Effect of cathodic potential on stress corrosion cracking behavior of 21Cr2NiMo steel in simulated seawater

Menghao Liu; Zhiyong Liu; Cuiwei Du; Xiaoqin Zhan; Chunduo Dai; Yue Pan; Xiaogang Li

doi:10.1007/s12613-020-2199-5

Volume 29 Issue 2

Feb. 2022

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Article Navigation > International Journal of Minerals, Metallurgy and Materials > 2022 > 29(2): 263-270

Menghao Liu, Zhiyong Liu, Cuiwei Du, Xiaoqin Zhan, Chunduo Dai, Yue Pan, and Xiaogang Li, Effect of cathodic potential on stress corrosion cracking behavior of 21Cr2NiMo steel in simulated seawater, Int. J. Miner. Metall. Mater., 29(2022), No. 2, pp. 263-270. https://doi.org/10.1007/s12613-020-2199-5

Cite this article as:

Menghao Liu, Zhiyong Liu, Cuiwei Du, Xiaoqin Zhan, Chunduo Dai, Yue Pan, and Xiaogang Li, Effect of cathodic potential on stress corrosion cracking behavior of 21Cr2NiMo steel in simulated seawater, Int. J. Miner. Metall. Mater., 29(2022), No. 2, pp. 263-270. https://doi.org/10.1007/s12613-020-2199-5

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Research Article

Effect of cathodic potential on stress corrosion cracking behavior of 21Cr2NiMo steel in simulated seawater

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Corresponding authors:
Zhiyong Liu E-mail: liuzhiyong7804@ustb.edu.cn

Cuiwei Du E-mail: dcw@ustb.edu.cn
Received: 22 May 2020; Revised: 17 September 2020; Accepted: 21 September 2020; Available online: 25 September 2020

Abstract

Abstract

This study aims at providing systematically insights to clarify the impact of cathodic polarization on the stress corrosion cracking (SCC) behavior of 21Cr2NiMo steel. Slow-strain-rate tensile tests demonstrated that 21Cr2NiMo steel is highly sensitive to hydrogen embrittlement at strong cathodic polarization. The lowest SCC susceptibility occurred at −775 mV vs. SCE, whereas the SCC susceptibility was remarkably higher at potentials below −950 mV vs. SCE. Scanning electron microscopy (SEM) and electron backscattered diffraction (EBSD) revealed that the cathodic potential decline caused a transition from transgranular to intergranular mode in the fracture path. The intergranular mode transformed from bainite boundaries separation to prior austenitic grain boundaries separation under stronger cathodic polarization. Furthermore, corrosion pits promoted the nucleation of SCC cracks. In conclusion, with the decrease in the applied potential, the SCC mechanism transformed from the combination of hydrogen embrittlement and anodic dissolution to typical hydrogen embrittlement.
- stress corrosion cracking;
- cathodic potential;
- hydrogen embrittlement;
- seawater;
- high-strength low-alloy steel

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