En-dian Fan, Shi-qi Zhang, Dong-han Xie, Qi-yue Zhao, Xiao-gang Li,  and Yun-hua Huang, Effect of nanosized NbC precipitates on hydrogen-induced cracking of high-strength low-alloy steel, Int. J. Miner. Metall. Mater., 28(2021), No. 2, pp. 249-256. https://doi.org/10.1007/s12613-020-2167-0
Cite this article as:
En-dian Fan, Shi-qi Zhang, Dong-han Xie, Qi-yue Zhao, Xiao-gang Li,  and Yun-hua Huang, Effect of nanosized NbC precipitates on hydrogen-induced cracking of high-strength low-alloy steel, Int. J. Miner. Metall. Mater., 28(2021), No. 2, pp. 249-256. https://doi.org/10.1007/s12613-020-2167-0
Research Article

Effect of nanosized NbC precipitates on hydrogen-induced cracking of high-strength low-alloy steel

+ Author Affiliations
  • Corresponding author:

    Yun-hua Huang    E-mail: huangyh@mater.ustb.edu.cn

  • Received: 27 December 2019Revised: 7 August 2020Accepted: 10 August 2020Available online: 14 August 2020
  • We investigated the effect of nanosized NbC precipitates on hydrogen-induced cracking (HIC) of high-strength low-alloy steel by conducting slow-strain-rate tensile tests (SSRT) and performing continuous hydrogen charging and fracture analysis. The results reveal that the HIC resistance of Nb-bearing steel is obviously superior to that of Nb-free steel, with the fractured Nb-bearing steel in the SSRT exhibiting a smaller ratio of elongation reduction (Iδ). However, as the hydrogen traps induced by NbC precipitates approach hydrogen saturation, the effect of the precipitates on the HIC resistance attenuate. We speculate that the highly dispersed nanosized NbC precipitates act as irreversible hydrogen traps that hinder the accumulation of hydrogen at potential crack nucleation sites. In addition, much like Nb-free steel, the Nb-bearing steel exhibits both H-solution strengthening and the resistance to HIC.

