Yue Liu, Shaobo Huang, Shanlong Peng, Heng Zhang, Lifan Wang,  and Xindong Wang, Novel Au nanoparticles-inlaid titanium paper for PEM water electrolysis with enhanced interfacial electrical conductivity, Int. J. Miner. Metall. Mater., 29(2022), No. 5, pp. 1090-1098. https://doi.org/10.1007/s12613-022-2452-1
Cite this article as:
Yue Liu, Shaobo Huang, Shanlong Peng, Heng Zhang, Lifan Wang,  and Xindong Wang, Novel Au nanoparticles-inlaid titanium paper for PEM water electrolysis with enhanced interfacial electrical conductivity, Int. J. Miner. Metall. Mater., 29(2022), No. 5, pp. 1090-1098. https://doi.org/10.1007/s12613-022-2452-1
Research Article

Novel Au nanoparticles-inlaid titanium paper for PEM water electrolysis with enhanced interfacial electrical conductivity

+ Author Affiliations
  • Corresponding authors:

    Lifan Wang    E-mail: wanglifanustb@163.com

    Xindong Wang    E-mail: echem@ustb.edu.cn

  • Received: 18 January 2022Revised: 28 February 2022Accepted: 1 March 2022Available online: 2 March 2022
  • Proton-exchange membrane water electrolysis (PEM WE) is a particularly promising technology for renewable hydrogen production. However, the excessive passivation of the gas diffusion layer (GDL) will seriously affect the high surface-contact resistance and result in energy losses. Thus, a mechanism for improving the conductivity and interface stability of the GDL is an urgent issue. In this work, we have prepared a hydrophilic and corrosion resistant conductive composite protective coating. The polydopamine (PDA) film on the Ti surface, which was obtained via the solution oxidation method, ensured that neither micropores nor pinholes existed in the final hybrid coatings. In-situ reduced gold nanoparticles (AuNPs) improved the conductivity to achieve the desired interfacial contact resistance and further enhanced the corrosion resistance. The surface composition of the treated samples was investigated using scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and Fourier transform infrared spectroscopy (FTIR). The results indicated that the optimized reaction conditions included a pH value of 3 of HAuCl4 solution with PDA deposition (48 h) on papers and revealed the lowest contact resistance (0.5 mΩ·cm2) and corrosion resistance (0.001 µA·cm−2) in a 0.5 M H2SO4 + 2 ppm F solution (1.7 V vs. RHE) among all the modified specimens, where RHE represents reversible hydrogen electrode. These findings indicated that the Au–PDA coating is very appropriate for the modification of Ti GDLs in PEM WE systems.
  • loading
  • Supplementary Information12613-022-2452-1-z.docx
  • [1]
    C. Liu, M. Shviro, A.S. Gago, et al., Exploring the interface of skin-layered titanium fibers for electrochemical water splitting, Adv. Energy Mater., 11(2021), No. 8, art. No. 2002926. doi: 10.1002/aenm.202002926
    [2]
    M. Carmo, D.L. Fritz, J. Mergel, and D. Stolten, A comprehensive review on PEM water electrolysis, Int. J. Hydrogen Energy, 38(2013), No. 12, p. 4901. doi: 10.1016/j.ijhydene.2013.01.151
    [3]
    C. Niether, S. Faure, A. Bordet, et al., Improved water electrolysis using magnetic heating of FeC–Ni core-shell nanoparticles, Nat. Energy, 3(2018), No. 6, p. 476. doi: 10.1038/s41560-018-0132-1
