Electrochemical behavior and corrosion resistance of IrO<sub>2</sub>–ZrO<sub>2</sub> binary oxide coatings for promoting oxygen evolution in sulfuric acid solution

Bao Liu; Shuo Wang; Cheng-yan Wang; Bao-zhong Ma; Yong-qiang Chen

doi:10.1007/s12613-019-1847-0

Volume 27 Issue 2

Feb. 2020

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Article Navigation > International Journal of Minerals, Metallurgy and Materials > 2020 > 27(2): 264-273

Bao Liu, Shuo Wang, Cheng-yan Wang, Bao-zhong Ma, and Yong-qiang Chen, Electrochemical behavior and corrosion resistance of IrO₂–ZrO₂ binary oxide coatings for promoting oxygen evolution in sulfuric acid solution, Int. J. Miner. Metall. Mater., 27(2020), No. 2, pp. 264-273. https://doi.org/10.1007/s12613-019-1847-0

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Bao Liu, Shuo Wang, Cheng-yan Wang, Bao-zhong Ma, and Yong-qiang Chen, Electrochemical behavior and corrosion resistance of IrO2–ZrO2 binary oxide coatings for promoting oxygen evolution in sulfuric acid solution, Int. J. Miner. Metall. Mater., 27(2020), No. 2, pp. 264-273. https://doi.org/10.1007/s12613-019-1847-0

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Research Article

Electrochemical behavior and corrosion resistance of IrO₂–ZrO₂ binary oxide coatings for promoting oxygen evolution in sulfuric acid solution

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Corresponding authors:
Cheng-yan Wang E-mail: chywang@yeah.net

Bao-zhong Ma E-mail: bzhma@126.com
Received: 7 March 2019; Revised: 14 April 2019; Accepted: 19 April 2019; Available online: 28 November 2019

Abstract

Abstract

In this study, we prepared Ti/IrO₂–ZrO₂ electrodes with different ZrO₂ contents using zirconium-n-butoxide (C₁₆H₃₆O₄Zr) and chloroiridic acid (H₂IrCl₆) via a sol–gel route. To explore the effect of ZrO₂ content on the surface properties and electrochemical behavior of electrodes, we performed physical characterizations and electrochemical measurements. The obtained results revealed that the binary oxide coating was composed of rutile IrO₂, amorphous ZrO₂, and an IrO₂–ZrO₂ solid solution. The IrO₂–ZrO₂ binary oxide coatings exhibited cracked structures with flat regions. A slight incorporation of ZrO₂ promoted the crystallization of the active component IrO₂. However, the crystallization of IrO₂ was hindered when the added ZrO₂ content was greater than 30at%. The appropriate incorporation of ZrO₂ enhanced the electrocatalytic performance of the pure IrO₂ coating. The Ti/70at%IrO₂–30at%ZrO₂ electrode, with its large active surface area, improved electrocatalytic activity, long service lifetime, and especially, lower cost, is the most effective for promoting oxygen evolution in sulfuric acid solution.
- electrode;
- IrO₂–ZrO₂;
- oxygen evolution reaction;
- electrochemical behavior;
- corrosion resistance