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  • [1]
    D. Hardie, E.A. Charles, and A.H. Lopez, Hydrogen embrittlement of high strength pipeline steels, Corros. Sci., 48(2006), No. 12, p. 4378. doi: 10.1016/j.corsci.2006.02.011
    [2]
    A.J. Haq, K. Muzaka, D.P. Dunne, A. Calka, and E.V. Pereloma, Effect of microstructure and composition on hydrogen permeation in X70 pipeline steels, Int. J. Hydrogen Energy, 38(2013), No. 5, p. 2544. doi: 10.1016/j.ijhydene.2012.11.127
    [3]
    G. Lovicu, M. Bottazzi, F. D'Aiuto, M. De Sanctis, A. Dimatteo, C. Santus, and R. Valentini, Hydrogen embrittlement of automotive advanced high-strength steels, Metall. Mater. Trans. A, 43(2012), No. 11, p. 4075. doi: 10.1007/s11661-012-1280-8
    [4]
    S.Q. Zhang, Y.H. Huang, B.T. Sun, Q.L. Liao, H.Z. Lu, B. Jian, H. Mohrbacher, W. Zhang, A.M. Guo, and Y. Zhang, Effect of Nb on hydrogen-induced delayed fracture in high strength hot stamping steels, Mater. Sci. Eng. A, 626(2015), p. 136. doi: 10.1016/j.msea.2014.12.051
    [5]
    Y. Komatsuzaki, H. Joo, and K. Yamada, Influence of yield strength levels on crack growth mode in delayed fracture of structural steels, Eng. Fract. Mech., 75(2008), No. 3-4, p. 551. doi: 10.1016/j.engfracmech.2007.02.009
    [6]
    S.Q. Zheng, Y.M. Qi, C.F. Chen, and S.Y. Li, Effect of hydrogen and inclusions on the tensile properties and fracture behavior of A350LF2 steels after exposure to wet H2S environments, Corros. Sci., 60(2012), p. 59. doi: 10.1016/j.corsci.2012.04.012
    [7]
    W. Wu, Z.Y. Liu, S.S. Hu, X.G. Li, and C.W. Du, Effect of pH and hydrogen on the stress corrosion cracking behavior of duplex stainless steel in marine atmosphere environment, Ocean Eng., 146(2017), p. 311. doi: 10.1016/j.oceaneng.2017.10.002
    [8]
    D. Hejazi, A.J. Haq, N. Yazdipour, D.P. Dunne, A. Calka, F. Barbaro, and E.V. Pereloma, Effect of manganese content and microstructure on the susceptibility of X70 pipeline steel to hydrogen cracking, Mater. Sci. Eng. A, 551(2012), p. 40. doi: 10.1016/j.msea.2012.04.076
    [9]
    L. Lin, B.S. Li, G.M. Zhu, Y.L. Kang, and R.D. Liu, Effect of niobium precipitation behavior on microstructure and hydrogen induced cracking of press hardening steel 22MnB5, Mater. Sci. Eng. A, 721(2018), p. 38. doi: 10.1016/j.msea.2018.02.021
    [10]
    S.Q. Zhang, Q.Y. Zhao, J. Liu, F. Huang, Y.H. Huang, and X.G. Li, Understanding the effect of niobium on hydrogen-induced blistering in pipeline steel: A combined experimental and theoretical study, Corros. Sci., 159(2019), art. No. 108142. doi: 10.1016/j.corsci.2019.108142
    [11]
    S.Q. Zhang, E.D. Fan, J.F. Wan, J. Liu, Y.H. Huang, and X.G. Li, Effect of Nb on the hydrogen-induced cracking of high-strength low-alloy steel, Corros. Sci., 139(2018), p. 83. doi: 10.1016/j.corsci.2018.04.041
    [12]
    R.J. Shi, Z.D. Wang, L.J. Qiao, and X.L. Pang, Effect of in-situ nanoparticles on the mechanical properties and hydrogen embrittlement of high-strength steel, Int. J. Miner. Metall. Mater., (2020). DOI: /10.1007/s12613-020-2157-2
    [13]
    A. Nagao, M.L. Martin, M. Dadfarnia, P. Sofronis, and I.M. Robertson, The effect of nanosized (Ti,Mo)C precipitates on hydrogen embrittlement of tempered lath martensitic steel, Acta Mater., 74(2014), p. 244. doi: 10.1016/j.actamat.2014.04.051
    [14]
    L.F. Li, B. Song, Z.Y. Cai, Z. Liu, and X.K. Cui, Effect of vanadium content on hydrogen diffusion behaviors and hydrogen induced ductility loss of X80 pipeline steel, Mater. Sci. Eng. A, 742(2019), p. 712. doi: 10.1016/j.msea.2018.09.048
    [15]
    L. Cho, E.J. Seo, D.H. Sulistiyo, K.R. Jo, S.W. Kim, J.K. Oh, Y.R. Cho, and B.C. De Cooman, Influence of vanadium on the hydrogen embrittlement of aluminized ultra-high strength press hardening steel, Mater. Sci. Eng. A, 735(2018), p. 448. doi: 10.1016/j.msea.2018.08.027
    [16]
    Q.Q. Qiao, L. Lu, E.D. Fan, J.B. Zhao, Y.L. Liu, G.C. Peng, Y.H. Huang, and X.G. Li, Effects of Nb on stress corrosion cracking of high-strength low-alloy steel in simulated seawater, Int. J. Hydrogen Energy, 44(2019), No. 51, p. 27962. doi: 10.1016/j.ijhydene.2019.08.259
    [17]
    S.Q. Zhang, J.F. Wan, Q.Y. Zhao, J. Liu, F. Huang, Y.H. Huang, and X.G. Li, Dual role of nanosized NbC precipitates in hydrogen embrittlement susceptibility of lath martensitic steel, Corros. Sci., 164(2020), art. No. 108345. doi: 10.1016/j.corsci.2019.108345
    [18]
    Z.J. Xie, X.P. Ma, C.J. Shang, X.M. Wang, and S.V. Subramanian, Nano-sized precipitation and properties of a low carbon niobium micro-alloyed bainitic steel, Mater. Sci. Eng. A, 641(2015), p. 37. doi: 10.1016/j.msea.2015.05.101