    [4]
    A. Landman, H. Dotan, G.E. Shter, et al., Photoelectrochemical water splitting in separate oxygen and hydrogen cells, Nat. Mater., 16(2017), No. 6, p. 646. doi: 10.1038/nmat4876
    [5]
    F. Barbir, PEM electrolysis for production of hydrogen from renewable energy sources, Sol. Energy, 78(2005), No. 5, p. 661. doi: 10.1016/j.solener.2004.09.003
    [6]
    H. Ito, T. Maeda, A. Nakano, A. Kato, and T. Yoshida, Influence of pore structural properties of current collectors on the performance of proton exchange membrane electrolyzer, Electrochim. Acta, 100(2013), p. 242. doi: 10.1016/j.electacta.2012.05.068
    [7]
    F. Arbabi, A. Kalantarian, R. Abouatallah, R. Wang, J.S. Wallace, and A. Bazylak, Feasibility study of using microfluidic platforms for visualizing bubble flows in electrolyzer gas diffusion layers, J. Power Sources, 258(2014), p. 142. doi: 10.1016/j.jpowsour.2014.02.042
    [8]
    S. Siracusano, A. Di Blasi, V. Baglio, et al., Optimization of components and assembling in a PEM electrolyzer stack, Int. J. Hydrogen Energy, 36(2011), No. 5, p. 3333. doi: 10.1016/j.ijhydene.2010.12.044
    [9]
    N. Sato, An overview on the passivity of metals, Corros. Sci., 31(1990), p. 1. doi: 10.1016/0010-938X(90)90086-K
    [10]
    H.Y. Jung, S.Y. Huang, P. Ganesan, and B.N. Popov, Performance of gold-coated titanium bipolar plates in unitized regenerative fuel cell operation, J. Power Sources, 194(2009), No. 2, p. 972. doi: 10.1016/j.jpowsour.2009.06.030
    [11]
    S.H. Wang, J. Peng, and W.B. Lui, Surface modification and development of titanium bipolar plates for PEM fuel cells, J. Power Sources, 160(2006), No. 1, p. 485. doi: 10.1016/j.jpowsour.2006.01.020
    [12]
    M.J. Hwang, E.J. Park, W.J. Moon, H.J. Song, and Y.J. Park, Characterization of passive layers formed on Ti–10wt% (Ag, Au, Pd, or Pt) binary alloys and their effects on galvanic corrosion, Corros. Sci., 96(2015), p. 152. doi: 10.1016/j.corsci.2015.04.007
    [13]
    Z.X. He, Y.R. Lv, T.A. Zhang, et al., Electrode materials for vanadium redox flow batteries: Intrinsic treatment and introducing catalyst, Chem. Eng. J., 427(2022), art. No. 131680. doi: 10.1016/j.cej.2021.131680
    [14]
    S.H. Wang, W.B. Lui, J. Peng, and J.S. Zhang, Performance of the iridium oxide (IrO2)-modified titanium bipolar plates for the light weight proton exchange membrane fuel cells, J. Fuel Cell Sci. Technol., 10(2013), No. 4, art. No. 041002. doi: 10.1115/1.4024565
    [15]
    H. Wakayama and K. Yamazaki, Low-cost bipolar plates of Ti4O7-coated Ti for water electrolysis with polymer electrolyte membranes, ACS Omega, 6(2021), No. 6, p. 4161. doi: 10.1021/acsomega.0c04786
    [16]
    Y.Z. Chen, D.J. Jiang, Z.Q. Gong, J.Y. Li, and L.N. Wang, Anodized metal oxide nanostructures for photoelectrochemical water splitting, Int. J. Miner. Metall. Mater., 27(2020), No. 5, p. 584. doi: 10.1007/s12613-020-1983-6
    [17]
    T.J. Toops, M.P. Brady, F.Y. Zhang, et al., Evaluation of nitrided titanium separator plates for proton exchange membrane electrolyzer cells, J. Power Sources, 272(2014), p. 954. doi: 10.1016/j.jpowsour.2014.09.016
    [18]