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[1]	D. Devilliers and E. Mahé, Modified titanium electrodes: Application to Ti/TiO₂/PbO₂ dimensionally stable anodes, Electrochim. Acta, 55(2010), No. 27, p. 8207. doi: 10.1016/j.electacta.2010.01.098
[2]	Y. Zhao, Y.F. E, L.Z. Fan, Y.F. Qiu, and S.H. Yang, A new route for the electrodeposition of platinum–nickel alloy nanoparticles on multi-walled carbon nanotubes, Electrochim. Acta, 52(2007), No. 19, p. 5873. doi: 10.1016/j.electacta.2007.03.020
[3]	J. L. Lu, S.F. Lu, D.L. Wang, M. Yang, Z.L. Liu, C.W. Xu, and S.P. Jiang, Nano-structured Pd_xPt_1−x/Ti anodes prepared by electrodeposition for alcohol electrooxidation, Electrochim. Acta, 54(2009), No. 23, p. 5486. doi: 10.1016/j.electacta.2009.04.048
[4]	E. Fabbri, A. Habereder, K. Waltar, R. Kötz, and T.J. Schmidt, Developments and perspectives of oxide-based catalysts for the oxygen evolution reaction, Catal. Sci. Technol., 4(2014), No. 11, p. 3800. doi: 10.1039/C4CY00669K
[5]	S. Siracusano, V. Baglio, A. Di Blasi, N. Briguglio, A. Stassi, R. Ornelas, E. Trifoni, V. Antonucci, and A.S. Aricò, Electrochemical characterization of single cell and short stack PEM electrolyzers based on a nanosized IrO₂ anode electrocatalyst, Int. J. Hydrogen Energy, 35(2010), No. 11, p. 5558. doi: 10.1016/j.ijhydene.2010.03.102
[6]	J. Shu, Z.L. Qiu, S.Z. Lv, K.Y. Zhang, and D.P. Tang, Plasmonic enhancement coupling with defect-engineered TiO_2−x: A mode for sensitive photoelectrochemical biosensing, Anal. Chem., 90(2018), No. 4, p. 2425. doi: 10.1021/acs.analchem.7b05296
[7]	G.N. Cai, Z.Z. Yu, R.R. Ren, and D.P. Tang, Exciton-plasmon interaction between AuNPs/graphene nanohybrids and CdS quantum dots/TiO₂ for photoelectrochemical aptasensing of prostate-specific antigen, ACS Sens., 3(2018), No. 3, p. 632. doi: 10.1021/acssensors.7b00899
[8]	Z.L. Qiu, J. Shu, and D.P. Tang, Near-infrared-to ultraviolet light-mediated photoelectrochemical aptasensing platform for cancer biomarker based on core–shell NaYF₄:Yb, Tm@TiO₂ upconversion microrods, Anal. Chem., 90(2018), No. 1, p. 1021. doi: 10.1021/acs.analchem.7b04479
[9]	J. Tang, D.P. Tang, R. Niessner, and D. Knopp, A novel strategy for ultra-sensitive electrochemical immunoassay of biomarkers by coupling multifunctional iridium oxide (IrO_x) nanospheres with catalytic recycling of self-produced reactants, Anal. Bioanal. Chem., 400(2011), No. 7, p. 2041. doi: 10.1007/s00216-011-4936-0
[10]	X.M. Chen and G.H. Chen, Stable Ti/RuO₂–Sb₂O₅–SnO₂ electrodes for O₂ evolution, Electrochim. Acta, 50(2005), No. 20, p. 4155. doi: 10.1016/j.electacta.2005.01.032
[11]	F. Moradi and C. Dehghanian, Addition of IrO₂ to RuO₂+ TiO₂ coated anodes and its effect on electrochemical performance of anodes in acid media, Prog. Nat. Sci:Mater. Int., 24(2014), No. 2, p. 134. doi: 10.1016/j.pnsc.2014.03.008
[12]	L.M. Gajić-Krstajić, T.L. Trišović, and N.V. Krstajić, Spectrophotometric study of the anodic corrosion of Ti/RuO₂ electrode in acid sulfate solution, Corros. Sci., 46(2004), No. 1, p. 65. doi: 10.1016/S0010-938X(03)00111-2
