Cite this article as: |
K. Bin Tayyab, A. Farooq, A. Ahmed Alvi, A. Basit Nadeem, and K.M. Deen, Corrosion behavior of cold-rolled and post heat-treated 316L stainless steel in 0.9wt% NaCl solution, Int. J. Miner. Metall. Mater., 28(2021), No. 3, pp. 440-449. https://doi.org/10.1007/s12613-020-2054-8 |
K.M. Deen E-mail: kmdeen.ceet@pu.edu.pk
The effect of cold rolling and post-rolling heat treatment on the microstructural and electrochemical properties of the 316L stainless steel was investigated. Two-pass and four-pass cold-rolled stainless steel specimens were heat-treated by annealing at 900°C followed by quenching in water. During the cold rolling, the microstructure of the as-received specimen transformed from austenite to strain-induced α′-martensite due to significant plastic deformation that also resulted in significant grain elongation (i.e., ~33% and 223% increases in the grain elongation after two and four rolling passes, respectively). The hardness of the heat-treated as-received specimen decreased from HV 190 to 146 due to the recovery and recrystallization of the austenite grain structure. The cyclic polarization scans of the as-rolled and heat-treated specimens were obtained in 0.9wt% NaCl solution. The pitting potential of the four-pass rolled specimen was significantly increased from 322.3 to 930.5 mV after post-rolling heat treatment. The beneficial effect of the heat treatment process was evident from ~10-times-lower corrosion current density and two-orders-of-magnitude-lower passive current density of the heat-treated specimens compared with those of the as-rolled specimens. Similarly, appreciably lower corrosion rate (3.302 × 10−4 mm/a) and higher pitting resistance (1115.5 mV) were exhibited by the post-rolled heat-treated specimens compared with the as-rolled 316L stainless steel specimens.
[1] |
C.C. Shih, C.M. Shih, Y.Y. Su, L.H.J. Su, M.S. Chang, and S.J. Lin, Effect of surface oxide properties on corrosion resistance of 316L stainless steel for biomedical applications, Corros. Sci., 46(2004), No. 2, p. 427. doi: 10.1016/S0010-938X(03)00148-3
|
[2] |
M.J.K. Lodhi, K.M. Deen, M.C. Greenlee-Wacker, and W. Haider, Additively manufactured 316L stainless steel with improved corrosion resistance and biological response for biomedical applications, Addit. Manuf., 27(2019), p. 8.
|
[3] |
J.A. Helsen and Y. Missirlis, Biomaterials: A Tantalus Experience, Springer, Berlin, Heidelberg, 2010, p. 607.
|
[4] |
T. Balusamy, S. Kumar, and T.S.N.S. Narayanan, Effect of surface nanocrystallization on the corrosion behaviour of AISI 409 stainless steel, Corros. Sci., 52(2010), No. 11, p. 3826. doi: 10.1016/j.corsci.2010.07.004
|
[5] |
G. Lorang, M.D.C. Belo, A.M.P. Simões, and M.G.S. Ferreira, Chemical composition of passive films on AISI 304 stainless steel, J. Electrochem. Soc., 141(1994), No. 12, p. 3347. doi: 10.1149/1.2059338
|
[6] |
L. Freire, M.J. Carmezim, M.G.S. Ferreira, and M.F. Montemor, The passive behaviour of AISI 316 in alkaline media and the effect of pH: A combined electrochemical and analytical study, Electrochim. Acta, 55(2010), No. 21, p. 6174. doi: 10.1016/j.electacta.2009.10.026
|
[7] |
M.J.K. Lodhi, K.M. Deen, and W. Haider, Corrosion behavior of additively manufactured 316L stainless steel in acidic media, Materialia, 2(2018), p. 111. doi: 10.1016/j.mtla.2018.06.015
|
[8] |
Y. Zhao, X.P. Li, C. Zhang, T. Zhang, J.F. Xie, G.X. Zeng, D.K. Xu, and F.H. Wang, Investigation of the rotation speed on corrosion behavior of HP-13Cr stainless steel in the extremely aggressive oilfield environment by using the rotating cage test, Corros. Sci., 145(2018), p. 307. doi: 10.1016/j.corsci.2018.10.011
|
[9] |
H. Feng, Z.H. Jiang, H.B. Li, P.C. Lu, S.C. Zhang, H.C. Zhu, B.B. Zhang, T. Zhang, D.K. Xu, and Z.G. Chen, Influence of nitrogen on corrosion behavior of high nitrogen martensitic stainless steels manufactured by pressurized metallurgy, Corros. Sci., 144(2018), p. 288. doi: 10.1016/j.corsci.2018.09.002
|
[10] |
H. Feng, H.B. Li, X.L. Wu, Z.H. Jiang, S. Zhao, T. Zhang, D.K. Xu, S.C. Zhang, H.C. Zhu, B.B. Zhang, and M.X. Yang, Effect of nitrogen on corrosion behavior of a novel high nitrogen medium-entropy alloy CrCoNiN manufactured by pressurized metallurgy, J. Mater. Sci. Technol., 34(2018), No. 10, p. 1781. doi: 10.1016/j.jmst.2018.03.021
|
[11] |
Z.B. Wang, N.R. Tao, W.P. Tong, J. Lu, and K. Lu, Diffusion of chromium in nanocrystalline iron produced by means of surface mechanical attrition treatment, Acta Mater., 51(2003), No. 14, p. 4319. doi: 10.1016/S1359-6454(03)00260-X
|
[12] |
M. Pisarek, P. Kędzierzawski, T. Płociński, M. Janik-Czachor, and K.J. Kuraydłowski, Characterization of the effects of hydrostatic extrusion on grain size, surface composition and the corrosion resistance of austenitic stainless steels, Mater. Charact., 59(2008), No. 9, p. 1292. doi: 10.1016/j.matchar.2007.11.002
|
[13] |
B. Zhang, Y. Li, and F.H. Wang, Electrochemical corrosion behaviour of microcrystalline aluminium in acidic solutions, Corros. Sci., 49(2007), No. 5, p. 2071. doi: 10.1016/j.corsci.2006.11.006