    J. Bi, J.M. Yang, X.X. Liu, et al., Development and evaluation of nitride coated titanium bipolar plates for PEM fuel cells, Int. J. Hydrogen Energy, 46(2021), No. 1, p. 1144. doi: 10.1016/j.ijhydene.2020.09.217
    [19]
    K. Feng, D.T.K. Kwok, D.A. Liu, Z.G. Li, X. Cai, and P.K. Chu, Nitrogen plasma-implanted titanium as bipolar plates in polymer electrolyte membrane fuel cells, J. Power Sources, 195(2010), No. 19, p. 6798. doi: 10.1016/j.jpowsour.2010.04.053
    [20]
    A. Shenhar, I. Gotman, E.Y. Gutmanas, and P. Ducheyne, Surface modification of titanium alloy orthopaedic implants via novel powder immersion reaction assisted coating nitriding method, Mater. Sci. Eng. A, 268(1999), No. 1-2, p. 40. doi: 10.1016/S0921-5093(99)00111-2
    [21]
    X. Zhang, W.W. Yang, M.Y. Gao, H. Liu, K.F. Li, and Y.S. Yu, Room-temperature solid phase surface engineering of BiOI sheets stacking g-C3N4 boosts photocatalytic reduction of Cr(VI), Green Energy Environ., 7(2022), No. 1, p. 66. doi: 10.1016/j.gee.2020.07.024
    [22]
    E. Petkucheva, G. Borisov, E. Lefterova, J. Heiss, U. Schnakenberg, and E. Slavcheva, Gold-supported magnetron sputtered Ir thin films as OER catalysts for cost-efficient water electrolysis, Int. J. Hydrogen Energy, 43(2018), No. 35, p. 16905. doi: 10.1016/j.ijhydene.2018.01.188
    [23]
    M. Stern and H. Wissenberg, The influence of noble metal alloy additions on the electrochemical and corrosion behavior of titanium, J. Electrochem. Soc., 106(1959), No. 9, art. No. 759. doi: 10.1149/1.2427493
    [24]
    L. Jiang, J.A. Syed, Y.Z. Gao, H.B. Lu, and X.K. Meng, Electrodeposition of Ni(OH)2 reinforced polyaniline coating for corrosion protection of 304 stainless steel, Appl. Surf. Sci., 440(2018), p. 1011. doi: 10.1016/j.apsusc.2018.01.145
    [25]
    Y. Wang and D.O. Northwood, An investigation into the effects of a nano-thick gold interlayer on polypyrrole coatings on 316L stainless steel for the bipolar plates of PEM fuel cells, J. Power Sources, 175(2008), No. 1, p. 40. doi: 10.1016/j.jpowsour.2007.09.089
    [26]
    C. Xia, Y. Li, Y. Tian, et al., Intermediate temperature fuel cell with a doped ceria-carbonate composite electrolyte, J. Power Sources, 195(2010), No. 10, p. 3149. doi: 10.1016/j.jpowsour.2009.11.104
    [27]
    L. Ai, Y. Liu, X.Y. Zhang, X.H. Ouyang, and Z.Y. Ge, A facile and template-free method for preparation of polythiophene microspheres and their dispersion for waterborne corrosion protection coatings, Synth. Met., 191(2014), p. 41. doi: 10.1016/j.synthmet.2014.02.004
    [28]
    K. Zhang and S. Sharma, Site-selective, low-loading, Au nanoparticle-polyaniline hybrid coatings with enhanced corrosion resistance and conductivity for fuel cells, ACS Sustain. Chem. Eng., 5(2017), No. 1, p. 277. doi: 10.1021/acssuschemeng.6b01504
    [29]
    A. Jacques, B. Barthélémy, J. Delhalle, and Z. Mekhalif, 1-Pyrrolyl-10-decylammoniumphosphonate monolayer: A molecular nanolink between electropolymerized pyrrole films and nickel or titanium surfaces, Electrochim. Acta, 170(2015), p. 218. doi: 10.1016/j.electacta.2015.04.123
    [30]
    M. Rohwerder and A. Michalik, Conducting polymers for corrosion protection: What makes the difference between failure and success? Electrochim. Acta, 53(2007), No. 3, p. 1300. doi: 10.1016/j.electacta.2007.05.026