    [19]
    Z.H. Wang, J.S. Wu, J. Li, X.G. Wu, Y.H. Huang, and X.G. Li, Effects of niobium on the mechanical properties and corrosion behavior of simulated weld HAZ of HSLA steel, Metall. Mater. Trans. A, 49(2018), p. 187. doi: 10.1007/s11661-017-4391-4
    [20]
    X.W. Chen, G.Y. Qiao, X.L. Han, X. Wang, F.R. Xiao, and B. Liao, Effects of Mo, Cr and Nb on microstructure and mechanical properties of heat affected zone for Nb-bearing X80 pipeline steels, Mater. Des., 53(2014), p. 888. doi: 10.1016/j.matdes.2013.07.037
    [21]
    S.L. Jeng, H.T. Lee, H.Y. Huang, and R.C. Kuo, Effects of Nb on the microstructure and elevated-temperature mechanical properties of alloy 690-SUS 304L dissimilar welds, Mater. Trans., 49(2008), No. 6, p. 1270. doi: 10.2320/matertrans.MRA2008008
    [22]
    J. Takahashi, K. Kawakami, and Y. Kobayashi, Origin of hydrogen trapping site in vanadium carbide precipitation strengthening steel, Acta Mater., 153(2018), p. 193. doi: 10.1016/j.actamat.2018.05.003
    [23]
    A. Turk, D. San Martín, P.E.J. Rivera-Díaz-del-Castillo, and E.I. Galindo-Nava, Correlation between vanadium carbide size and hydrogen trapping in ferritic steel, Scripta Mater., 152(2018), p. 112. doi: 10.1016/j.scriptamat.2018.04.013
    [24]
    Z.X. Peng, J. Liu, F. Huang, Q. Hu, Z.Y. Cheng, S. Liu, and Y.F. Cheng, Effect of submicron-scale MnS inclusions on hydrogen trapping and HIC susceptibility of X70 pipeline steels, Steel Res. Int., 89(2018), No. 7, art. No. 1700566. doi: 10.1002/srin.201700566
    [25]
    J. Ma, F. Feng, B.Q. Yu, H.F. Chen, and L.F. Fan, Effect of cooling temperature on the microstructure and corrosion behavior of X80 pipeline steel, Int. J. Miner. Metall. Mater., 27(2020), No. 3, p. 347. doi: 10.1007/s12613-019-1882-x
    [26]
    P. Zhao, C. Cheng, G. Gao, W. Hui, R.D.K. Misra, B. Bai, and Y. Weng, The potential significance of microalloying with niobium in governing very high cycle fatigue behavior of bainite/martensite multiphase steels, Mater. Sci. Eng. A, 650(2016), p. 438. doi: 10.1016/j.msea.2015.10.044
    [27]
    A.G. Kalashami, A. Kermanpur, E. Ghassemali, A. Najafizadeh, and Y. Mazaheri, Correlation of microstructure and strain hardening behavior in the ultrafine-grained Nb-bearing dual phase steels, Mater. Sci. Eng. A, 678(2016), p. 215. doi: 10.1016/j.msea.2016.09.108
    [28]
    T. Zhang, J. Long, X.L. Sun, Y. Su, and Z.X. Li, Relationship between threshold stress of hydrogen induced cracking and hydrogen permeation for X80 pipeline steel, Mater. Mech. Eng., 27(2003), p. 14.
    [29]
    P.P. Bai, J. Zhou, B.W. Luo, S.Q. Zheng, P.Y. Wang, and Y. Tian, Hydrogen embrittlement of X80 pipeline steel in H2S environment: Effect of hydrogen charging time, hydrogen-trapped state and hydrogen charging releasing–recharging cycles, Int. J. Miner. Metall. Mater., 27(2020), No. 1, p. 63. doi: 10.1007/s12613-019-1870-1
    [30]
    M.A.V. Devanathan and Z. Stachurski, The mechanism of hydrogen evolution on iron in acid solutions by determination of permeation rates, J. Electrochem. Soc., 111(1964), No. 5, p. 619. doi: 10.1149/1.2426195
    [31]
    R. Wang, Effects of hydrogen on fracture of pre-cracking samples of X70 pipeline steel, J. Chin. Soc. Corros. Prot., 28(2008), No. 2, p. 81.
    [32]
    G.P. Tiwari, A. Bose, J.K. Chakravartty, S.L. Wadekar, M.K. Totlani, R.N. Arya, and R.K. Fotedar, A study of internal hydrogen embrittlement of steels, Mater. Sci. Eng. A, 286(2000), No. 2, p. 269. doi: 10.1016/S0921-5093(00)00793-0
    [33]
    G. M. Pressouyre, A classification of hydrogen traps in steel, Metall. Trans. A, 10(1979), No. 10, p. 1571. doi: 10.1007/BF02812023
    [34]
    P. CastañoRivera, V.P. Ramunni, and P. Bruzzoni, Hydrogen trapping in an API 5L X60, Corros. Sci., 54(2012), p. 106. doi: 10.1016/j.corsci.2011.09.008
    [35]
    J. Li, J.S. Wu, Z.H. Wang, S.Q. Zhang, X.G. Wu, Y.H. Huang, and X.G. Li, The effect of nanosized NbC precipitates on electrochemical corrosion behavior of high-strength low-alloy steel in 3.5%NaCl solution, Int. J. Hydrogen Energy, 42(2017), No. 34, p. 22175. doi: 10.1016/j.ijhydene.2017.03.087
    [36]
    Q.Q. Cui, J.S. Wu, D.H. Xie, X.G. Wu, Y.H. Huang, and X.G. Li, Effect of nanosized NbC precipitates on hydrogen diffusion in X80 pipeline steel, Materials (Basel), 10(2017), No. 7, p. 721. doi: 10.3390/ma10070721
    [37]
    F.G. Wei, T. Hara, and K. Tsuzaki, Nano-precipitates design with hydrogen trapping character in high strengthsteels, [in] Y. Weng, H. Dong, and Y. Gan, eds., Advanced Steels, Springer, Berlin, Heidelberg, 2011, p. 87.
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