    M. Zhang, T. Liu, C.N. He, J. Ding, E.Z. Liu, C.S. Shi, J.J. Li, and N.Q. Zhao, Evolution of microstructure and properties of Al-Zn-Mg-Cu-Sc-Zr alloy during aging treatment, J. Alloys Compd., 658(2016), p. 946.
    [5]
    Y.L. Duan, G.F. Xu, L. Tang, Y. Liu, J.W. Xu, Y. Deng, and Z.M. Yin, Excellent high strain rate super plasticity of Al-Mg-Sc-Zr alloy sheet produced by an improved asymmetrical rolling process, J. Alloys Compd., 715(2017), p. 311.
    [6]
    B. Li, Q.L. Pan, X. Huang, and Z.M. Yin, Microstructures and properties of Al-Zn-Mg-Mn alloy with trace amounts of Sc and Zr, Mater. Sci. Eng. A, 616(2014), p. 219.
    [7]
    X. Huang, Q.L. Pan, B. Li, Z.M. Liu, Z.Q. Huang, and Z.M. Yin, Microstructure, mechanical properties and stress corrosion cracking of Al-Zn-Mg-Zr alloy sheet with trace amount of Sc, J. Alloys Compd., 650(2015), p. 805.
    [8]
    G. Li, N.Q. Zhao, T. Liu, J.J. Li, C.N. He, C.S. Shi, E.Z. Liu, and J.W. Sha, Effect of Sc/Zr ratio on the microstructure and mechanical properties of new type of Al-Zn-Mg-Sc-Zr alloys, Mater. Sci. Eng. A, 617(2014), p. 219.
    [9]
    Y. Deng, B. Peng, G.F. Xu, Q.L. Pan, Z.M. Yin, R. Ye, Y.J. Wang, and L.Y. Lu, Effects of Sc and Zr on mechanical property and microstructure of tungsten inert gas and friction stir welded aerospace high strength Al-Zn-Mg alloys, Mater. Sci. Eng. A, 639(2015), p. 500.
    [10]
    C.Y. Liu, B. Zhang, Z.Y. Ma, G.B. Teng, L.L. Wei, W.B. Zhou, and X.Y. Zhang, Effects of pre-aging and minor Sc addition on the microstructure and mechanical properties of friction stir processed 7055 Al alloy, Vacuum, 149(2018), p. 106.
    [11]
    Y. Chen, C.Y. Liu, B. Zhang, Z.Y. Ma, W.B. Zhou, H.J. Jiang, H.F. Huang, and L.L. Wei, Effects of friction stir processing and minor Sc addition on the microstructure, mechanical properties, and damping capacity of 7055 Al alloy, Mater. Charact., 135(2018), p. 25.
    [12]
    G.B. Teng, C.Y. Liu, Z.Y. Ma, W.B. Zhou, L.L. Wei, Y. Chen, J. Li, and Y.F. Mo, Effects of minor Sc addition on the microstructure and mechanical properties of 7055 Al alloy during aging, Mater. Sci. Eng. A, 713(2018), p. 61.
    [13]
    C.Y. Liu, B. Zhang, Z.Y. Ma, H.J. Jiang, and W.B. Zhou, Effect of Sc addition, friction stir processing, and T6 treatment on the damping and mechanical properties of 7055 Al alloy, J. Alloys Compd. 772(2019), p. 775.
    [14]
    Z.H. Zhang, J. Xue, Y.B. Jiang, and F. Jin, Effect of pre-annealing treatment on the microstructure and mechanical properties of extruded Al-Zn-Mg-Cu alloy bars, Int. J. Miner. Metall. Mater., 24(2017), No. 11, p. 1284.
    [15]
    C.B. Cai, X.J. Xu, J.D. Huang, S.H. Ju, Q. Ding, and C.S. Wang, Effect of pre-recovery on microstructure and properties of rolled Al-12.18Zn-3.31Mg-1.43Cu-0.20Zr-0.04Sr aluminum alloy, Int. J. Miner. Metall. Mater., 26(2019), No. 2, p. 241.
    [16]
    C.B. Zheng, B.H. Yan, K. Zhang, and G. Yi, Electrochemical investigation on the hydrogen permeation behavior of 7075-T6 Al alloy and its influence on stress corrosion cracking, Int. J. Miner. Metall. Mater., 22(2015), No. 7, p. 729.