    [31]
    J.L. Tan, Z. Zhang, and D.T. Ge, Electrodeposition of adherent polypyrrole film on titanium surface with enhanced anti-corrosion performance, MATEC Web Conf., 130(2017), art. No. 08007. doi: 10.1051/matecconf/201713008007
    [32]
    V. Ball, Polydopamine films and particles with catalytic activity, Catal. Today, 301(2018), p. 196. doi: 10.1016/j.cattod.2017.01.031
    [33]
    Y. Liang, J. Wei, Y.X. Hu, et al., Metal-polydopamine frameworks and their transformation to hollow metal/N-doped carbon particles, Nanoscale, 9(2017), No. 16, p. 5323. doi: 10.1039/C7NR00978J
    [34]
    T.L. Chang, X.J. Yu, and J.F. Liang, Polydopamine-enabled surface coating with nano-metals, Surf. Coat. Technol., 337(2018), p. 389. doi: 10.1016/j.surfcoat.2018.01.009
    [35]
    W. Tamakloe, D.A. Agyeman, M. Park, J. Yang, and Y.M. Kang, Polydopamine-induced surface functionalization of carbon nanofibers for Pd deposition enabling enhanced catalytic activity for the oxygen reduction and evolution reactions, J. Mater. Chem. A, 7(2019), No. 13, p. 7396. doi: 10.1039/C9TA00025A
    [36]
    X.H. Guo, M. Zhang, J. Zheng, et al., Fabrication of Co@SiO2@C/Ni submicrorattles as highly efficient catalysts for 4-nitrophenol reduction, Dalton Trans., 46(2017), No. 35, p. 11598. doi: 10.1039/C7DT02095C
    [37]
    C.H. Liu, Y.Y. Qiu, Y.J. Xia, et al., Noble-metal-free tungsten oxide/carbon (WOx/C) hybrid manowires for highly efficient hydrogen evolution, Nanotechnology, 28(2017), No. 44, art. No. 445403. doi: 10.1088/1361-6528/aa8613
    [38]
    K.M. Im, T.W. Kim, and J.R. Jeon, Metal-chelation-assisted deposition of polydopamine on human hair: A ready-to-use eumelanin-based hair dyeing methodology, ACS Biomater. Sci. Eng., 3(2017), No. 4, p. 628. doi: 10.1021/acsbiomaterials.7b00031
    [39]
    H. Lee, S.M. Dellatore, W.M. Miller, and P.B. Messersmith, Mussel-inspired surface chemistry for multifunctional coatings, Science, 318(2007), No. 5849, p. 426. doi: 10.1126/science.1147241
    [40]
    H.Q. Li, Y.V. Aulin, L. Frazer, et al., Structure evolution and thermoelectric properties of carbonized polydopamine thin films, ACS Appl. Mater. Interfaces, 9(2017), No. 8, p. 6655. doi: 10.1021/acsami.6b15601
    [41]
    J.A.A. Ho, H.C. Chang, and W.T. Su, DOPA-mediated reduction allows the facile synthesis of fluorescent gold nanoclusters for use as sensing probes for ferric ions, Anal. Chem., 84(2012), No. 7, p. 3246. doi: 10.1021/ac203362g
    [42]
    C.C. Lu, M. Zhang, A.J. Li, X.W. He, and X.B. Yin, 3, 4-dihydroxy-L-phenylalanine for preparation of gold nanoparticles and as electron transfer promoter in H2O2 biosensor, Electroanalysis, 23(2011), No. 10, p. 2421. doi: 10.1002/elan.201100291
    [43]
    P.C. Huang, W.J. Ma, P. Yu, and L.Q. Mao, Dopamine-directed in situ and one-step synthesis of Au@Ag core-shell nanoparticles immobilized to a metal-organic framework for synergistic catalysis, Chem. Asian J., 11(2016), No. 19, p. 2705. doi: 10.1002/asia.201600469
    [44]
    Y.Z. Ni, G.S. Tong, J. Wang, et al., One-pot preparation of pomegranate-like polydopamine stabilized small gold nanoparticles with superior stability for recyclable nanocatalysts, RSC Adv., 6(2016), No. 47, p. 40698. doi: 10.1039/C6RA05902C