[13]	R. Shan, Z.C. Zhang, M. Kan, T.Y. Zhang, Q. Zan, and Y.X. Zhao, A novel highly active nanostructured IrO₂/Ti anode for water oxidation, Int. J. Hydrogen Energy, 40(2015), No. 41, p. 14279. doi: 10.1016/j.ijhydene.2015.04.071
[14]	C.E. Vallet, B.V. Tilak, R.A. Zuhr, and C.P. Chen, Rutherford backscattering spectroscopic study of the failure mechanism of (RuO₂ + TiO₂)/Ti thin film electrodes in H₂SO₄ solutions, J. Electrochem. Soc., 144(1997), No. 4, p. 1289. doi: 10.1149/1.1837586
[15]	B.S. Li, A. Lin, and F.X. Gan, Preparation and characterization of Ti/IrO₂–Ta₂O₅ anodes for oxygen evolution used to sulfate electrolysis, Rare Met. Mater. Eng., 36(2007), No. 2, p. 245.
[16]	J. J. Zhang, J. M. Hu, J. Q. Zhang, and C.N. Cao, IrO₂–SiO₂ binary oxide films: Geometric or kinetic interpretation of the improved electrocatalytic activity for the oxygen evolution reaction, Int. J. Hydrogen Energy, 36(2011), No. 9, p. 5218. doi: 10.1016/j.ijhydene.2011.01.131
[17]	C. Iwakura and K. Sakamoto, Effect of active layer composition on the service life of (SnO₂ and RuO₂)-coated Ti electrodes in sulfuric acid solution, J. Electrochem. Soc., 132(1985), No. 10, p. 2420. doi: 10.1149/1.2113590
[18]	G.C. Pathiraja, N. Nanayakkara, and A. Wijayasinghe, Oxygen evolution reaction of Ti/IrO₂–SnO₂ electrodes: a study by cyclic voltammetry, Bull. Mater. Sci., 39(2016), No. 3, p. 803. doi: 10.1007/s12034-016-1190-2
[19]	H.A. Mazhari, K. Jafarzadeh, and S.M. Mirali, An investigation of the effect of RuO₂ on the deactivation and corrosion mechanism of a Ti/IrO₂–Ta₂O₅ coating in an OER application, J. Electroanal. Chem., 777(2016), p. 67. doi: 10.1016/j.jelechem.2016.07.036
[20]	G.P. Vercesi, J. Y. Salamin, and C. Comninellis, Morphological and microstructural the Ti/IrO₂–Ta₂O₅ electrode: effect of the preparation temperature, Electrochim. Acta, 36(1991), No. 5-6, p. 991. doi: 10.1016/0013-4686(91)85306-R
[21]	R.E. Palma-Goyes, J. Vazquez-Arenas, C. Ostos, R.A. Torres-Palma, and I. González, The effects of ZrO₂ on the electrocatalysis to yield active chlorine species on Sb₂O₅-doped Ti/RuO₂ anodes, J. Electrochem. Soc, 163(2016), No. 9, p. H818. doi: 10.1149/2.0891609jes
[22]	L.D. Burke and M. McCarthy, Oxygen gas evolution at, and deterioration of, RuO₂/ZrO₂-coated titanium anodes at elevated temperature in strong base, Electrochim. Acta, 29(1984), No. 2, p. 211. doi: 10.1016/0013-4686(84)87049-8
[23]	J. B. Wang, W.P. Zhu, X.W. He, and S.X. Yang, Catalytic wet air oxidation of acetic acid over different ruthenium catalysts, Catal. Commun., 9(2008), No. 13, p. 2163. doi: 10.1016/j.catcom.2008.04.019
[24]	Y.Q. Shao, Z.Y. Yi, C. He, J. Q. Zhu, and D. Tang, Effects of annealing temperature on the structure and capacitive performance of nanoscale Ti/IrO₂–ZrO₂ electrodes, J. Am. Ceram. Soc., 98(2015), No. 5, p. 1485. doi: 10.1111/jace.13475
[25]	C.H. Comninellis and G.P. Vercesi, Characterization of DSA^®-type oxygen evolving electrodes: choice of a coating, J. Appl. Electrochem., 21(1991), No. 4, p. 335. doi: 10.1007/BF01020219
[26]	A.J. Terezo and E.C. Pereira, Preparation and characterisation of Ti/RuO₂ anodes obtained by sol-gel and conventional routes, Mater. Lett., 53(2002), No. 4-5, p. 339. doi: 10.1016/S0167-577X(01)00504-3
