Extraction and kinetic analysis of Pb and Sr from the leaching residue of zinc oxide ore

Xiao-yi Shen; Yuan-yong Liang; Hong-mei Shao; Yi Sun; Yan Liu; Yu-chun Zhai

doi:10.1007/s12613-020-1972-9

Volume 28 Issue 2

Feb. 2021

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Article Navigation > International Journal of Minerals, Metallurgy and Materials > 2021 > 28(2): 201-209

Xiao-yi Shen, Yuan-yong Liang, Hong-mei Shao, Yi Sun, Yan Liu, and Yu-chun Zhai, Extraction and kinetic analysis of Pb and Sr from the leaching residue of zinc oxide ore, Int. J. Miner. Metall. Mater., 28(2021), No. 2, pp. 201-209. https://doi.org/10.1007/s12613-020-1972-9

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Xiao-yi Shen, Yuan-yong Liang, Hong-mei Shao, Yi Sun, Yan Liu, and Yu-chun Zhai, Extraction and kinetic analysis of Pb and Sr from the leaching residue of zinc oxide ore, Int. J. Miner. Metall. Mater., 28(2021), No. 2, pp. 201-209. https://doi.org/10.1007/s12613-020-1972-9

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Research Article

Extraction and kinetic analysis of Pb and Sr from the leaching residue of zinc oxide ore

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Corresponding author:
Xiao-yi Shen E-mail: shenxy@smm.neu.edu.cn
Received: 13 November 2019; Revised: 17 December 2019; Accepted: 20 December 2019; Available online: 12 October 2020

Abstract

Abstract

NH₄HCO₃ conversion followed by HCl leaching was performed and proven to be effective in extracting Pb and Sr from zinc extracted residual. The mechanism and operating conditions of NH₄HCO₃ conversion, including molar ratio of NH₄HCO₃ to zinc extracted residual, NH₄HCO₃ concentration, conversion temperature, conversion time, and stirring velocity, were discussed, and operating conditions were optimized by the orthogonal test. Experimental results indicate that NH₄HCO₃ conversion at temperatures ranging from 25 to 85°C follows the shrinking unreacted core model and is controlled by inner diffusion through the product layer. The extraction ratios of Pb and Sr under optimized conditions reached 85.15% and 87.08%, respectively. Moreover, the apparent activation energies of Pb and Sr were 13.85 and 13.67 kJ·mol⁻¹, respectively.
- zinc extraction residual;
- NH₄HCO₃ conversion;
- HCl leaching;
- Pb;
- Sr;
- reaction mechanism;
- kinetics

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