|
[14] |
J. Park and R.S. Lakes, Biomaterial: An Introduction, 3rd ed., Springer, New York, 2007.
|
[15] |
Y. Fu, X.Q. Wu, E.H. Han, W. Ke, K. Yang, and Z.H. Jiang, Effects of cold work and sensitization treatment on the corrosion resistance of high nitrogen stainless steel in chloride solutions, Electrochim. Acta, 54(2009), No. 5, p. 1618. doi: 10.1016/j.electacta.2008.09.053
|
[16] |
S.V. Muley, A.N. Vidvans, G.P. Chaudhari, and S. Udainiya, An assessment of ultra fine grained 316L stainless steel for implant applications, Acta Biomater., 30(2016), p. 408. doi: 10.1016/j.actbio.2015.10.043
|
[17] |
M. Pisarek, P. Kędzierzawski, M. Janik-Czachor, and K.J. Kurzydłowski, The effect of hydrostatic extrusion on resistance of 316 austenitic stainless steel to pit nucleation, Electrochem. Commun., 9(2007), No. 10, p. 2463. doi: 10.1016/j.elecom.2007.07.028
|
[18] |
C.J. Semino, P. Pedeferri, G.T. Burstein, and T.P. Hoar, The localized corrosion of resistant alloys in chloride solutions, Corros. Sci., 19(1979), No. 7, p. 1069. doi: 10.1016/S0010-938X(79)80096-7
|
[19] |
P.L. Mangonon and G. Thomas, Structure and properties of thermal-mechanically treated 304 stainless steel, Metall. Trans., 1(1970), No. 6, p. 1587. doi: 10.1007/BF02642004
|
[20] |
R.B. Cruise and L. Gardner, Strength enhancements induced during cold forming of stainless steel sections, J. Constr. Steel Res., 64(2008), No. 11, p. 1310. doi: 10.1016/j.jcsr.2008.04.014
|
[21] |
B. Mazza, P. Pedeferri, D. Sinigaglia, A. Cigada, G. Fumagalli, and G. Re, Electrochemical and corrosion behavior of work-hardened commercial austenitic stainless steels in acid solutions, Corros. Sci., 19(1979), No. 11, p. 907. doi: 10.1016/S0010-938X(79)80112-2
|
[22] |
G. Schmitt and K. Bedbur, Investigations on structural and electronic effects in acid inhibitors by AC impedance, [in] Proceedings of the 9th International Congress on Metallic Corrosion, Toronto, Canada, 1984, p. 112.
|
[23] |
H.P. Leckie and H.H. Uhlig, Environmental factors affecting the critical potential for pitting in 18-8 stainless steel, J. Electrochem. Soc., 113(1966), No. 12, p. 1262. doi: 10.1149/1.2423801
|
[24] |
K.M. Deen, M.A. Virk, C.I. Haque, R. Ahmad, and I.H. Khan, Failure investigation of heat exchanger plates due to pitting corrosion, Eng. Fail. Anal., 17(2010), No. 4, p. 886. doi: 10.1016/j.engfailanal.2009.10.023
|
[25] |
S.D. Cramer and B.S. Covino, Corrosion: Fundamentals, Testing, and Protection, ASM International, Materials Park, OH, 2003.
|
[26] |
M. Eskandari, M. Yeganeh, and M. Motamedi, Investigation in the corrosion behavior of bulk nanocrystalline 316L austenitic stainless steel in NaCl solution, Micro Nano Lett., 7(2012), No. 4, p. 380. doi: 10.1049/mnl.2012.0162
|
[27] |
J.H. Shin and J.W. Lee, Effects of twin intersection on the tensile behavior in high nitrogen austenitic stainless steel, Mater. Charact., 91(2014), p. 19. doi: 10.1016/j.matchar.2014.01.025
|
[28] |
S.H. Avner, Introduction to Physical Metallurgy, 2nd ed., McgrawHill, New York, 1974.