    [45]
    G.X. Su, C. Yang, and J.J. Zhu, Fabrication of gold nanorods with tunable longitudinal surface plasmon resonance peaks by reductive dopamine, Langmuir, 31(2015), No. 2, p. 817. doi: 10.1021/la504041f
    [46]
    V. Ball, D.D. Frari, V. Toniazzo, and D. Ruch, Kinetics of polydopamine film deposition as a function of pH and dopamine concentration: Insights in the polydopamine deposition mechanism, J. Colloid Interface Sci., 386(2012), No. 1, p. 366. doi: 10.1016/j.jcis.2012.07.030
    [47]
    J.H. Jiang, L.P. Zhu, L.J. Zhu, B.K. Zhu, and Y.Y. Xu, Surface characteristics of a self-polymerized dopamine coating deposited on hydrophobic polymer films, Langmuir, 27(2011), No. 23, p. 14180. doi: 10.1021/la202877k
    [48]
    W. Zhang, F.K. Yang, Y.G. Han, R. Gaikwad, Z. Leonenko, and B.X. Zhao, Surface and tribological behaviors of the bioinspired polydopamine thin films under dry and wet conditions, Biomacromolecules, 14(2013), No. 2, p. 394. doi: 10.1021/bm3015768
    [49]
    F. Bernsmann, V. Ball, F. Addiego, et al., Dopamine–melanin film deposition depends on the used oxidant and buffer solution, Langmuir, 27(2011), No. 6, p. 2819. doi: 10.1021/la104981s
    [50]
    Y.H. Lee and T.G. Park, Facile fabrication of branched gold nanoparticles by reductive hydroxyphenol derivatives, Langmuir, 27(2011), No. 6, p. 2965. doi: 10.1021/la1044078
    [51]
    M. Bisaglia, S. Mammi, and L. Bubacco, Kinetic and structural analysis of the early oxidation products of dopamine: Analysis of the interactions with α-synuclein, J. Biol. Chem., 282(2007), No. 21, p. 15597. doi: 10.1074/jbc.M610893200
    [52]
    I. Iftikhar, K.M.A. El-Nour, and A. Brajter-Toth, Detection of transient dopamine antioxidant radicals using electrochemistry in electrospray ionization mass spectrometry, Electrochim. Acta, 249(2017), p. 145. doi: 10.1016/j.electacta.2017.07.087
    [53]
    S.N. Du, Y. Luo, Z.F. Liao, et al., New insights into the formation mechanism of gold nanoparticles using dopamine as a reducing agent, J. Colloid Interface Sci., 523(2018), p. 27. doi: 10.1016/j.jcis.2018.03.077
    [54]
    O. Terland, T. Flatmark, A. Tangerås, and M. Grønberg, Dopamine oxidation generates an oxidative stress mediated by dopamine semiquinone and unrelated to reactive oxygen species, J. Mol. Cell. Cardiol., 29(1997), No. 6, p. 1731. doi: 10.1006/jmcc.1997.0412
    [55]
    A. Klegeris, L.G. Korkina, and S.A. Greenfield, Autoxidation of dopamine: A comparison of luminescent and spectrophotometric detection in basic solutions, Free. Radic. Biol. Med., 18(1995), No. 2, p. 215. doi: 10.1016/0891-5849(94)00141-6
    [56]
    S.P. Mani, C. Anandan, and N. Rajendran, Formation of a protective nitride layer by electrochemical nitridation on 316L SS bipolar plates for a proton exchange membrane fuel cell (PEMFC), RSC Adv., 5(2015), No. 79, p. 64466. doi: 10.1039/C5RA05412E
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Figures(6)  / Tables(1)

    Share Article

    Article Metrics

    Article Views(1918) PDF Downloads(84) Cited by()
    Proportional views

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return