[27]	B. Liu, C.Y. Wang, Y.Q. Chen, B.Z. Ma, and J. L. Zhang, Effects of calcination temperature on the surface morphology and electrocatalytic properties of Ti/IrO₂–ZrO₂ anodes in an oxygen evolution application, J. Electrochem. Soc., 165(2018), No. 14, p. F1192. doi: 10.1149/2.0701814jes
[28]	G.R.P. Malpass and A.J. Motheo, Cyclic voltammetric behavior of dimensionally stable anodes in the presence of C1-C3 aldehydes, J. Braz. Chem. Soc., 14(2003), No. 4, p. 645. doi: 10.1590/S0103-50532003000400023
[29]	W.H. Lee and H. Kim, Oxidized iridium nanodendrites as catalysts for oxygen evolution reactions, Catal. Commum., 12(2011), No. 6, p. 408. doi: 10.1016/j.catcom.2010.11.003
[30]	W. Xu, G.M. Haarberg, S. Sunde, F. Seland, A.P. Ratvik, E. Zimmerman, T. Shimamune, J. Gustavsson, and T. Akre, Calcination temperature dependent catalytic activity and stability of IrO₂–Ta₂O₅ anodes for oxygen evolution reaction in aqueous sulfate electrolytes, J. Electrochem. Soc, 164(2017), No. 9, p. F895. doi: 10.1149/2.0061710jes
[31]	L.K. Wu, X.Y. Liu, and J.M. Hu, Electrodeposited SiO₂ film: a promising interlayer of a highly active Ti electrode for the oxygen evolution reaction, J. Mater. Chem. A, 4(2016), No. 30, p. 11949. doi: 10.1039/C6TA03931F
[32]	L.A. Da Silva, V.A. Alves, M.A.P. Da Silva, S. Trasatti, and J.F.C. Boodts, Morphological chemical and electrochemical properties of Ti/(TiO₂–IrO₂) electrodes, Can. J. Chem., 75(1997), No. 11, p. 1483. doi: 10.1139/v97-178
[33]	V. Pfeifer, T.E. Jones, J.J. Velasco Vélez, C. Massué, M.T. Greiner, R. Arrigo, D. Teschner, F. Girgsdies, M. Scherzer. J. Allan, M. Hashagen, G. Weinberg, S. Piccinin, M. Hävecker, A. Knop-Gericke, and R. Schlögl, The electronic structure of iridium oxide electrodes active in water splitting, Phys. Chem. Chem. Phys., 18(2016), p. 2292. doi: 10.1039/C5CP06997A
[34]	R.D. Xu, L.P. Huang, J.F. Zhou, P. Zhan, Y.Y. Guan, and Y. Kong, Effects of tungsten carbide on electrochemical properties and microstructural features of Al/Pb–PANI–WC composite inert anodes used in zinc electrowinning, Hydrometallurgy, 125-126(2012), p. 8. doi: 10.1016/j.hydromet.2012.04.012
[35]	T. Audichon, S. Morisset, T.W. Napporn, K.B. Kokoh, C. Comminges, and C. Morals, Effect of adding CeO₂ to RuO₂–IrO₂ mixed nanocatalysts: activity towards the oxygen evolution reaction and stability in acidic media, ChemElectroChem, 2(2015), No. 8, p. 1128. doi: 10.1002/celc.201500072
[36]	E. Rasten, G. Hagen, and R. Tunold, Electrocatalysts in water electrolysis with solid polymer electrolyte, Electrochim. Acta, 48(2003), No. 25-26, p. 3945. doi: 10.1016/j.electacta.2003.04.001
[37]	M.H.P. Santana, L.A. De Faria, and J.F.C. Boodts, Effect of preparation procedure of IrO₂–Nb₂O₅ anodes on surface and electrocatalytic properties, J. Appl. Electrochem., 35(2005), No. 9, p. 915. doi: 10.1007/s10800-005-4720-y
[38]	L.M. Da Silva, L.A. De Faria, and J.F.C. Boodts, Electrochemical ozone production: influence of the supporting electrolyte on kinetics and current efficiency, Electrochim. Acta, 48(2003), No. 6, p. 699. doi: 10.1016/S0013-4686(02)00739-9