    [17]
    D. Wang, Z.Y. Ma, and Z.M. Gao, Effects of severe cold rolling on tensile properties and stress corrosion cracking of 7050 aluminum alloy, Mater. Chem. Phys., 117(2009), No. 1, p. 228.
    [18]
    J.F. Xie, Y.L. Zhu, F.L. Bian, and C. Liu, Dynamic recovery and recrystallization mechanisms during ultrasonic spot welding of Al-Cu-Mg alloy, Mater. Charact., 132(2017), p. 145.
    [19]
    S.K. Moghanaki, M. Kazeminezhad, and R. Logé, Effect of concurrent precipitation on the texture evolution during continuous heating of multi directionally forged solution treated Al-Cu-Mg alloy, Mater. Charact., 131(2017), p. 399.
    [20]
    I. Zuiko and R. Kaibyshev, Deformation structures and strengthening mechanisms in an Al-Cu alloy subjected to extensive cold rolling, Mater. Sci. Eng. A, 702(2017), p. 53.
    [21]
    K. Yu, W.X. Li, S.R. Li, and J. Zhao, Mechanical properties and microstructure of aluminum alloy 2618 with Al3(Sc,Zr) phases, Mater. Sci. Eng. A, 368(2004), No. 1-2, p. 88.
    [22]
    A.M. Samuel, S.A. Alkahtani, H.W. Doty, and F.H. Samuel, Role of Zr and Sc addition in controlling the microstructure and tensile properties of aluminum-copper based alloys, Mater. Des., 88(2015), p. 1134.
    [23]
    N.A. Belov, A.N. Alabin, and I.A. Matveeva, Optimization of phase composition of Al-Cu-Mn-Zr-Sc alloys for rolled products without requirement for solution treatment and quenching, J. Alloys Compd., 583(2014), p. 206.
    [24]
    M. Jia, Z.Q. Zheng, and Z. Gong, Microstructure evolution of the 1469 Al-Cu-Li-Sc alloy during, J. Alloys Compd., 614(2014), p. 131.
    [25]
    M. Gazizov, V. Teleshov, V. Zakharov, and R. Kaibyshev, Solidification behaviour and the effects of homogenisation on the structure of an Al-Cu-Mg-Ag-Sc alloy, J. Alloys Compd., 509(2011), No. 39, p. 9497.
    [26]
    Y.T. Li, Z.Y. Liu, Q.K. Xia, and Y.B. Liu, Grain refinement of the Al-Cu-Mg-Ag alloy with Er and Sc additions, Metall. Mater. Trans. A, 38(2007), No. 11, p. 2853.
    [27]
    B.A. Chen, L. Pan, R.H. Wang, G. Liu, P.M. Cheng, L. Xiao, and J. Sun, Effect of solution treatment on precipitation behaviors and age hardening response of Al-Cu alloys with Sc addition, Mater. Sci. Eng. A, 530(2011), p. 607.
    [28]
    L. Jiang, J.K. Li, G. Liu, R.H. Wang, B.A. Chen, J.Y. Zhang, J. Sun, M.X. Yang, G. Yang, J. Yang, and X.Z. Cao, Length-scale dependent microalloying effects on precipitation behaviors and mechanical properties of Al-Cu alloys with minor Sc addition, Mater. Sci. Eng. A, 637(2015), p. 139.
    [29]
    S.D. Liu, X.M. Zhang, M.A. Chen, and J.H. You, Influence of aging on quench sensitivity effect of 7055 aluminum alloy, Mater. Charact., 59(2008), No. 1, p. 53.
    [30]
    J.R. Zuo, L.G. Hou, J.T. Shi, H. Cui, L.Z. Zhuang, and J.S. Zhang, The mechanism of grain refinement and plasticity enhancement by an improved thermomechanical treatment of 7055 Al alloy, Mater. Sci. Eng. A, 702(2017), p. 42.
    [31]
    Y.X. Chen, Y.Q. Yang, Z.Q. Feng, B. Huang, and X. Luo, Surface gradient nanostructures in high speed machined 7055 aluminum alloy, J. Alloys Compd., 726(2017), p. 367.
    [32]
    H. She, D. Shu, J. Wang, and B.D. Sun, Influence of multi-microstructural alterations on tensile property inhomogeneity of 7055 aluminum alloy medium thick plate, Mater. Charact., 113(2016), p. 189.
    [33]
    Y.H. Zhao, X.Z. Liao, S. Cheng, E. Ma, and Y.T. Zhu, Simultaneously increasing the ductility and strength of nanostructured alloys, Adv. Mater., 18(2006), p. 2280.
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