Synthesis, characterization and magnetic properties of KFeO<sub>2</sub> nanoparticles prepared by a simple egg white solution route

Thongsuk Sichumsaeng; Nutthakritta Phromviyo; Supree Pinitsoontorn; Pinit Kidkhunthod; Narong Chanlek; Santi Maensiri

doi:10.1007/s12613-020-2194-x

Volume 29 Issue 1

Jan. 2022

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Article Navigation > International Journal of Minerals, Metallurgy and Materials > 2022 > 29(1): 128-135

Thongsuk Sichumsaeng, Nutthakritta Phromviyo, Supree Pinitsoontorn, Pinit Kidkhunthod, Narong Chanlek, and Santi Maensiri, Synthesis, characterization and magnetic properties of KFeO₂ nanoparticles prepared by a simple egg white solution route, Int. J. Miner. Metall. Mater., 29(2022), No. 1, pp. 128-135. https://doi.org/10.1007/s12613-020-2194-x

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Thongsuk Sichumsaeng, Nutthakritta Phromviyo, Supree Pinitsoontorn, Pinit Kidkhunthod, Narong Chanlek, and Santi Maensiri, Synthesis, characterization and magnetic properties of KFeO2 nanoparticles prepared by a simple egg white solution route, Int. J. Miner. Metall. Mater., 29(2022), No. 1, pp. 128-135. https://doi.org/10.1007/s12613-020-2194-x

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Synthesis, characterization and magnetic properties of KFeO₂ nanoparticles prepared by a simple egg white solution route

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Corresponding author:
Santi Maensiri E-mail: antimaensiri@gmail.com
Received: 3 July 2020; Revised: 8 September 2020; Accepted: 11 September 2020; Available online: 12 September 2020

Abstract

Abstract

Nanoparticles of potassium ferrite (KFeO₂) in this work were synthesized by a simple egg white solution method upon calcination in air at 773, 873, and 973 K for 2 h. The effects of calcination temperature on the structural and magnetic properties of the synthesized KFeO₂ nanoparticles were investigated. By varying the calcination temperature, X-ray diffraction and transmission electron microscopy results indicated the changes in crystallinity and morphology including particle size, respectively. Notably, the reduction in particle size of the synthesized KFeO₂ was found to have a remarkable influence on the magnetic properties. At room temperature, the synthesized KFeO₂ nanoparticles prepared at 873 K exhibited the highest saturation magnetization (M_S) of 2.07 × 10⁴ A·m⁻¹. In addition, the coercivity (H_C) increased from 3.51 to 16.89 kA·m⁻¹ as the calcination temperature increased to 973 K. The zero-field cooled (ZFC) results showed that the blocking temperatures (T_B) of about 125 and 85 K were observed in the samples calcined at 773 and 873 K, respectively. Therefore, this work showed that the egg white solution method is simple, cost effective, and environmentally friendly for the preparation of KFeO₂ nanoparticles.
- egg white solution method;
- potassium ferrite nanoparticles;
- magnetic properties;
- ferromagnetism

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