[39]	T.A.F. Lassali, J.F.C. Boodts, and L.O.S. Bulhoes, Charging processes and electrocatalytic properties of IrO₂/TiO₂/SnO₂ oxide films investigated byin situ AC impedance measurements, Electrochim. Acta, 44(1999), No. 24, p. 4203. doi: 10.1016/S0013-4686(99)00135-8
[40]	J. M. Hu, H.M. Meng, J.Q. Zhang, and C.N. Cao, Degradation mechanism of long service life Ti/IrO₂–Ta₂O₅ oxide anodes in sulphuric acid, Corros. Sci., 44(2002), No. 8, p. 1655. doi: 10.1016/S0010-938X(01)00165-2
[41]	Y.Y. Hou, J.M. Hu, L. Liu, J.Q. Zhang, and C.N. Cao, Effects of calcination temperature on electrocatalytic activities of Ti/IrO₂ electrodes in methanol aqueous solutions, Electrochim. Acta, 51(2006), No. 28, p. 6258. doi: 10.1016/j.electacta.2006.04.008
[42]	S. Palmas, A.M. Polcaro, F. Ferrara, J.R. Ruiz, F. Delogu, C. Bonatto-Minella, and G. Mulas, Electrochemical performance of mechanically treated SnO₂ powers for OER in acid solution, J. Appl. Electrochem., 38(2008), No. 7, p. 907. doi: 10.1007/s10800-008-9494-6
[43]	B. Piela and P.K. Wrona, Capacitance of the gold electrode in 0.5 M H₂SO₄ solution: a.c. impedance studies, J. Appl. Electroanal. Chem., 388(1995), No. 1-2, p. 69. doi: 10.1016/0022-0728(94)03848-W
[44]	H.T. Yang, H.R. Liu, Z.C. Guo, B.M. Chen, Y.C. Zhang, H. Huang, X.L. Li, R.C. Fu, and R.D. Xu, Electrochemical behavior of rolled Pb–0.8%Ag anodes, Hydrometallurgy, 140(2013), p. 144. doi: 10.1016/j.hydromet.2013.10.003
[45]	V.A. Alves, L.A. da Silva, and J.F.C. Boodts, Surface characterisation of IrO₂/TiO₂/CeO₂ oxide electrodes and Faradaic impedance investigation of the oxygen evolution reaction from alkaline solution, Electrochim. Acta, 44(1998), No. 8-9, p. 1525. doi: 10.1016/S0013-4686(98)00276-X
[46]	Z.G. Ye, H.M. Meng, and D.B. Sun, New degradation mechanism of Ti/IrO₂–MnO₂ anode for oxygen evolution in 0.5 M H₂SO₄ solution, Electrochim. Acta, 53(2008), No. 18, p. 5639. doi: 10.1016/j.electacta.2008.03.025
[47]	G.N. Martelli, R. Ornelas, and G. Faita, Deactivation mechanisms of oxygen evolving anodes at high current densities, Electrochim. Acta, 39(1994), No. 11-12, p. 1551. doi: 10.1016/0013-4686(94)85134-4
[48]	R. Kötz, H. Neff, and S. Stucki, Anodic iridium oxide films: XPS-studies of oxidation state changes and O₂-evolution, J. Electrochem. Soc., 131(1984), No. 1, p. 72. doi: 10.1149/1.2115548
[49]	Y. Song, G. Wei, and R. Xiong, Structure and properties of PbO₂−CeO₂ anodes on stainless steel, Electrochim. Acta, 52(2007), No. 24, p. 7022. doi: 10.1016/j.electacta.2007.05.024
[50]	H.T. Yang, B.M. Chen, H.R. Liu, Z.C. Guo, Y.C. Zhang, X.L. Li, and R.D. Xu, Effects of manganese nitrate concentration on the performance of an aluminum substrate β-PbO₂–MnO₂–WC–ZrO₂ composite electrode material, Int. J. Hydrogen Energy, 39(2014), No. 7, p. 3087. doi: 10.1016/j.ijhydene.2013.12.091
[51]	W. Zhang, E. Ghali, and G. Houlachi, Review of oxide coated catalytic titanium anodes performance for metal electrowinning, Hydrometallurgy, 169(2017), p. 456. doi: 10.1016/j.hydromet.2017.02.014