|
[29] |
T. Sourmail, P. Opdenacker, G. Hopkin, and H.K.D.H. Bhadeshia, Metals and Alloys: Annealing Twins, University of Cambridge (2001). https://www.phase-trans.msm.cam.ac.uk/abstracts/annealing.twin.html
|
[30] |
N. Solomon and I. Solomon, Effect of deformation-induced phase transformation on AISI 316 stainless steel corrosion resistance, Eng. Fail. Anal., 79(2017), p. 865. doi: 10.1016/j.engfailanal.2017.05.031
|
[31] |
N. Solomon and I. Solomon, Deformation induced martensite in AISI 316 stainless steel, Rev. Metal., 46(2010), No. 2, p. 121. doi: 10.3989/revmetalm.0920
|
[32] |
Z.H. Jiang, H. Feng, H.B. Li, H.C. Zhu, S.C. Zhang, B.B. Zhang, Y. Han, T. Zhang, and D.K. Xu, Relationship between microstructure and corrosion behavior of martensitic high nitrogen stainless steel 30Cr15Mo1N at different austenitizing temperatures, Materials, 10(2017), No. 8, p. 861. doi: 10.3390/ma10080861
|
[33] |
W. Ozgowicz, A. Kurc, and M. Kciuk, Effect of deformation-induced martensite on the microstructure, mechanical properties and corrosion resistance of X5CrNi18-8 stainless steel, Arch. Mater. Sci. Eng., 43(2010), No. 1, p. 42.
|
[34] |
D. Fahr, Stress- and strain-induced formation of martensite and its effects on strength and ductility of metastable austenitic stainless steels, Metall. Trans., 2(1971), No. 7, p. 1883.
|
[35] |
H. Chandler, Heat Treater's Guide: Practices and Procedures for Irons and Steels, 2nd ed., ASM International, Materials Park, OH, 1995.
|
[36] |
C. Suryanarayana, Microstructure: An introduction, [in] N.E. Prasad and R.J.H. Wanhill, eds., Aerospace Materials and Meterial Technologies: Volume 2: Aerospace Material Technologies, Springer, Singapore, 2017, p. 105.
|
[37] |
M.A. Meyers and K.K. Chawla, Mechanical Behavior of Materials, 2nd ed., Cambridge University Press, Cambridge, 2009.
|
[38] |
W.B. Qin, J.S. Li, Y.Y. Liu, W. Yue, C.B. Wang, Q.Z. Mao, and Y.S. Li, Effect of rolling strain on the mechanical and tribological properties of 316L stainless steel, J. Tribol., 141(2019), No. 2, art. No. 021606. doi: 10.1115/1.4041214
|
[39] |
D.M. Xu, X.L. Wan, J.X. Yu, G. Xu, and G.Q. Li, Effect of cold deformation on microstructures and mechanical properties of austenitic stainless steel, Metals, 8(2018), No. 7, art. No. 522. doi: 10.3390/met8070522
|
[40] |
R.B. Song, J.Y. Xiang, and D.P. Hou, Characterization of mechanical properties and microstructure for 316L austenitic stainless steel, J. Iron Steel Res. Int., 18(2011), No. 11, p. 53. doi: 10.1016/S1006-706X(11)60117-9
|
[41] |
M. Pourbaix, Atlas of Electrochemical Equilibria in Aqueous Solution, 2nd ed., National Association of Corrosion Engineers, Houston, 1974.
|
[42] |
Y.S. Lim, J.S. Kim, S.J. Ahn, H.S. Kwon, and Y. Katada, The influence of microstructure and nitrogen alloying on pitting corrosion of type 316L and 20wt.% Mn-substituted type 316L stainless steels, Corros. Sci., 43(2001), No. 1, p. 53. doi: 10.1016/S0010-938X(00)00074-3
|
[43] |
S. Esmailzadeh, M. Aliofkhazraei, and H. Sarlak, Interpretation of cyclic potentiodynamic polarization test results for study of corrosion behaviour of metals: A Review, Prot. Met. Phys. Chem. Surf., 54(2018), No. 5, p. 976. doi: 10.1134/S207020511805026X
|
[44] |
R.M. Cornell, A.M. Posner, and J.P. Quirk, Kinetics and mechanisms of the acid dissolution of goethite (α-FeOOH), J. Inorg. Nucl. Chem., 38(1976), No. 3, p. 563. doi: 10.1016/0022-1902(76)80305-3
|
[45] |
S. Tanhaei, K. Gheisari, and S.R.A. Zaree, Effect of cold rolling on the microstructural. magnetic, mechanical.and corrosion properties of AISI 316L austenitic stainless steel, Int. J. Miner. Metall. Mater., 25(2018), No. 6, p. 630. doi: 10.1007/s12613-018-1610-y
|
[46] |
A. Farooq, K.M. Deen, I.H. Khan, M.A. Raza, R. Ahmad, A. Salam, and W. Haider, Peculiar corrosion behavior of type 316L SS in simulated cooling water at various pH values, Mater. Perform., 53(2014), No. 10, p. 44.
|